封面专题：铱配合物中 SacNac 配体的柔性配位及其在催化氢硼化反应中的应用（Eur.）

IF 2.2 4区化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR

European Journal of Inorganic Chemistry Pub Date : 2024-10-25 DOI:10.1002/ejic.202483002

Jesus Rangel-Garcia, Christopher E. Rivas, Gerardo González-García, Jesús Campos, Oracio Serrano, Crispin Cristobal

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引用次数: 0

摘要

封面特写展示了正在工作的矿工，从而反映了瓜纳华托（墨西哥）在过去五个世纪中采矿业的重要性。为了类比这些努力及其取得的成功，我们的研究成果首次表明，IrI 和 IrIII 有机金属前体可以通过双配位和单配位灵活地与 SacNac 配体结合。此外，还报告了苯乙烯与新戊基乙二醇硼烷的富有成效的催化氢硼化反应。更多信息，请参阅 J. Campos、O. Serrano、C. Cristobal 及其合作者的研究文章。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Cover Feature: Flexible Coordination of SacNac Ligands in Iridium Complexes and their Application to Catalytic Hydroboration (Eur. J. Inorg. Chem. 30/2024)

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Cover Feature: Flexible Coordination of SacNac Ligands in Iridium Complexes and their Application to Catalytic Hydroboration (Eur. J. Inorg. Chem. 30/2024)

The Cover Feature shows working miners, thus reflecting the importance of mining in Guanajuato (México) for the last five centuries. As an analogy to these efforts and their success, our contribution shows for the first time that Ir^I and Ir^III organometallic precursors can be bonded to the SacNac ligand, in bi- and monodentate flexible coordination modes. A fruitful catalytical hydroboration of styrene with neopentylglycolborane is reported too. More information can be found in the Research Article by J. Campos, O. Serrano, C. Cristobal and co-workers.

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来源期刊

European Journal of Inorganic Chemistry 化学-无机化学与核化学

CiteScore

4.30

自引率

4.30%

发文量

419

审稿时长

1.3 months

期刊介绍： The European Journal of Inorganic Chemistry (2019 ISI Impact Factor: 2.529) publishes Full Papers, Communications, and Minireviews from the entire spectrum of inorganic, organometallic, bioinorganic, and solid-state chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. The following journals have been merged to form the two leading journals, European Journal of Inorganic Chemistry and European Journal of Organic Chemistry: Chemische Berichte Bulletin des Sociétés Chimiques Belges Bulletin de la Société Chimique de France Gazzetta Chimica Italiana Recueil des Travaux Chimiques des Pays-Bas Anales de Química Chimika Chronika Revista Portuguesa de Química ACH—Models in Chemistry Polish Journal of Chemistry The European Journal of Inorganic Chemistry continues to keep you up-to-date with important inorganic chemistry research results.