{"title":"聚硫乙醛:从旧化学到新视角","authors":"Emre Akar, Umit Tunca, Hakan Durmaz","doi":"10.1016/j.eurpolymj.2024.113532","DOIUrl":null,"url":null,"abstract":"<div><div>In this review, we comprehensively described the synthetic approaches for the preparation of polythioacetals (PTAs) by step-growth, chain-growth, and post-polymerization modification techniques from the<!--> <!-->past to the<!--> <!-->present. In addition, we reviewed the state-of-the-art applications of PTAs as reactive oxygen species (ROS) responsive polymers, chemosensors for Hg<sup>2+</sup> ions, and polymers with dynamic covalent bond properties. Since a wide range of reactive oxygen species (ROS) applications of PTAs for cell delivery is beyond the scope of this review, some pioneering works are discussed, and the remaining items are only cited in the text. However, the utilization of PTAs as chemosensors for Hg<sup>2+</sup> ions and the dynamic covalent bond properties of PTAs are extensively reviewed here. Also, as less common implementations of PTAs, the proton shelter and the polymeric bone cement examples are described in the text. The practical synthesizability of PTA and its wide range of applications in materials science and bio-based applications indicate that this fundamental reaction will proceed to be used continuously in various disciplines of chemistry in the future.</div></div>","PeriodicalId":315,"journal":{"name":"European Polymer Journal","volume":"221 ","pages":"Article 113532"},"PeriodicalIF":5.8000,"publicationDate":"2024-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Polythioacetals: From old chemistry to new perspectives\",\"authors\":\"Emre Akar, Umit Tunca, Hakan Durmaz\",\"doi\":\"10.1016/j.eurpolymj.2024.113532\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>In this review, we comprehensively described the synthetic approaches for the preparation of polythioacetals (PTAs) by step-growth, chain-growth, and post-polymerization modification techniques from the<!--> <!-->past to the<!--> <!-->present. In addition, we reviewed the state-of-the-art applications of PTAs as reactive oxygen species (ROS) responsive polymers, chemosensors for Hg<sup>2+</sup> ions, and polymers with dynamic covalent bond properties. Since a wide range of reactive oxygen species (ROS) applications of PTAs for cell delivery is beyond the scope of this review, some pioneering works are discussed, and the remaining items are only cited in the text. However, the utilization of PTAs as chemosensors for Hg<sup>2+</sup> ions and the dynamic covalent bond properties of PTAs are extensively reviewed here. Also, as less common implementations of PTAs, the proton shelter and the polymeric bone cement examples are described in the text. The practical synthesizability of PTA and its wide range of applications in materials science and bio-based applications indicate that this fundamental reaction will proceed to be used continuously in various disciplines of chemistry in the future.</div></div>\",\"PeriodicalId\":315,\"journal\":{\"name\":\"European Polymer Journal\",\"volume\":\"221 \",\"pages\":\"Article 113532\"},\"PeriodicalIF\":5.8000,\"publicationDate\":\"2024-10-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"European Polymer Journal\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0014305724007936\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"European Polymer Journal","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0014305724007936","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
Polythioacetals: From old chemistry to new perspectives
In this review, we comprehensively described the synthetic approaches for the preparation of polythioacetals (PTAs) by step-growth, chain-growth, and post-polymerization modification techniques from the past to the present. In addition, we reviewed the state-of-the-art applications of PTAs as reactive oxygen species (ROS) responsive polymers, chemosensors for Hg2+ ions, and polymers with dynamic covalent bond properties. Since a wide range of reactive oxygen species (ROS) applications of PTAs for cell delivery is beyond the scope of this review, some pioneering works are discussed, and the remaining items are only cited in the text. However, the utilization of PTAs as chemosensors for Hg2+ ions and the dynamic covalent bond properties of PTAs are extensively reviewed here. Also, as less common implementations of PTAs, the proton shelter and the polymeric bone cement examples are described in the text. The practical synthesizability of PTA and its wide range of applications in materials science and bio-based applications indicate that this fundamental reaction will proceed to be used continuously in various disciplines of chemistry in the future.
期刊介绍:
European Polymer Journal is dedicated to publishing work on fundamental and applied polymer chemistry and macromolecular materials. The journal covers all aspects of polymer synthesis, including polymerization mechanisms and chemical functional transformations, with a focus on novel polymers and the relationships between molecular structure and polymer properties. In addition, we welcome submissions on bio-based or renewable polymers, stimuli-responsive systems and polymer bio-hybrids. European Polymer Journal also publishes research on the biomedical application of polymers, including drug delivery and regenerative medicine. The main scope is covered but not limited to the following core research areas:
Polymer synthesis and functionalization
• Novel synthetic routes for polymerization, functional modification, controlled/living polymerization and precision polymers.
Stimuli-responsive polymers
• Including shape memory and self-healing polymers.
Supramolecular polymers and self-assembly
• Molecular recognition and higher order polymer structures.
Renewable and sustainable polymers
• Bio-based, biodegradable and anti-microbial polymers and polymeric bio-nanocomposites.
Polymers at interfaces and surfaces
• Chemistry and engineering of surfaces with biological relevance, including patterning, antifouling polymers and polymers for membrane applications.
Biomedical applications and nanomedicine
• Polymers for regenerative medicine, drug delivery molecular release and gene therapy
The scope of European Polymer Journal no longer includes Polymer Physics.