三聚氰胺衍生介孔碳用于高效、选择性地去除金银花煎剂中的痕量汞(II)

IF 3.7 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
ACS Omega Pub Date : 2024-11-01 DOI:10.1021/acsomega.4c03269
Qing He, Kun Pang, Lin Tian, Yiqian Ma, Xiang Guo, Jianyong Zhang, Ming Yu
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引用次数: 0

摘要

通过热解改性三聚氰胺得到的三聚氰胺衍生介孔碳被用于消除金银花煎剂中的微量汞(II)。具有 N 功能的介孔碳(MCN1)的比表面积为 648.372 m2-g-1。对 MCN1 的化学成分和形态进行了深入研究,并通过综合分析确定了其形成机制。吸附效果与 MCN1 的化学成分之间存在着显著的联系。在广泛的 pH 值范围(pH 值 2-9)内消除水溶液中的痕量汞时,MCN1 表现出很高的有效性,接近 100%。吸附动力学和等温线结果表明,伪二阶动力学和 Freundlich 模型能更准确地反映 MCN1 对 Hg(II) 的吸附情况,而化学吸附则是主要机制。本研究进一步考察了 MCN1 对生物活性成分绿原酸的去除情况。研究结果表明,MCN1 对金银花煎剂中汞的去除率高达 80%,同时还能保持其药用成分(尤其是绿原酸)的纯度。因此,利用 MCN1 来吸附金银花煎剂中的汞(II)似乎是一种合理的方法。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Melamine-Derived Mesoporous Carbon for Efficient and Selective Removal of Trace Hg(II) from Honeysuckle Decoction

Melamine-Derived Mesoporous Carbon for Efficient and Selective Removal of Trace Hg(II) from Honeysuckle Decoction
Melamine-derived mesoporous carbon, which was obtained from pyrolysis of modified melamine, was employed for the purpose of eliminating trace amounts of Hg(II) from honeysuckle decoction. The specific surface area of the mesoporous carbons with N-functional (MCN1) was 648.372 m2·g–1. The chemical composition and morphology of MCN1 were thoroughly examined, and a comprehensive analysis led to the identification of its formation mechanism. A noteworthy association has been identified between the adsorption efficacy and the chemical composition of MCN1. In the elimination of trace mercury in aqueous solutions over a broad pH range (pH 2–9), MCN1 demonstrates high effectiveness, approaching 100%. Adsorption kinetics and isotherm results indicate that a more accurate representation of Hg(II) adsorption on MCN1 is provided by pseudo-second-order kinetics and Freundlich models, with chemical adsorption being the dominant mechanism. This study further examined the removal of chlorogenic acid, a bioactive component, by MCN1. The findings imply that MCN1 has a noteworthy 80% efficacy in removing mercury from honeysuckle decoction while maintaining the purity of its medicinal ingredients, particularly chlorogenic acid. As a result, utilizing MCN1 for the adsorption of Hg(II) in honeysuckle decoction appears to be a reasonable approach.
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来源期刊
ACS Omega
ACS Omega Chemical Engineering-General Chemical Engineering
CiteScore
6.60
自引率
4.90%
发文量
3945
审稿时长
2.4 months
期刊介绍: ACS Omega is an open-access global publication for scientific articles that describe new findings in chemistry and interfacing areas of science, without any perceived evaluation of immediate impact.
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