铜催化机械化学法通过氧化胺化原生亚磺酰胺合成 NH-磺酰亚胺类化合物

IF 7.3 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

ACS Sustainable Chemistry & Engineering Pub Date : 2024-10-15 DOI:10.1021/acssuschemeng.4c0437710.1021/acssuschemeng.4c04377

Peng Wu, Li Ling, Yijie Hu, Shulei Pan and Carsten Bolm*,

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引用次数: 0

摘要

我们开发了一种铜催化的机械化学氧化氨基化初级亚磺酰胺的方法，可在无溶剂条件下以中等至良好的产率获得 NH-磺酰亚胺。空气可作为终端氧化剂，无需外加添加剂。所获得的产品可以很容易地转化为无环和环磺酰亚胺衍生物。与基于溶剂的方法相比，这种机械化学方法具有相当大的生态效益。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Mechanochemical Copper-Catalyzed Synthesis of NH-Sulfonimidamides by Oxidative Amination of Primary Sulfinamides

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Mechanochemical Copper-Catalyzed Synthesis of NH-Sulfonimidamides by Oxidative Amination of Primary Sulfinamides

A mechanochemical copper-catalyzed oxidative amination of primary sulfinamides has been developed, leading to NH-sulfonimidamides in moderate to good yields under solvent-free conditions. Air serves as a terminal oxidant without the need for external additives. The obtained products could be readily converted into both acyclic and cyclic sulfonimidamide derivatives. This mechanochemical approach demonstrates considerable ecological benefits compared to solvent-based methods.

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来源期刊

ACS Sustainable Chemistry & Engineering CHEMISTRY, MULTIDISCIPLINARY-ENGINEERING, CHEMICAL

CiteScore

13.80

自引率

4.80%

发文量

1470

审稿时长

1.7 months

期刊介绍： ACS Sustainable Chemistry & Engineering is a prestigious weekly peer-reviewed scientific journal published by the American Chemical Society. Dedicated to advancing the principles of green chemistry and green engineering, it covers a wide array of research topics including green chemistry, green engineering, biomass, alternative energy, and life cycle assessment. The journal welcomes submissions in various formats, including Letters, Articles, Features, and Perspectives (Reviews), that address the challenges of sustainability in the chemical enterprise and contribute to the advancement of sustainable practices. Join us in shaping the future of sustainable chemistry and engineering.