{"title":"催化转化二氧化碳的新兴二维 MXene 量子点","authors":"Nadeem Hussain Solangi , Lakshmi Prasanna Lingamdinne , Rama Rao Karri , Nabisab Mujawar Mubarak , Shaukat Ali Mazari , Janardhan Reddy Koduru","doi":"10.1016/j.carbon.2024.119758","DOIUrl":null,"url":null,"abstract":"<div><div>MXene is an emerging material for converting carbon dioxide (CO<sub>2</sub>) into valuable products because of its robust physical and chemical properties. The high specific surface area (SSA), conductivity, and stability of the MXene make it an attractive material for the catalytic conversion of CO<sub>2</sub>. The pristine MXene possessed poor catalytic properties as compared to their composites. This study briefly discussed the magical properties and advanced synthesizing routes of MXene and MXene quantum dots (MQDs). In addition, the oxidation of the MXene is responsible for altering its chemical composition, and the factors used to oxidize the MXene were discussed in detail. Furthermore, the mechanism of hydrogenation, chemical, electrocatalytic, and photocatalytic reduction of CO<sub>2</sub> has been discussed. Finally, the MXene quantum dots (MQDs) for photocatalytic conversion of CO<sub>2</sub> for the first time also present the future challenges and prospectus associated with MXene.</div></div>","PeriodicalId":262,"journal":{"name":"Carbon","volume":"232 ","pages":"Article 119758"},"PeriodicalIF":10.5000,"publicationDate":"2024-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Emerging 2D MXene quantum dots for catalytic conversion of CO2\",\"authors\":\"Nadeem Hussain Solangi , Lakshmi Prasanna Lingamdinne , Rama Rao Karri , Nabisab Mujawar Mubarak , Shaukat Ali Mazari , Janardhan Reddy Koduru\",\"doi\":\"10.1016/j.carbon.2024.119758\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>MXene is an emerging material for converting carbon dioxide (CO<sub>2</sub>) into valuable products because of its robust physical and chemical properties. The high specific surface area (SSA), conductivity, and stability of the MXene make it an attractive material for the catalytic conversion of CO<sub>2</sub>. The pristine MXene possessed poor catalytic properties as compared to their composites. This study briefly discussed the magical properties and advanced synthesizing routes of MXene and MXene quantum dots (MQDs). In addition, the oxidation of the MXene is responsible for altering its chemical composition, and the factors used to oxidize the MXene were discussed in detail. Furthermore, the mechanism of hydrogenation, chemical, electrocatalytic, and photocatalytic reduction of CO<sub>2</sub> has been discussed. Finally, the MXene quantum dots (MQDs) for photocatalytic conversion of CO<sub>2</sub> for the first time also present the future challenges and prospectus associated with MXene.</div></div>\",\"PeriodicalId\":262,\"journal\":{\"name\":\"Carbon\",\"volume\":\"232 \",\"pages\":\"Article 119758\"},\"PeriodicalIF\":10.5000,\"publicationDate\":\"2024-10-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Carbon\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0008622324009771\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Carbon","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0008622324009771","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Emerging 2D MXene quantum dots for catalytic conversion of CO2
MXene is an emerging material for converting carbon dioxide (CO2) into valuable products because of its robust physical and chemical properties. The high specific surface area (SSA), conductivity, and stability of the MXene make it an attractive material for the catalytic conversion of CO2. The pristine MXene possessed poor catalytic properties as compared to their composites. This study briefly discussed the magical properties and advanced synthesizing routes of MXene and MXene quantum dots (MQDs). In addition, the oxidation of the MXene is responsible for altering its chemical composition, and the factors used to oxidize the MXene were discussed in detail. Furthermore, the mechanism of hydrogenation, chemical, electrocatalytic, and photocatalytic reduction of CO2 has been discussed. Finally, the MXene quantum dots (MQDs) for photocatalytic conversion of CO2 for the first time also present the future challenges and prospectus associated with MXene.
期刊介绍:
The journal Carbon is an international multidisciplinary forum for communicating scientific advances in the field of carbon materials. It reports new findings related to the formation, structure, properties, behaviors, and technological applications of carbons. Carbons are a broad class of ordered or disordered solid phases composed primarily of elemental carbon, including but not limited to carbon black, carbon fibers and filaments, carbon nanotubes, diamond and diamond-like carbon, fullerenes, glassy carbon, graphite, graphene, graphene-oxide, porous carbons, pyrolytic carbon, and other sp2 and non-sp2 hybridized carbon systems. Carbon is the companion title to the open access journal Carbon Trends. Relevant application areas for carbon materials include biology and medicine, catalysis, electronic, optoelectronic, spintronic, high-frequency, and photonic devices, energy storage and conversion systems, environmental applications and water treatment, smart materials and systems, and structural and thermal applications.