Assessment of Nuclear Fusion Reaction Spontaneity via Engineering Thermodynamics.

This work recalls the basic thermodynamics of chemical processes for introducing the evaluation of the nuclear reactions' spontaneity. The application and definition of the thermodynamic state functions of the nuclear processes have been described by focusing on their contribution to the chemical potential. The variation of the nuclear binding potentials involved in a nuclear reaction affects the chemical potential through a modification of the internal energy and of the other state functions. These energy changes are related to the mass defect between reactants and products of the nuclear reaction and are of the order of magnitude of 1 MeV per particle, about six orders of magnitude larger than those of the chemical reactions. In particular, this work assesses the Gibbs free energy change of the fusion reactions by assuming the Q_value as the nuclear contribution to the chemical potential and by calculating the entropy through the Sackur-Tetrode expression. Then, the role of the entropy in fusion processes was re-examined by demonstrating the previous spontaneity analyses, which assume a perfect gas of DT atoms in the initial state of the fusion reactions, are conservative and lead to assessing more negative ΔG than in the real case (ionized gas). As a final point, this paper examines the thermodynamic spontaneity of exothermic processes with a negative change of entropy and discusses the different thermodynamic spontaneity exhibited by the DT fusion processes when conducted in a controlled or uncontrolled way.