从光致发光和吸收光谱揭示电气绝缘油热老化的新见解

IF 4.4 2区 工程技术 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC
High Voltage Pub Date : 2024-09-20 DOI:10.1049/hve2.12482
Hesham S. Karaman, Eman G. Atiya, Diaa-Eldin A. Mansour, Mohsen Ghali, Z. M. S. Elbarbary, Manal M. Emara
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引用次数: 0

摘要

最近,出于安全和环境问题的考虑,人们一直在努力用环保型油类取代矿物油。然而,有必要澄清这些油类老化影响背后的物理机制。作者利用先进的光学光谱技术和介电测量方法来了解环保油和矿物油的老化过程。首先,利用不同的环保油和矿物油样品来研究老化机制。使用热加速老化工艺对这些样品进行了不同的老化处理。其次,根据代表宏观和微观类别的几种测量特性,研究了油降解产生的副产品的严重程度。宏观类别通过介电特性进行评估,包括击穿电压、介电常数和耗散因子。而微观类别则通过紫外可见吸收光谱和光致发光光谱等技术进行评估。这些技术有助于深入了解油类在老化条件下发生的分子级变化,从而对油类老化机制有新的认识。值得一提的是,天然酯油在老化条件下的各种性能表现最为优异。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

New insights on thermal ageing of electrical insulating oils as revealed from photoluminescence and absorption spectroscopy

New insights on thermal ageing of electrical insulating oils as revealed from photoluminescence and absorption spectroscopy

Recently, significant efforts have been exerted to replace mineral oil with environmentally friendly oils due to safety and environmental issues. However, there is a need to clarify the physical mechanisms behind the ageing impact of these oils. The authors use advanced optical spectroscopy techniques in correlation with dielectric measurements to understand the ageing processes in environmentally friendly oils as well as mineral oil. Firstly, different samples of environmentally friendly oils and mineral oil were utilised to investigate the ageing mechanism. The samples were subjected to different ageing periods using a thermal accelerated ageing process. Secondly, the severity of the produced byproducts due to the oil degradation is examined based on several measured properties representing macroscopic and microscopic categories. The macroscopic category was evaluated through dielectric properties, including breakdown voltage, dielectric permittivity, and dissipation factor. The microscopic category, on the other hand, was assessed using techniques such as ultraviolet–visible absorption spectroscopy and photoluminescence spectroscopy. These techniques enabled a deep understanding of the molecular-level changes occurring in the oil under ageing conditions, thereby getting new insights into oil ageing mechanisms. It is worth mentioning that natural ester oil demonstrated the most favourable performance across various properties under ageing conditions.

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来源期刊
High Voltage
High Voltage Energy-Energy Engineering and Power Technology
CiteScore
9.60
自引率
27.30%
发文量
97
审稿时长
21 weeks
期刊介绍: High Voltage aims to attract original research papers and review articles. The scope covers high-voltage power engineering and high voltage applications, including experimental, computational (including simulation and modelling) and theoretical studies, which include: Electrical Insulation ● Outdoor, indoor, solid, liquid and gas insulation ● Transient voltages and overvoltage protection ● Nano-dielectrics and new insulation materials ● Condition monitoring and maintenance Discharge and plasmas, pulsed power ● Electrical discharge, plasma generation and applications ● Interactions of plasma with surfaces ● Pulsed power science and technology High-field effects ● Computation, measurements of Intensive Electromagnetic Field ● Electromagnetic compatibility ● Biomedical effects ● Environmental effects and protection High Voltage Engineering ● Design problems, testing and measuring techniques ● Equipment development and asset management ● Smart Grid, live line working ● AC/DC power electronics ● UHV power transmission Special Issues. Call for papers: Interface Charging Phenomena for Dielectric Materials - https://digital-library.theiet.org/files/HVE_CFP_ICP.pdf Emerging Materials For High Voltage Applications - https://digital-library.theiet.org/files/HVE_CFP_EMHVA.pdf
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