{"title":"可见光光氧化催化的 [1.1.1]propellane 三组分自由基烷基酰化反应。","authors":"Lanqin Liu, Shengkun Guo, Chengjun Chen, Xiaoyu Shen, Xiaoyun Chen, Huaguang Yu, Ying Han, Qiu Sun, Shaoqun Zhu, Hong Hou","doi":"10.1039/d4ob01549e","DOIUrl":null,"url":null,"abstract":"<p><p>We described herein a three-component radical alkyl-acylation of [1.1.1]propellane <i>via</i> a visible-light photoredox single electron transfer process, demonstrating an efficient approach for accessing a diverse array of 1,3-disubstituted BCP ketone derivatives. The synthetic utility of the present radical protocol was further demonstrated by the Baeyer-Villiger oxidation of the BCP ketone for BCP ester formation.</p>","PeriodicalId":2,"journal":{"name":"ACS Applied Bio Materials","volume":null,"pages":null},"PeriodicalIF":4.6000,"publicationDate":"2024-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Visible-light photoredox-catalyzed three-component radical alkyl-acylation of [1.1.1]propellane.\",\"authors\":\"Lanqin Liu, Shengkun Guo, Chengjun Chen, Xiaoyu Shen, Xiaoyun Chen, Huaguang Yu, Ying Han, Qiu Sun, Shaoqun Zhu, Hong Hou\",\"doi\":\"10.1039/d4ob01549e\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>We described herein a three-component radical alkyl-acylation of [1.1.1]propellane <i>via</i> a visible-light photoredox single electron transfer process, demonstrating an efficient approach for accessing a diverse array of 1,3-disubstituted BCP ketone derivatives. The synthetic utility of the present radical protocol was further demonstrated by the Baeyer-Villiger oxidation of the BCP ketone for BCP ester formation.</p>\",\"PeriodicalId\":2,\"journal\":{\"name\":\"ACS Applied Bio Materials\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":4.6000,\"publicationDate\":\"2024-10-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ACS Applied Bio Materials\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1039/d4ob01549e\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, BIOMATERIALS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Applied Bio Materials","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d4ob01549e","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, BIOMATERIALS","Score":null,"Total":0}
Visible-light photoredox-catalyzed three-component radical alkyl-acylation of [1.1.1]propellane.
We described herein a three-component radical alkyl-acylation of [1.1.1]propellane via a visible-light photoredox single electron transfer process, demonstrating an efficient approach for accessing a diverse array of 1,3-disubstituted BCP ketone derivatives. The synthetic utility of the present radical protocol was further demonstrated by the Baeyer-Villiger oxidation of the BCP ketone for BCP ester formation.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
