影响铕络合物阴极发光强度的关键因素是什么?

IF 4.3 3区 材料科学 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC
Rongdeng Lu, Tinghui Xuan, Alexander S Goloveshkin, Dmitry Kopytov, Kseniia Orekhova, Ivan Khanbekov, Valentina V. Utochnikova
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引用次数: 0

摘要

为了用带有有机配体的配位化合物来替代已被充分研究但难以沉积的无机阴极发光(CL)化合物,最重要的是建立 CL 与光致发光的相关性,以及提高 CL 的强度。本文研究了铕的同配体和混合配体 1,4-对苯二甲酸盐和萘-2,6-羧酸盐,包括新型配体,并确定了其中一种配体(Eu2(nda)3(BPhen)2)的晶体结构。在快速电子的激发下,它们显示出不同强度的发光,这是 Eu3+ 的特征。在未达到饱和状态时,发光强度与 PLQY 相关,而在饱和状态时,发光强度与 PLQY/τ 相关。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
What is the key factor affecting the cathodoluminescence intensity of europium complexes?
In order to substitute well-studied, but hard-to-deposit inorganic cathodoluminescent (CL) compounds with coordination compounds with organic ligands, its is primarily important to establish CL correlation to photoluminescence, as well as to increase the CL intensity. In the present paper it was studied for homo- and mixed-ligand 1,4-terephthalates and naphthalene-2,6-carboxylates of europium, including novel, for one of which (Eu2(nda)3(BPhen)2) the crystal structure was determined. They were found to display luminescence of various intensities under excitation by fast electrons, characteristic for Eu3+. CL intensity correlated with PLQY, when saturation regime was not reached, and with PLQY/τ in saturation regime.
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来源期刊
CiteScore
7.20
自引率
4.30%
发文量
567
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