羟基氨烷基化技术实现乙烯基端聚乙烯的胺官能化，可直接获得响应性功能材料

IF 16.1 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Angewandte Chemie International Edition Pub Date : 2024-10-30 DOI:10.1002/anie.202410154

Saeed Ataie, Amir Malmir, Sabrina S. Scott, James T. Goettel, Steven N. Clemens, Darryl J. Morrison, Cyrus Mackie, Belinda Heyne, Savvas G. Hatzikiriakos, Laurel L. Schafer

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引用次数: 0

摘要

本文介绍了一种通过 100% 原子经济性钽催化乙烯基封端聚乙烯 (VTPE) 的氢氨基烷基化生产功能化聚乙烯 (PE) 的新方法。我们的方法能够在熔融阶段将胺官能团高效地加入结晶聚乙烯中，从而解决了当前的合成难题。这些功能材料具有多种潜在应用，我们在此展示的胺化聚乙烯具有更强的材料特性和 pH 值响应特性，可制成抗菌聚乙烯薄膜。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Hydroaminoalkylation for Amine Functionalization of Vinyl-Terminated Polyethylene Enables Direct Access to Responsive Functional Materials

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Hydroaminoalkylation for Amine Functionalization of Vinyl-Terminated Polyethylene Enables Direct Access to Responsive Functional Materials

This paper presents a novel method for producing functionalized polyethylenes (PEs) via a 100 % atom economic tantalum-catalyzed hydroaminoalkylation of vinyl-terminated polyethylene (VTPE). Our approach addresses current synthetic challenges by enabling the efficient incorporation of amine functionalities into crystalline PEs in the melt phase. These functional materials have diverse potential applications and here we show that aminated PEs exhibit enhanced material properties, and pH responsive properties results in antibacterial PE films.

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来源期刊

Angewandte Chemie International Edition 化学-化学综合

CiteScore

26.60

自引率

6.60%

发文量

3549

审稿时长

1.5 months

期刊介绍： Angewandte Chemie, a journal of the German Chemical Society (GDCh), maintains a leading position among scholarly journals in general chemistry with an impressive Impact Factor of 16.6 (2022 Journal Citation Reports, Clarivate, 2023). Published weekly in a reader-friendly format, it features new articles almost every day. Established in 1887, Angewandte Chemie is a prominent chemistry journal, offering a dynamic blend of Review-type articles, Highlights, Communications, and Research Articles on a weekly basis, making it unique in the field.