A. Ashothaman, J. Sudha, N. Senthilkumar, K. Palanikumar
{"title":"评估用香根草切碎纤维和珍珠粟衍生纳米二氧化硅增强的聚乳酸聚合物复合材料对环境可持续性的影响","authors":"A. Ashothaman, J. Sudha, N. Senthilkumar, K. Palanikumar","doi":"10.1007/s10965-024-04184-0","DOIUrl":null,"url":null,"abstract":"<div><p>In search of lightweight materials, polymer (biodegradable) composites are considered across the globe in engineering applications that suit their requirements towards environmental sustainability. In this study, the biodegradable polylactic acid (PLA) based polymer composite is fabricated by reinforcing chopped vetiver fibers (VFs) of varying proportions of weight (5, 10, 15, 20 and 25 wt.%) along with 2 wt.% addition of nano-silica (nSiO<sub>2</sub>) derived from pearl millet using injection moulding. The fabricated PLA + VF composite is characterized by its mechanical, wear and thermal behaviour as per ASTM guidelines. Micrographs show an even distribution of nSiO<sub>2</sub> and chopped VFs in the PLA matrix which can impact the properties of composite. Results show that, with the inclusion of VFs in the PLA matrix the density and porosity increase proportionally. Similarly tensile, impact and flexural strength increases until 20 wt.% addition, afterwards a decreasing trend is observed due to poor interfacial bonding of fibers with the matrix. Water absorption nature decreases with the inclusion of nSiO<sub>2</sub>, but increases with the inclusion of VFs. The heat deflection temperature of PLA + nSiO<sub>2</sub> + VF increases whereas the coefficient of linear thermal expansion decreases with the inclusion of VFs till 20 wt.%. Wear resistance gets improved due to the incorporation of nSiO<sub>2</sub> and VFs which possess certain self-lubricating properties. Thermal gravimetry analysis (TGA) and differential scanning calorimetry (DSC) assessments exposed that, the addition of VF (20 wt.%) and nSiO<sub>2</sub> increases the heat-withstanding capability as the matrix softening occurs in the 57°C-80.7°C range, with a heating value of 99.4°C, the residual mass obtained is 99.6%.</p></div>","PeriodicalId":658,"journal":{"name":"Journal of Polymer Research","volume":null,"pages":null},"PeriodicalIF":2.6000,"publicationDate":"2024-10-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Evaluation of polylactic acid polymer composites strengthened with chopped vetiver fiber and pearl millet-derived- nano silica towards environmental sustainability\",\"authors\":\"A. Ashothaman, J. Sudha, N. Senthilkumar, K. Palanikumar\",\"doi\":\"10.1007/s10965-024-04184-0\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>In search of lightweight materials, polymer (biodegradable) composites are considered across the globe in engineering applications that suit their requirements towards environmental sustainability. In this study, the biodegradable polylactic acid (PLA) based polymer composite is fabricated by reinforcing chopped vetiver fibers (VFs) of varying proportions of weight (5, 10, 15, 20 and 25 wt.%) along with 2 wt.% addition of nano-silica (nSiO<sub>2</sub>) derived from pearl millet using injection moulding. The fabricated PLA + VF composite is characterized by its mechanical, wear and thermal behaviour as per ASTM guidelines. Micrographs show an even distribution of nSiO<sub>2</sub> and chopped VFs in the PLA matrix which can impact the properties of composite. Results show that, with the inclusion of VFs in the PLA matrix the density and porosity increase proportionally. Similarly tensile, impact and flexural strength increases until 20 wt.% addition, afterwards a decreasing trend is observed due to poor interfacial bonding of fibers with the matrix. Water absorption nature decreases with the inclusion of nSiO<sub>2</sub>, but increases with the inclusion of VFs. The heat deflection temperature of PLA + nSiO<sub>2</sub> + VF increases whereas the coefficient of linear thermal expansion decreases with the inclusion of VFs till 20 wt.%. Wear resistance gets improved due to the incorporation of nSiO<sub>2</sub> and VFs which possess certain self-lubricating properties. Thermal gravimetry analysis (TGA) and differential scanning calorimetry (DSC) assessments exposed that, the addition of VF (20 wt.%) and nSiO<sub>2</sub> increases the heat-withstanding capability as the matrix softening occurs in the 57°C-80.7°C range, with a heating value of 99.4°C, the residual mass obtained is 99.6%.</p></div>\",\"PeriodicalId\":658,\"journal\":{\"name\":\"Journal of Polymer Research\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.6000,\"publicationDate\":\"2024-10-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Polymer Research\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10965-024-04184-0\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Polymer Research","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10965-024-04184-0","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
Evaluation of polylactic acid polymer composites strengthened with chopped vetiver fiber and pearl millet-derived- nano silica towards environmental sustainability
In search of lightweight materials, polymer (biodegradable) composites are considered across the globe in engineering applications that suit their requirements towards environmental sustainability. In this study, the biodegradable polylactic acid (PLA) based polymer composite is fabricated by reinforcing chopped vetiver fibers (VFs) of varying proportions of weight (5, 10, 15, 20 and 25 wt.%) along with 2 wt.% addition of nano-silica (nSiO2) derived from pearl millet using injection moulding. The fabricated PLA + VF composite is characterized by its mechanical, wear and thermal behaviour as per ASTM guidelines. Micrographs show an even distribution of nSiO2 and chopped VFs in the PLA matrix which can impact the properties of composite. Results show that, with the inclusion of VFs in the PLA matrix the density and porosity increase proportionally. Similarly tensile, impact and flexural strength increases until 20 wt.% addition, afterwards a decreasing trend is observed due to poor interfacial bonding of fibers with the matrix. Water absorption nature decreases with the inclusion of nSiO2, but increases with the inclusion of VFs. The heat deflection temperature of PLA + nSiO2 + VF increases whereas the coefficient of linear thermal expansion decreases with the inclusion of VFs till 20 wt.%. Wear resistance gets improved due to the incorporation of nSiO2 and VFs which possess certain self-lubricating properties. Thermal gravimetry analysis (TGA) and differential scanning calorimetry (DSC) assessments exposed that, the addition of VF (20 wt.%) and nSiO2 increases the heat-withstanding capability as the matrix softening occurs in the 57°C-80.7°C range, with a heating value of 99.4°C, the residual mass obtained is 99.6%.
期刊介绍:
Journal of Polymer Research provides a forum for the prompt publication of articles concerning the fundamental and applied research of polymers. Its great feature lies in the diversity of content which it encompasses, drawing together results from all aspects of polymer science and technology.
As polymer research is rapidly growing around the globe, the aim of this journal is to establish itself as a significant information tool not only for the international polymer researchers in academia but also for those working in industry. The scope of the journal covers a wide range of the highly interdisciplinary field of polymer science and technology, including:
polymer synthesis;
polymer reactions;
polymerization kinetics;
polymer physics;
morphology;
structure-property relationships;
polymer analysis and characterization;
physical and mechanical properties;
electrical and optical properties;
polymer processing and rheology;
application of polymers;
supramolecular science of polymers;
polymer composites.