New approach to constraining Cr-mineralization and forearc processes: U-Pb dating and geochemistry of titanites in chromitites of the Dun Mountain ophiolite belt (New Zealand)

Ophiolites provide important insights for understanding of subduction zones and forearc mantle-wedge geodynamics. Specifically, within the mantle section, podiform chromitites may record processes associated with development of highly depleted supra-subduction ophiolites, chromium mineralization and subsequent metasomatism. This study explores the first ever U-Pb isotope and trace-element data obtained from titanites in chromitites of the Dun Mountain ophiolite belt in New Zealand. Titanite is unusual in such geochemically depleted rocks and a low recovery rate attests to its rarity (ca. 190 grains from 100 kg of material from two chromitite samples). Results of U-Pb geochronology and geochemistry for the titanites constrain both the mid-Permian timing of chromitite crystallization (∼283 Ma) and later metasomatism (∼272 Ma). Older titanite grains are depleted in HFSE and have flat REE chondrite-normalized patterns reflecting a high-degree of partial melting in depths greater than the plagioclase stability field (>15 km). Younger titanites show enrichment in HFSE, depletion in LREE and negative Eu anomalies, revealing melt extraction at shallower depths (<15 km) that likely record refertilization of the mantle-wedge. Results highlight the potential of titanites in the acquisition of direct geochronological and geochemical constraints from rocks commonly devoid of minerals suitable for U-Pb dating.