{"title":"用于高性能 VRFB 的石墨毡装饰 MoO3-x@K3PW12O40 微纳米复合相工程的高电催化活性","authors":"Nadra Nasir, Kue-Ho Kim, Ha-Na Jang, Hyo-Jin Ahn","doi":"10.1007/s11814-024-00292-1","DOIUrl":null,"url":null,"abstract":"<div><p>The catalytic activity of metal cations exchanged with heteropoly acids (HPA) and the selectivity towards precursor composite materials can be tailored by adjusting the reaction mechanism. A structural defect engineering strategy was developed for the metallic phase of O-MoS<sub>2</sub>, doped with a Keggin-type HPA to serve as a double gyroid layer (O-MoS<sub>2</sub>@HPA). This was achieved through thermal oxidation treatment to enable a high surface area by depositing abundant catalytically active sites on the graphite felt. Optimization strategies involving MoO<sub>3−<i>x</i></sub> (MoO<sub>3−<i>x</i></sub>@K<sub>3</sub>PW<sub>12</sub>O<sub>40</sub>) species have been crafted, anchoring active sites in a spherical nanomorphology through the self-assembly of acid. This development introduces a new approach for enhancing electrocatalysts, aiming for superior performance in VRFB. The electrochemical results show remarkable enhancement in electrocatalytic behavior with abundant heteroatom active sites, promoting oxidation at a high current density of 150 mA/cm<sup>2</sup>, achieving an outstanding 84.62% high energy efficiency. This result is 14% higher than pristine graphite felt and exhibits extraordinary stability after 1350 cycles, overcoming the sluggish kinetic mechanism that limits redox active materials. This study creates new avenues for the design of hybrid micro/nanostructured materials on cathodes and anodes to achieve excellent performance as electrocatalysts for VRFB.</p></div>","PeriodicalId":684,"journal":{"name":"Korean Journal of Chemical Engineering","volume":null,"pages":null},"PeriodicalIF":2.9000,"publicationDate":"2024-10-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Highly Electrocatalytic Activity of Micro and Nanocomposite Phase Engineering of MoO3−x@K3PW12O40 Decorated on Graphite Felt for High-Performance VRFB\",\"authors\":\"Nadra Nasir, Kue-Ho Kim, Ha-Na Jang, Hyo-Jin Ahn\",\"doi\":\"10.1007/s11814-024-00292-1\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The catalytic activity of metal cations exchanged with heteropoly acids (HPA) and the selectivity towards precursor composite materials can be tailored by adjusting the reaction mechanism. A structural defect engineering strategy was developed for the metallic phase of O-MoS<sub>2</sub>, doped with a Keggin-type HPA to serve as a double gyroid layer (O-MoS<sub>2</sub>@HPA). This was achieved through thermal oxidation treatment to enable a high surface area by depositing abundant catalytically active sites on the graphite felt. Optimization strategies involving MoO<sub>3−<i>x</i></sub> (MoO<sub>3−<i>x</i></sub>@K<sub>3</sub>PW<sub>12</sub>O<sub>40</sub>) species have been crafted, anchoring active sites in a spherical nanomorphology through the self-assembly of acid. This development introduces a new approach for enhancing electrocatalysts, aiming for superior performance in VRFB. The electrochemical results show remarkable enhancement in electrocatalytic behavior with abundant heteroatom active sites, promoting oxidation at a high current density of 150 mA/cm<sup>2</sup>, achieving an outstanding 84.62% high energy efficiency. This result is 14% higher than pristine graphite felt and exhibits extraordinary stability after 1350 cycles, overcoming the sluggish kinetic mechanism that limits redox active materials. This study creates new avenues for the design of hybrid micro/nanostructured materials on cathodes and anodes to achieve excellent performance as electrocatalysts for VRFB.</p></div>\",\"PeriodicalId\":684,\"journal\":{\"name\":\"Korean Journal of Chemical Engineering\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.9000,\"publicationDate\":\"2024-10-05\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Korean Journal of Chemical Engineering\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11814-024-00292-1\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Korean Journal of Chemical Engineering","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1007/s11814-024-00292-1","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Highly Electrocatalytic Activity of Micro and Nanocomposite Phase Engineering of MoO3−x@K3PW12O40 Decorated on Graphite Felt for High-Performance VRFB
The catalytic activity of metal cations exchanged with heteropoly acids (HPA) and the selectivity towards precursor composite materials can be tailored by adjusting the reaction mechanism. A structural defect engineering strategy was developed for the metallic phase of O-MoS2, doped with a Keggin-type HPA to serve as a double gyroid layer (O-MoS2@HPA). This was achieved through thermal oxidation treatment to enable a high surface area by depositing abundant catalytically active sites on the graphite felt. Optimization strategies involving MoO3−x (MoO3−x@K3PW12O40) species have been crafted, anchoring active sites in a spherical nanomorphology through the self-assembly of acid. This development introduces a new approach for enhancing electrocatalysts, aiming for superior performance in VRFB. The electrochemical results show remarkable enhancement in electrocatalytic behavior with abundant heteroatom active sites, promoting oxidation at a high current density of 150 mA/cm2, achieving an outstanding 84.62% high energy efficiency. This result is 14% higher than pristine graphite felt and exhibits extraordinary stability after 1350 cycles, overcoming the sluggish kinetic mechanism that limits redox active materials. This study creates new avenues for the design of hybrid micro/nanostructured materials on cathodes and anodes to achieve excellent performance as electrocatalysts for VRFB.
期刊介绍:
The Korean Journal of Chemical Engineering provides a global forum for the dissemination of research in chemical engineering. The Journal publishes significant research results obtained in the Asia-Pacific region, and simultaneously introduces recent technical progress made in other areas of the world to this region. Submitted research papers must be of potential industrial significance and specifically concerned with chemical engineering. The editors will give preference to papers having a clearly stated practical scope and applicability in the areas of chemical engineering, and to those where new theoretical concepts are supported by new experimental details. The Journal also regularly publishes featured reviews on emerging and industrially important subjects of chemical engineering as well as selected papers presented at international conferences on the subjects.