Bin Zhang , Dechuan Peng , Bing Hao , Yongqing Shen , Manyuan Gan , Yanhui Song , Haixia Zhang , Peizhi Liu , Bingshe Xu , Junjie Guo
{"title":"利用水下电弧放电一步合成碳离子支撑的铂钴合金,用于 pH 值通用氢进化反应","authors":"Bin Zhang , Dechuan Peng , Bing Hao , Yongqing Shen , Manyuan Gan , Yanhui Song , Haixia Zhang , Peizhi Liu , Bingshe Xu , Junjie Guo","doi":"10.1016/j.susmat.2024.e01160","DOIUrl":null,"url":null,"abstract":"<div><div>Exploring low-cost and highly efficient electrocatalysts for pH-universal hydrogen evolution reaction (HER) is critical for the development of hydrogen energy conversion but challenging. In this study a novel catalyst of well-dispersed Pt<img>Co alloy nanoparticles with a size of ∼2 nm anchored on carbon nano onions (CNOs) has been constructed by a one-step underwater arc discharge method. The optimized Pt<sub>0.91</sub>Co<sub>0.09</sub>@CNOs catalyst with a Pt loading of 17.5 wt% and Co loading of 0.54 wt% exhibits excellent HER performances with overpotentials of 24 mV, 15 mV and 39 mV at the current density of 10 mA cm<sup>−2</sup>, and 137 mV, 108 mV and 63 mV at 100 mA cm<sup>−2</sup> in alkaline, neutral, and acidic electrolytes, respectively, as well as superior continuous stability. Density functional theory calculations indicate the formation of Pt<img>Co nano alloy is beneficial for the modulation of the electron structure of catalysts, and thus presents a moderate H* adsorption energy and d-band center. This work provides a simple and economical strategy on constructing efficient alloy catalysts for pH-universal HER and offers an opportunity for the real-world application of hydrogen energy conversions.</div></div>","PeriodicalId":22097,"journal":{"name":"Sustainable Materials and Technologies","volume":"42 ","pages":"Article e01160"},"PeriodicalIF":8.6000,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"One-step synthesis of carbon-onion-supported PtCo alloy by underwater arc discharge for pH-universal hydrogen evolution reaction\",\"authors\":\"Bin Zhang , Dechuan Peng , Bing Hao , Yongqing Shen , Manyuan Gan , Yanhui Song , Haixia Zhang , Peizhi Liu , Bingshe Xu , Junjie Guo\",\"doi\":\"10.1016/j.susmat.2024.e01160\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Exploring low-cost and highly efficient electrocatalysts for pH-universal hydrogen evolution reaction (HER) is critical for the development of hydrogen energy conversion but challenging. In this study a novel catalyst of well-dispersed Pt<img>Co alloy nanoparticles with a size of ∼2 nm anchored on carbon nano onions (CNOs) has been constructed by a one-step underwater arc discharge method. The optimized Pt<sub>0.91</sub>Co<sub>0.09</sub>@CNOs catalyst with a Pt loading of 17.5 wt% and Co loading of 0.54 wt% exhibits excellent HER performances with overpotentials of 24 mV, 15 mV and 39 mV at the current density of 10 mA cm<sup>−2</sup>, and 137 mV, 108 mV and 63 mV at 100 mA cm<sup>−2</sup> in alkaline, neutral, and acidic electrolytes, respectively, as well as superior continuous stability. Density functional theory calculations indicate the formation of Pt<img>Co nano alloy is beneficial for the modulation of the electron structure of catalysts, and thus presents a moderate H* adsorption energy and d-band center. This work provides a simple and economical strategy on constructing efficient alloy catalysts for pH-universal HER and offers an opportunity for the real-world application of hydrogen energy conversions.</div></div>\",\"PeriodicalId\":22097,\"journal\":{\"name\":\"Sustainable Materials and Technologies\",\"volume\":\"42 \",\"pages\":\"Article e01160\"},\"PeriodicalIF\":8.6000,\"publicationDate\":\"2024-10-29\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Sustainable Materials and Technologies\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2214993724003403\",\"RegionNum\":2,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ENERGY & FUELS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Sustainable Materials and Technologies","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2214993724003403","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
One-step synthesis of carbon-onion-supported PtCo alloy by underwater arc discharge for pH-universal hydrogen evolution reaction
Exploring low-cost and highly efficient electrocatalysts for pH-universal hydrogen evolution reaction (HER) is critical for the development of hydrogen energy conversion but challenging. In this study a novel catalyst of well-dispersed PtCo alloy nanoparticles with a size of ∼2 nm anchored on carbon nano onions (CNOs) has been constructed by a one-step underwater arc discharge method. The optimized Pt0.91Co0.09@CNOs catalyst with a Pt loading of 17.5 wt% and Co loading of 0.54 wt% exhibits excellent HER performances with overpotentials of 24 mV, 15 mV and 39 mV at the current density of 10 mA cm−2, and 137 mV, 108 mV and 63 mV at 100 mA cm−2 in alkaline, neutral, and acidic electrolytes, respectively, as well as superior continuous stability. Density functional theory calculations indicate the formation of PtCo nano alloy is beneficial for the modulation of the electron structure of catalysts, and thus presents a moderate H* adsorption energy and d-band center. This work provides a simple and economical strategy on constructing efficient alloy catalysts for pH-universal HER and offers an opportunity for the real-world application of hydrogen energy conversions.
期刊介绍:
Sustainable Materials and Technologies (SM&T), an international, cross-disciplinary, fully open access journal published by Elsevier, focuses on original full-length research articles and reviews. It covers applied or fundamental science of nano-, micro-, meso-, and macro-scale aspects of materials and technologies for sustainable development. SM&T gives special attention to contributions that bridge the knowledge gap between materials and system designs.