煤气化细渣流化熔融燃烧中试规模试验。

IF 7.1 2区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL
Shuai Guo , Chen Liang , Zhiyong Chen , Wei Li , Qiangqiang Ren
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引用次数: 0

摘要

为解决煤气化细渣(CGFS)处置问题,提出了一种新型流化熔融燃烧(FMC)工艺。本研究通过 0.4 兆瓦中试规模的试验,评估了该工艺的操作可行性、燃烧性能和气体污染物排放。结果表明,在整个试验期间,温度和压力波动均保持在可控范围内。在高循环速率和不完全燃烧的影响下,CGFS 有效地实现了快速脱水、预热和破碎。同时产生了一些可燃的 H2 和 CO。经过预热改性后,难燃的 CGFS 变成了热气固复合燃料。为了实现完全除碳和灰烬玻璃化,熔化燃烧温度高达 1501.1 ℃。在过高的温度下,液态炉渣顺利地从出渣孔排出,未发现任何堵塞现象。熔渣中的碳含量仅为 0.4 wt%。炉渣捕集率和脱碳率分别高达 79.0 % 和 93.8 %。初始 CO 排放量低至 103.0 mg/m3。在辐射锅炉后燃烧条件下,初始 NO 排放量高达 452.5 mg/m3。在多种因素的综合影响下,二氧化硫的初始排放量飙升至 1789.3 毫克/立方米。进一步的研究将集中在控制烟气污染物排放、熔融炉渣的资源化利用以及发展全氧燃烧等方面。目标是实现煤化工全过程的碳中和。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
A pilot scale test on the fluidized melting combustion of coal gasification fine slag
To address the issue of coal gasification fine slag (CGFS) disposal, a novel fluidized melting combustion (FMC) process has been proposed. In this study, the operating feasibility, combustion performance and gas pollutant emission were assessed through 0.4 MW pilot-scale test. The results indicated that both temperature and pressure fluctuation remained within the controllable range throughout entire test period. Under the influence of high cycle rate and incomplete combustion, CGFS efficiently achieved the rapid dehydration, preheating and crushing. Some combustible H2 and CO were generated simultaneously. After the preheating modification, the refractory CGFS transformed into hot gas–solid composite fuel. To achieve the complete carbon removal and ash vitrification, the melting combustion temperature was up to 1501.1 °C. Under the excessively high temperature, liquid slag was discharged smoothly from the tap hole without any observed blockage. Carbon content in slag was only 0.4 wt%. The slag captured rate and decarbonization rate were up to 79.0 % and 93.8 %, respectively. The initial CO emission was as low as 103.0 mg/m3. The initial NO emission reached up to 452.5 mg/m3 under radiation boiler afterburning. Due to the combined influence of multiple factors, the initial SO2 emission soared up to 1789.3 mg/m3. Further research will focus on controlling flue gas pollutant emissions, resource utilization of molten slag, and developing oxy-combustion. The objective is to attain full carbon neutrality in the entire coal chemical industry process.
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来源期刊
Waste management
Waste management 环境科学-工程:环境
CiteScore
15.60
自引率
6.20%
发文量
492
审稿时长
39 days
期刊介绍: Waste Management is devoted to the presentation and discussion of information on solid wastes,it covers the entire lifecycle of solid. wastes. Scope: Addresses solid wastes in both industrialized and economically developing countries Covers various types of solid wastes, including: Municipal (e.g., residential, institutional, commercial, light industrial) Agricultural Special (e.g., C and D, healthcare, household hazardous wastes, sewage sludge)
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