Ting Xiong, Bowen Zheng, Keding Li, Lin Zhang, Shuai Zhang
{"title":"十六烷基三甲基溴化铵改性蒙脱石-羟基磷灰石复合吸附剂对水溶液中铀(VI)的吸附行为","authors":"Ting Xiong, Bowen Zheng, Keding Li, Lin Zhang, Shuai Zhang","doi":"10.1016/j.clay.2024.107609","DOIUrl":null,"url":null,"abstract":"<div><div>In this task, a novel montmorillonite composite (CMH) was successfully prepared by surfactant modifying with cetyltrimethylammonium bromide (CTAB) and compounding with hydroxyapatite (HAP). In contrast to nature montmorillonite (MMT), CMH showed better U(VI) adsorption properties (<em>R</em> > 99 %) in a wide adsorbent dose range (0.2 to 1.0 mg/L) with the initial U(VI) concentration of 10 mg/L at pH = 5.0 and <em>T</em> = 298 K. The adsorption capacity of CMH for U(VI) reached 678.6 mg/g, which was much higher than most of reported clay-based adsorbents, suggesting that the adsorption performances of CMH were at the upper-middle level among clay-based adsorbents. In addition, CMH also performed good recoverability with the adsorption efficiency of 96.2 % after five cycles and could still maintain relatively high U(VI) adsorption capacity even during complex water system, which was expected to be used for adsorbing U(VI) from various water environment. In terms of the differences in morphology, structure and composition between MMT and CMH, the excellent U(VI) adsorption performances of CMH could be explained by the rougher surface, larger interlayer spacing and more pores and functional groups, thus providing more binding sites. The adsorption mechanism involved electrostatic interaction, ion exchange and complexation. This job supplied a novel opinion for the explore of low cost and highly efficient adsorbent synthesis for U(VI) adsorption.</div></div>","PeriodicalId":245,"journal":{"name":"Applied Clay Science","volume":"262 ","pages":"Article 107609"},"PeriodicalIF":5.3000,"publicationDate":"2024-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Adsorption behaviors of U(VI) in aqueous solution by cetyltrimethylammonium bromide modified montmorillonite-hydroxyapatite composite adsorbent\",\"authors\":\"Ting Xiong, Bowen Zheng, Keding Li, Lin Zhang, Shuai Zhang\",\"doi\":\"10.1016/j.clay.2024.107609\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>In this task, a novel montmorillonite composite (CMH) was successfully prepared by surfactant modifying with cetyltrimethylammonium bromide (CTAB) and compounding with hydroxyapatite (HAP). In contrast to nature montmorillonite (MMT), CMH showed better U(VI) adsorption properties (<em>R</em> > 99 %) in a wide adsorbent dose range (0.2 to 1.0 mg/L) with the initial U(VI) concentration of 10 mg/L at pH = 5.0 and <em>T</em> = 298 K. The adsorption capacity of CMH for U(VI) reached 678.6 mg/g, which was much higher than most of reported clay-based adsorbents, suggesting that the adsorption performances of CMH were at the upper-middle level among clay-based adsorbents. In addition, CMH also performed good recoverability with the adsorption efficiency of 96.2 % after five cycles and could still maintain relatively high U(VI) adsorption capacity even during complex water system, which was expected to be used for adsorbing U(VI) from various water environment. In terms of the differences in morphology, structure and composition between MMT and CMH, the excellent U(VI) adsorption performances of CMH could be explained by the rougher surface, larger interlayer spacing and more pores and functional groups, thus providing more binding sites. The adsorption mechanism involved electrostatic interaction, ion exchange and complexation. This job supplied a novel opinion for the explore of low cost and highly efficient adsorbent synthesis for U(VI) adsorption.</div></div>\",\"PeriodicalId\":245,\"journal\":{\"name\":\"Applied Clay Science\",\"volume\":\"262 \",\"pages\":\"Article 107609\"},\"PeriodicalIF\":5.3000,\"publicationDate\":\"2024-10-31\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Applied Clay Science\",\"FirstCategoryId\":\"89\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0169131724003570\",\"RegionNum\":2,\"RegionCategory\":\"地球科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Clay Science","FirstCategoryId":"89","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0169131724003570","RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Adsorption behaviors of U(VI) in aqueous solution by cetyltrimethylammonium bromide modified montmorillonite-hydroxyapatite composite adsorbent
In this task, a novel montmorillonite composite (CMH) was successfully prepared by surfactant modifying with cetyltrimethylammonium bromide (CTAB) and compounding with hydroxyapatite (HAP). In contrast to nature montmorillonite (MMT), CMH showed better U(VI) adsorption properties (R > 99 %) in a wide adsorbent dose range (0.2 to 1.0 mg/L) with the initial U(VI) concentration of 10 mg/L at pH = 5.0 and T = 298 K. The adsorption capacity of CMH for U(VI) reached 678.6 mg/g, which was much higher than most of reported clay-based adsorbents, suggesting that the adsorption performances of CMH were at the upper-middle level among clay-based adsorbents. In addition, CMH also performed good recoverability with the adsorption efficiency of 96.2 % after five cycles and could still maintain relatively high U(VI) adsorption capacity even during complex water system, which was expected to be used for adsorbing U(VI) from various water environment. In terms of the differences in morphology, structure and composition between MMT and CMH, the excellent U(VI) adsorption performances of CMH could be explained by the rougher surface, larger interlayer spacing and more pores and functional groups, thus providing more binding sites. The adsorption mechanism involved electrostatic interaction, ion exchange and complexation. This job supplied a novel opinion for the explore of low cost and highly efficient adsorbent synthesis for U(VI) adsorption.
期刊介绍:
Applied Clay Science aims to be an international journal attracting high quality scientific papers on clays and clay minerals, including research papers, reviews, and technical notes. The journal covers typical subjects of Fundamental and Applied Clay Science such as:
• Synthesis and purification
• Structural, crystallographic and mineralogical properties of clays and clay minerals
• Thermal properties of clays and clay minerals
• Physico-chemical properties including i) surface and interface properties; ii) thermodynamic properties; iii) mechanical properties
• Interaction with water, with polar and apolar molecules
• Colloidal properties and rheology
• Adsorption, Intercalation, Ionic exchange
• Genesis and deposits of clay minerals
• Geology and geochemistry of clays
• Modification of clays and clay minerals properties by thermal and physical treatments
• Modification by chemical treatments with organic and inorganic molecules(organoclays, pillared clays)
• Modification by biological microorganisms. etc...