Thoughts on the Rational Design of MOF-Guest Interactions for Future Intelligent Materials.

The MOF-guest relationship is broken down in elementary phases, descriptors, and parameters. These descriptors and parameters allow precise descriptions of processes, whether they occur at the point when the guest enters the MOF, during the stay, or at the point of exiting. Description of these three phases is possible according to the location of the guest inside the MOF, the activity between MOF and guest, whether stimuli can be used, and whether a selective action can be exercised. The vocabulary provided herein can be useful to better formulate requirements when designing host-guest interactions in, and building new classes of, intelligent materials.