Meng Zhao, Xue-Song Gu, Lanlan Sun, Yun Yang, Tong Li
{"title":"基于沸石和金属有机框架的微孔晶体材料在 C4 碳氢化合物吸附分离中的应用","authors":"Meng Zhao, Xue-Song Gu, Lanlan Sun, Yun Yang, Tong Li","doi":"10.1016/j.ccr.2024.216293","DOIUrl":null,"url":null,"abstract":"<div><div>The quest for energy-efficient and environmentally benign methods for separating C4 hydrocarbon mixtures has led to the exploration of porous materials, with zeolites and metal-organic frameworks (MOFs), especially MOFs at the forefront. These materials exhibit tunable pore sizes, diverse chemical functionalities, and the capacity for structural transformation in response to external stimuli, attributes that are highly desirable for separation processes. This review provides an in-depth analysis of the fundamental principles governing the adsorptive separation of C4 hydrocarbons, including thermodynamic, kinetic, molecular sieving, responsive framework separation, and guest conformation-controlled mechanisms. It also examines strategies to enhance the selectivity and stability of porous materials, such as the introduction of open metal sites, functional group modifications, and the engineering of flexible frameworks. The discussion extends to the current limitations and challenges in the industrial application of these materials. By synthesizing recent breakthroughs and identifying pivotal research directions, this review aims to offer a strategic roadmap for future research endeavors.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216293"},"PeriodicalIF":20.3000,"publicationDate":"2024-10-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Zeolite and metal-organic framework based microporous crystalline materials in adsorption separation of C4 hydrocarbons\",\"authors\":\"Meng Zhao, Xue-Song Gu, Lanlan Sun, Yun Yang, Tong Li\",\"doi\":\"10.1016/j.ccr.2024.216293\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The quest for energy-efficient and environmentally benign methods for separating C4 hydrocarbon mixtures has led to the exploration of porous materials, with zeolites and metal-organic frameworks (MOFs), especially MOFs at the forefront. These materials exhibit tunable pore sizes, diverse chemical functionalities, and the capacity for structural transformation in response to external stimuli, attributes that are highly desirable for separation processes. This review provides an in-depth analysis of the fundamental principles governing the adsorptive separation of C4 hydrocarbons, including thermodynamic, kinetic, molecular sieving, responsive framework separation, and guest conformation-controlled mechanisms. It also examines strategies to enhance the selectivity and stability of porous materials, such as the introduction of open metal sites, functional group modifications, and the engineering of flexible frameworks. The discussion extends to the current limitations and challenges in the industrial application of these materials. By synthesizing recent breakthroughs and identifying pivotal research directions, this review aims to offer a strategic roadmap for future research endeavors.</div></div>\",\"PeriodicalId\":289,\"journal\":{\"name\":\"Coordination Chemistry Reviews\",\"volume\":\"523 \",\"pages\":\"Article 216293\"},\"PeriodicalIF\":20.3000,\"publicationDate\":\"2024-10-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Coordination Chemistry Reviews\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0010854524006398\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Coordination Chemistry Reviews","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0010854524006398","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Zeolite and metal-organic framework based microporous crystalline materials in adsorption separation of C4 hydrocarbons
The quest for energy-efficient and environmentally benign methods for separating C4 hydrocarbon mixtures has led to the exploration of porous materials, with zeolites and metal-organic frameworks (MOFs), especially MOFs at the forefront. These materials exhibit tunable pore sizes, diverse chemical functionalities, and the capacity for structural transformation in response to external stimuli, attributes that are highly desirable for separation processes. This review provides an in-depth analysis of the fundamental principles governing the adsorptive separation of C4 hydrocarbons, including thermodynamic, kinetic, molecular sieving, responsive framework separation, and guest conformation-controlled mechanisms. It also examines strategies to enhance the selectivity and stability of porous materials, such as the introduction of open metal sites, functional group modifications, and the engineering of flexible frameworks. The discussion extends to the current limitations and challenges in the industrial application of these materials. By synthesizing recent breakthroughs and identifying pivotal research directions, this review aims to offer a strategic roadmap for future research endeavors.
期刊介绍:
Coordination Chemistry Reviews offers rapid publication of review articles on current and significant topics in coordination chemistry, encompassing organometallic, supramolecular, theoretical, and bioinorganic chemistry. It also covers catalysis, materials chemistry, and metal-organic frameworks from a coordination chemistry perspective. Reviews summarize recent developments or discuss specific techniques, welcoming contributions from both established and emerging researchers.
The journal releases special issues on timely subjects, including those featuring contributions from specific regions or conferences. Occasional full-length book articles are also featured. Additionally, special volumes cover annual reviews of main group chemistry, transition metal group chemistry, and organometallic chemistry. These comprehensive reviews are vital resources for those engaged in coordination chemistry, further establishing Coordination Chemistry Reviews as a hub for insightful surveys in inorganic and physical inorganic chemistry.