{"title":"阳离子 13 族和 14 族元素簇。","authors":"Antoine Barthélemy, Ingo Krossing","doi":"10.1021/acs.inorgchem.4c03251","DOIUrl":null,"url":null,"abstract":"<p><p>Anionic and neutral clusters dominate the cluster chemistry of group 13 and 14 elements, many of which have become classic textbook examples of main group element clusters. However, facilitated by the development of unreactive, weakly coordinating anions, the number of known group 13 and 14 cationic cluster compounds has risen rapidly in recent years. Hence, this review aims to give an overview over this research field, which arouses increasing interest owing to the often unusual structures of the cationic clusters, as well as their application in bond activation chemistry. Challenges of the cluster formation are discussed and suitable starting materials are presented, as well as syntheses, structures and the rich follow-up chemistry of (also mixed) group 13 and 14 cluster cations.</p>","PeriodicalId":40,"journal":{"name":"Inorganic Chemistry","volume":" ","pages":"21763-21787"},"PeriodicalIF":4.7000,"publicationDate":"2024-11-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Cationic Group 13 and 14 Element Clusters.\",\"authors\":\"Antoine Barthélemy, Ingo Krossing\",\"doi\":\"10.1021/acs.inorgchem.4c03251\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>Anionic and neutral clusters dominate the cluster chemistry of group 13 and 14 elements, many of which have become classic textbook examples of main group element clusters. However, facilitated by the development of unreactive, weakly coordinating anions, the number of known group 13 and 14 cationic cluster compounds has risen rapidly in recent years. Hence, this review aims to give an overview over this research field, which arouses increasing interest owing to the often unusual structures of the cationic clusters, as well as their application in bond activation chemistry. Challenges of the cluster formation are discussed and suitable starting materials are presented, as well as syntheses, structures and the rich follow-up chemistry of (also mixed) group 13 and 14 cluster cations.</p>\",\"PeriodicalId\":40,\"journal\":{\"name\":\"Inorganic Chemistry\",\"volume\":\" \",\"pages\":\"21763-21787\"},\"PeriodicalIF\":4.7000,\"publicationDate\":\"2024-11-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Inorganic Chemistry\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1021/acs.inorgchem.4c03251\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2024/11/1 0:00:00\",\"PubModel\":\"Epub\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganic Chemistry","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1021/acs.inorgchem.4c03251","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2024/11/1 0:00:00","PubModel":"Epub","JCR":"Q1","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Anionic and neutral clusters dominate the cluster chemistry of group 13 and 14 elements, many of which have become classic textbook examples of main group element clusters. However, facilitated by the development of unreactive, weakly coordinating anions, the number of known group 13 and 14 cationic cluster compounds has risen rapidly in recent years. Hence, this review aims to give an overview over this research field, which arouses increasing interest owing to the often unusual structures of the cationic clusters, as well as their application in bond activation chemistry. Challenges of the cluster formation are discussed and suitable starting materials are presented, as well as syntheses, structures and the rich follow-up chemistry of (also mixed) group 13 and 14 cluster cations.
期刊介绍：
Inorganic Chemistry publishes fundamental studies in all phases of inorganic chemistry. Coverage includes experimental and theoretical reports on quantitative studies of structure and thermodynamics, kinetics, mechanisms of inorganic reactions, bioinorganic chemistry, and relevant aspects of organometallic chemistry, solid-state phenomena, and chemical bonding theory. Emphasis is placed on the synthesis, structure, thermodynamics, reactivity, spectroscopy, and bonding properties of significant new and known compounds.
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