{"title":"聚(丙烯酸-乙烯基苄基氯)功能化表面上的高导电性均匀 PEDOT","authors":"Kurtuluş Yılmaz , Mustafa Karaman","doi":"10.1016/j.surfin.2024.105320","DOIUrl":null,"url":null,"abstract":"<div><div>This study demonstrates increasing the uniformity and conductivity of poly(3,4-ethylene dioxythiophene) (PEDOT) thin films synthesized by vapor phase polymerization (VPP) through the utilization of a thin interfacial prime layer on the substrate surface. The prime layer, which is a copolymer of acrylic acid (AA) and vinylbenzyl chloride (VBC), was coated on the substrate surface using initiated chemical vapor deposition (iCVD) method. FTIR and XPS were used to analyze the structure of as-deposited films. The use of P(AA-VBC) copolymer as a prime layer allowed uniform and complete coverage of the oxidant solution on the substrate surface due to the hydrophilic nature of the AA constituent. During the VPP, the existence of the chlorine ions originating from the VBC constituent allowed in-situ doping of the as-deposited polymer, which contributes to the increased uniformity and the conductivity. The experimental studies were carried out to show the increase in uniformity, conductivity and adherence of the as-deposited PEDOT film in the presence of the prime layer. There was nearly a 4-fold increase in the conductivity of as-deposited PEDOT in the presence of the prime layer, with measured conductivity uniformity as high as 96% over a 5×5 cm<sup>2</sup> glass surface.</div></div>","PeriodicalId":22081,"journal":{"name":"Surfaces and Interfaces","volume":"55 ","pages":"Article 105320"},"PeriodicalIF":5.7000,"publicationDate":"2024-10-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Highly conductive and uniform PEDOT on poly(acrylic acid-vinylbenzyl chloride) functionalized surfaces\",\"authors\":\"Kurtuluş Yılmaz , Mustafa Karaman\",\"doi\":\"10.1016/j.surfin.2024.105320\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>This study demonstrates increasing the uniformity and conductivity of poly(3,4-ethylene dioxythiophene) (PEDOT) thin films synthesized by vapor phase polymerization (VPP) through the utilization of a thin interfacial prime layer on the substrate surface. The prime layer, which is a copolymer of acrylic acid (AA) and vinylbenzyl chloride (VBC), was coated on the substrate surface using initiated chemical vapor deposition (iCVD) method. FTIR and XPS were used to analyze the structure of as-deposited films. The use of P(AA-VBC) copolymer as a prime layer allowed uniform and complete coverage of the oxidant solution on the substrate surface due to the hydrophilic nature of the AA constituent. During the VPP, the existence of the chlorine ions originating from the VBC constituent allowed in-situ doping of the as-deposited polymer, which contributes to the increased uniformity and the conductivity. The experimental studies were carried out to show the increase in uniformity, conductivity and adherence of the as-deposited PEDOT film in the presence of the prime layer. There was nearly a 4-fold increase in the conductivity of as-deposited PEDOT in the presence of the prime layer, with measured conductivity uniformity as high as 96% over a 5×5 cm<sup>2</sup> glass surface.</div></div>\",\"PeriodicalId\":22081,\"journal\":{\"name\":\"Surfaces and Interfaces\",\"volume\":\"55 \",\"pages\":\"Article 105320\"},\"PeriodicalIF\":5.7000,\"publicationDate\":\"2024-10-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Surfaces and Interfaces\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2468023024014767\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Surfaces and Interfaces","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2468023024014767","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Highly conductive and uniform PEDOT on poly(acrylic acid-vinylbenzyl chloride) functionalized surfaces
This study demonstrates increasing the uniformity and conductivity of poly(3,4-ethylene dioxythiophene) (PEDOT) thin films synthesized by vapor phase polymerization (VPP) through the utilization of a thin interfacial prime layer on the substrate surface. The prime layer, which is a copolymer of acrylic acid (AA) and vinylbenzyl chloride (VBC), was coated on the substrate surface using initiated chemical vapor deposition (iCVD) method. FTIR and XPS were used to analyze the structure of as-deposited films. The use of P(AA-VBC) copolymer as a prime layer allowed uniform and complete coverage of the oxidant solution on the substrate surface due to the hydrophilic nature of the AA constituent. During the VPP, the existence of the chlorine ions originating from the VBC constituent allowed in-situ doping of the as-deposited polymer, which contributes to the increased uniformity and the conductivity. The experimental studies were carried out to show the increase in uniformity, conductivity and adherence of the as-deposited PEDOT film in the presence of the prime layer. There was nearly a 4-fold increase in the conductivity of as-deposited PEDOT in the presence of the prime layer, with measured conductivity uniformity as high as 96% over a 5×5 cm2 glass surface.
期刊介绍:
The aim of the journal is to provide a respectful outlet for ''sound science'' papers in all research areas on surfaces and interfaces. We define sound science papers as papers that describe new and well-executed research, but that do not necessarily provide brand new insights or are merely a description of research results.
Surfaces and Interfaces publishes research papers in all fields of surface science which may not always find the right home on first submission to our Elsevier sister journals (Applied Surface, Surface and Coatings Technology, Thin Solid Films)