海水混合胶凝材料受硫酸盐侵蚀的降解机理

IF 10.8 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY
Yamei Cai , Xiaohong Zhu , Keke Sun , Kesheng Yin , Dongxing Xuan , Chi Sun Poon
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引用次数: 0

摘要

本研究主要基于微观结构观察,比较了去离子水(DI)和海水(SW)混合水泥基材料的抗硫酸盐性能。结果表明,在 50 克/升 Na2SO4 溶液中暴露 450 天后,去离子水和海水混合浆料的 C-S-H 凝胶中剩余硅酸盐链的平均链长和聚合度在距离暴露表面 0 - 2 毫米的深度都有所增加。值得注意的是,在深度大于 0.3 毫米的 SW 混合浆料中,C-S-H 凝胶的钙浸出量略低于 DI 混合浆料,尽管在深度为 0.1 毫米时两种样品中的钙浸出量相当。就铝酸盐相而言,在 50 g/L Na2SO4 溶液中浸泡不同时间后,SW 混合 C3A 砂浆的质量损失和长度变化均低于 DI 混合 C3A 砂浆。由此看来,SW-混合的 C3A 基质中可以容纳更多的膨胀产物。因此,在 SW 混合砂浆中观察到的石膏沉积裂缝少于 DI 混合砂浆。因此,在 450 d 的硫酸盐侵蚀时间内,SW-混合砂浆的抗压强度损失相对较小。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Degradation mechanism of seawater-mixed cementitious material subjecting to sulphate attack
This study compared the sulphate resistance of deionized water (DI)- and seawater (SW)-mixed cementitious materials based mainly on microstructural observations. The results show that, after a 450-day exposure to 50 g/L Na2SO4 solution, there was an increase in the mean chain length and polymerization degree of the remaining silicate chains in C-S-H gel for both DI- and SW-mixed pastes at a depth of 0–2 mm from the exposed surface. Notably, the Ca leaching of C-S-H gel in the SW-mixed paste at depths larger than 0.3 mm was slightly less than that in the DI-mixed one, despite the Ca leaching in both samples was comparable at a depth of 0.1 mm. For the aluminate phase, the mass loss and length change of the SW-mixed C3A mortar were lower than that of the DI-mixed C3A mortar, after immersing in 50 g/L Na2SO4 solution at different times. It seemed that more expansive product can be accommodated in the SW-mixed C3A matrix. Consequently, fewer cracks deposited by gypsum were observed in SW-mixed paste than in DI-mixed paste. The above were responsible for relatively less compressive strength loss of the SW-mixed mortars suffering from sulphate attack for 450 d.
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来源期刊
Cement & concrete composites
Cement & concrete composites 工程技术-材料科学:复合
CiteScore
18.70
自引率
11.40%
发文量
459
审稿时长
65 days
期刊介绍: Cement & concrete composites focuses on advancements in cement-concrete composite technology and the production, use, and performance of cement-based construction materials. It covers a wide range of materials, including fiber-reinforced composites, polymer composites, ferrocement, and those incorporating special aggregates or waste materials. Major themes include microstructure, material properties, testing, durability, mechanics, modeling, design, fabrication, and practical applications. The journal welcomes papers on structural behavior, field studies, repair and maintenance, serviceability, and sustainability. It aims to enhance understanding, provide a platform for unconventional materials, promote low-cost energy-saving materials, and bridge the gap between materials science, engineering, and construction. Special issues on emerging topics are also published to encourage collaboration between materials scientists, engineers, designers, and fabricators.
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