设计用于高性能非线性光学应用的卤代和传统供体-受体复合材料

IF 2.2 4区 化学 Q2 Engineering
Fatima Sarwar, Shahzad Ahmed Saeed, Randa A. Althobiti, Shabbir Muhammad, Abdullah G. Al-Sehemi, Saleh S. Alarfaji, H. Algarni, Aijaz Rasool Chaudhry
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引用次数: 0

摘要

具有非线性光学(NLO)特性的材料已在电信、固体物理、激光光学以及最近的量子计算等多个现代领域显示出高科技用途。本研究对通过卤素和传统受体设计的查尔酮化合物进行了全面的计算分析。对母体化合物 (E)-1-(4-aminophenyl)-3-(3-chlorophenyl)prop-2-en-1-one (C1) 的分子结构和电子特性进行了量子化学模拟,发现其与实验报告的结果十分吻合。通过将氯与受体(F、Br、CH3、CF3、COOH、CN 和 NO2)置换到具有固定供体(苯胺)和π桥(丙烯醛)的苯环中,还提出了新的查尔酮化合物 C2-C8。利用 DFT 和 TD-DFT 计算揭示了电荷转移特性、有希望的结构、状态密度图和 NLO 特性。用受体取代卤素和非卤素基团有效地改变了结构,从而改善了 NLO 特性。在所有提出的化合物中都出现了显著的 NLO 反应。值得注意的是,通过分子内电荷转移(ICT)过程,C2-C3 和 C4-C8 的 NLO 特性得到了显著改善,β//值为 18.30 × 10-30 esu。然而,C7 的 < γ > 值最高,达到 106.6 × 10-36。在 C1-C8 化合物中,C8 的 HOMO-LUMO 能隙较窄,有利于有效的电子激发和共振增强,从而提高了 NLO 响应。TDM 分析证实了 C1-C8 化合物中的分子内电荷转移 (ICT),这是由于电荷通过 π 桥成功地从供体迁移到了受体。目前的研究激发了科学界对形成具有吸引力的查耳酮基 NLO 化合物的兴趣,这些化合物可能会在最近的高科技应用中发挥作用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Designing of halogenated and traditional donor–acceptors composites for high-performance nonlinear optical applications

Designing of halogenated and traditional donor–acceptors composites for high-performance nonlinear optical applications

Materials having nonlinear optical (NLO) properties have shown hi-tech uses in a variety of modern fields including telecommunications, solid-state physics, laser optics and more recently in quantum computing. The current study offers a comprehensive computational analysis of the chalcone compounds designed through halogens and traditional acceptors. The molecular structure and electronic properties of parent compound (E)-1-(4-aminophenyl)-3-(3-chlorophenyl)prop-2-en-1-one (C1) were quantum chemically simulated and found in good agreement with experimentally reported results. The new chalcone compounds C2C8 were also proposed by substituting chlorine with acceptors (F, Br, CH3, CF3, COOH, CN and NO2) into a benzene ring with fixed donor (aniline) and a π-bridge (acrolein). DFT and TD-DFT calculations were employed to shed light on charge transfer properties, promising structures, density of states plots and NLO characteristics. The substitution with acceptors effectively modified the structures with halogens and nonhalogen groups, resulting in improved NLO characteristics. A striking NLO response was seen in all proposed compounds. It is interesting to note that the NLO characteristics of C2–C3 and C4–C8 have been significantly improved by the intramolecular charge transfer (ICT) process with β// value of 18.30 × 10−30 esu. However, C7 showed the highest < γ > values of 106.6 × 10−36. Among C1–C8 compounds, C8 had a narrower HOMO–LUMO energy gap, facilitating efficient electronic excitations and resonance enhancement which led to an improved NLO response. TDM analysis confirms the intramolecular charge transfer (ICT) in C1–C8 compounds due to the successful migration of charge from donor to acceptor via π-bridge. The current study intrigues scientific interest regarding the formation of chalcone-based appealing NLO compounds that may be useful in recent high-tech applications.

Graphical abstract

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来源期刊
Chemical Papers
Chemical Papers Chemical Engineering-General Chemical Engineering
CiteScore
3.30
自引率
4.50%
发文量
590
期刊介绍: Chemical Papers is a peer-reviewed, international journal devoted to basic and applied chemical research. It has a broad scope covering the chemical sciences, but favors interdisciplinary research and studies that bring chemistry together with other disciplines.
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