{"title":"使用不同铁催化剂的基于羟基和硫酸根自由基的高级氧化工艺对酸性红 337 染料进行脱色:实验和统计调查","authors":"Pelin Saraç Uluçtan, Handan Atalay Eroğlu, Elif Nihan Kadıoğlu, Feryal Akbal","doi":"10.1016/j.jphotochem.2024.116105","DOIUrl":null,"url":null,"abstract":"<div><div>The removal efficiencies of Acid Red 337 dye were investigated by combining advanced oxidation processes based on <img>OH and SO<sub>4</sub><img><sup>−</sup> radicals. The photocatalytic oxidation processes were carried out at the natural pH (5.4) and acidic pH (3.0) values of the dye solution. In the experiments, iron (II) sulfate (Fe<sup>2+</sup>) and potassium ferrioxalate (FeOx) were used as catalysts, hydrogen peroxide (H<sub>2</sub>O<sub>2</sub>) and peroxymonosulfate (PMS) were used as oxidants to compare dye removal efficiency and to determine the optimum doses. This comparison provided the opportunity to identify suitable catalysts and oxidants for dye removal. Furthermore, time-based comparisons were conducted from 2 to 10 min using the optimum catalyst doses. It was obtained that PMS was more effective as an oxidant in the presence of both iron catalysts for colour removal. The colour removal efficiency of 98.2 % was achieved in the PMS/Fe<sup>2+</sup>/UV process with doses of 1 mM PMS and 0.1 mM Fe<sup>2+</sup> at pH 5.4 and an irradiation time of 10 min. In experiments using light-sensitive ferrioxalate (FeOx), colour removal was achieved in the PMS/FeOx/UV process with an efficiency of 97.8 %. Additionally, an artificial neural networks (ANNs) model effectively optimized the oxidation parameters, with predicted values closely matching the experimental data. The ANNs model yielded excellent statistical performance, with a root mean square error (RMSE) of 0.0317, 0.0223 and coefficient of determination (R<sup>2</sup>) of 0.9690 and 0.9854 for UV/Fe<sup>2+</sup>/H<sub>2</sub>O<sub>2</sub>-UV/FeOx/H<sub>2</sub>O<sub>2</sub> and UV/Fe<sup>2+</sup>/PMS-UV/FeOx/PMS oxidation systems respectively.</div></div>","PeriodicalId":16782,"journal":{"name":"Journal of Photochemistry and Photobiology A-chemistry","volume":"459 ","pages":"Article 116105"},"PeriodicalIF":4.1000,"publicationDate":"2024-10-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Decolorization of Acid Red 337 dye with hydroxyl and sulfate radical based advanced oxidation processes using different iron Catalyst: An experimental and statistical Investigation\",\"authors\":\"Pelin Saraç Uluçtan, Handan Atalay Eroğlu, Elif Nihan Kadıoğlu, Feryal Akbal\",\"doi\":\"10.1016/j.jphotochem.2024.116105\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The removal efficiencies of Acid Red 337 dye were investigated by combining advanced oxidation processes based on <img>OH and SO<sub>4</sub><img><sup>−</sup> radicals. The photocatalytic oxidation processes were carried out at the natural pH (5.4) and acidic pH (3.0) values of the dye solution. In the experiments, iron (II) sulfate (Fe<sup>2+</sup>) and potassium ferrioxalate (FeOx) were used as catalysts, hydrogen peroxide (H<sub>2</sub>O<sub>2</sub>) and peroxymonosulfate (PMS) were used as oxidants to compare dye removal efficiency and to determine the optimum doses. This comparison provided the opportunity to identify suitable catalysts and oxidants for dye removal. Furthermore, time-based comparisons were conducted from 2 to 10 min using the optimum catalyst doses. It was obtained that PMS was more effective as an oxidant in the presence of both iron catalysts for colour removal. The colour removal efficiency of 98.2 % was achieved in the PMS/Fe<sup>2+</sup>/UV process with doses of 1 mM PMS and 0.1 mM Fe<sup>2+</sup> at pH 5.4 and an irradiation time of 10 min. In experiments using light-sensitive ferrioxalate (FeOx), colour removal was achieved in the PMS/FeOx/UV process with an efficiency of 97.8 %. Additionally, an artificial neural networks (ANNs) model effectively optimized the oxidation parameters, with predicted values closely matching the experimental data. The ANNs model yielded excellent statistical performance, with a root mean square error (RMSE) of 0.0317, 0.0223 and coefficient of determination (R<sup>2</sup>) of 0.9690 and 0.9854 for UV/Fe<sup>2+</sup>/H<sub>2</sub>O<sub>2</sub>-UV/FeOx/H<sub>2</sub>O<sub>2</sub> and UV/Fe<sup>2+</sup>/PMS-UV/FeOx/PMS oxidation systems respectively.</div></div>\",\"PeriodicalId\":16782,\"journal\":{\"name\":\"Journal of Photochemistry and Photobiology A-chemistry\",\"volume\":\"459 \",\"pages\":\"Article 116105\"},\"PeriodicalIF\":4.1000,\"publicationDate\":\"2024-10-21\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Photochemistry and Photobiology A-chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S101060302400649X\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Photochemistry and Photobiology A-chemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S101060302400649X","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Decolorization of Acid Red 337 dye with hydroxyl and sulfate radical based advanced oxidation processes using different iron Catalyst: An experimental and statistical Investigation
The removal efficiencies of Acid Red 337 dye were investigated by combining advanced oxidation processes based on OH and SO4− radicals. The photocatalytic oxidation processes were carried out at the natural pH (5.4) and acidic pH (3.0) values of the dye solution. In the experiments, iron (II) sulfate (Fe2+) and potassium ferrioxalate (FeOx) were used as catalysts, hydrogen peroxide (H2O2) and peroxymonosulfate (PMS) were used as oxidants to compare dye removal efficiency and to determine the optimum doses. This comparison provided the opportunity to identify suitable catalysts and oxidants for dye removal. Furthermore, time-based comparisons were conducted from 2 to 10 min using the optimum catalyst doses. It was obtained that PMS was more effective as an oxidant in the presence of both iron catalysts for colour removal. The colour removal efficiency of 98.2 % was achieved in the PMS/Fe2+/UV process with doses of 1 mM PMS and 0.1 mM Fe2+ at pH 5.4 and an irradiation time of 10 min. In experiments using light-sensitive ferrioxalate (FeOx), colour removal was achieved in the PMS/FeOx/UV process with an efficiency of 97.8 %. Additionally, an artificial neural networks (ANNs) model effectively optimized the oxidation parameters, with predicted values closely matching the experimental data. The ANNs model yielded excellent statistical performance, with a root mean square error (RMSE) of 0.0317, 0.0223 and coefficient of determination (R2) of 0.9690 and 0.9854 for UV/Fe2+/H2O2-UV/FeOx/H2O2 and UV/Fe2+/PMS-UV/FeOx/PMS oxidation systems respectively.
期刊介绍:
JPPA publishes the results of fundamental studies on all aspects of chemical phenomena induced by interactions between light and molecules/matter of all kinds.
All systems capable of being described at the molecular or integrated multimolecular level are appropriate for the journal. This includes all molecular chemical species as well as biomolecular, supramolecular, polymer and other macromolecular systems, as well as solid state photochemistry. In addition, the journal publishes studies of semiconductor and other photoactive organic and inorganic materials, photocatalysis (organic, inorganic, supramolecular and superconductor).
The scope includes condensed and gas phase photochemistry, as well as synchrotron radiation chemistry. A broad range of processes and techniques in photochemistry are covered such as light induced energy, electron and proton transfer; nonlinear photochemical behavior; mechanistic investigation of photochemical reactions and identification of the products of photochemical reactions; quantum yield determinations and measurements of rate constants for primary and secondary photochemical processes; steady-state and time-resolved emission, ultrafast spectroscopic methods, single molecule spectroscopy, time resolved X-ray diffraction, luminescence microscopy, and scattering spectroscopy applied to photochemistry. Papers in emerging and applied areas such as luminescent sensors, electroluminescence, solar energy conversion, atmospheric photochemistry, environmental remediation, and related photocatalytic chemistry are also welcome.