利用双光束热透镜光谱仪对液体系统进行高精度光热分析的特点。

IF 4.4 3区 材料科学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Nanomaterials Pub Date : 2024-10-01 DOI:10.3390/nano14191586
Vladislav R Khabibullin, Ivan V Mikheev, Mikhail A Proskurnin
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引用次数: 0

摘要

热透镜光谱法是一种高灵敏度方法,可用于测量不同性质样品的光学和热学参数。要获得准确度和精确度较高的热扩散率和基于吸光度的信号测量值,就必须关注影响光热测量真实性的因素。本研究对液体物体的特征进行了研究,并探讨了伴随光热现象的光学效应和热效应的影响。对具有光诱导活性的分散溶液和系统进行热透镜分析会产生大量的副作用,而这些副作用对真实度的影响并非总能确定。有必要考虑到纳米相和具有光诱导活性成分的物理化学特性以及光学和形态特征。所获得的结果可以减少在确定液体物体基于热扩散率和吸光度的光热信号时出现的系统误差和随机误差,还有助于加深对样品中物理化学过程的理解。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Features of High-Precision Photothermal Analysis of Liquid Systems by Dual-Beam Thermal Lens Spectrometry.

Thermal lens spectrometry is a high-sensitivity method for measuring the optical and thermal parameters of samples of different nature. To obtain both thermal diffusivity and absorbance-based signal measurements with high accuracy and precision, it is necessary to pay attention to the factors that influence the trueness of photothermal measurements. In this study, the features of liquid objects are studied, and the influence of optical and thermal effects accompanying photothermal phenomena are investigated. Thermal lens analysis of dispersed solutions and systems with photoinduced activity is associated with a large number of side effects, the impact of which on trueness is not always possible to determine. It is necessary to take into account the physicochemical properties and optical and morphological features of the nanophase and components exhibiting photoinduced activity. The results obtained make it possible to reduce systematic and random errors in determining the thermal-diffusivity-based and absorbance-based photothermal signals for liquid objects, and also contribute to a deeper understanding of the physicochemical processes in the sample.

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来源期刊
Nanomaterials
Nanomaterials NANOSCIENCE & NANOTECHNOLOGY-MATERIALS SCIENCE, MULTIDISCIPLINARY
CiteScore
8.50
自引率
9.40%
发文量
3841
审稿时长
14.22 days
期刊介绍: Nanomaterials (ISSN 2076-4991) is an international and interdisciplinary scholarly open access journal. It publishes reviews, regular research papers, communications, and short notes that are relevant to any field of study that involves nanomaterials, with respect to their science and application. Thus, theoretical and experimental articles will be accepted, along with articles that deal with the synthesis and use of nanomaterials. Articles that synthesize information from multiple fields, and which place discoveries within a broader context, will be preferred. There is no restriction on the length of the papers. Our aim is to encourage scientists to publish their experimental and theoretical research in as much detail as possible. Full experimental or methodical details, or both, must be provided for research articles. Computed data or files regarding the full details of the experimental procedure, if unable to be published in a normal way, can be deposited as supplementary material. Nanomaterials is dedicated to a high scientific standard. All manuscripts undergo a rigorous reviewing process and decisions are based on the recommendations of independent reviewers.
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