三苯基膦在鉴定有机化合物与分子氧和过氧化物的氧化产物中的应用

IF 1.7 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Russian Chemical Bulletin Pub Date : 2024-10-26 DOI:10.1007/s11172-024-4367-7

A. L. Perkel, S. G. Voronina

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引用次数: 0

摘要

系统整理并讨论了有关使用三苯基膦测定有机化合物与分子氧和/或过氧化物氧化反应产物组成中的过氧化物官能团和单个含氧化合物的文献数据。确定了造成分析测定结果失真的原因和机制，并提出了消除这些原因和机制的可能方法。

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Triphenylphosphine in the identification of oxidation products of organic compounds with molecular oxygen and peroxides

The literature data on the use of triphenylphosphine in determining peroxide functional groups and individual oxygen-containing compounds in the composition of the products of oxidation reactions of organic compounds with molecular oxygen and/or peroxides were systematized and discussed. The causes and mechanisms of distortions of the results of analytical determinations were identified and possible ways of their elimination were suggested.

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来源期刊

Russian Chemical Bulletin 化学-化学综合

CiteScore

2.70

自引率

47.10%

发文量

257

审稿时长

3-8 weeks

期刊介绍： Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections: General and Inorganic Chemistry; Physical Chemistry; Organic Chemistry; Organometallic Chemistry; Chemistry of Natural Compounds and Bioorganic Chemistry.