Emily Myatt, Simrun Lata, Jem Pitcairn, Dominik Daisenberger, Silva Kronawitter, Sebastian Hallweger, Gregor Kieslich, Stephen Argent, Jeremiah P. Tidey, Matthew Cliffe
{"title":"配体固溶体调整范德华金属有机磁体 NiCl2(btd)1-x(bod)x 的磁性和机械特性","authors":"Emily Myatt, Simrun Lata, Jem Pitcairn, Dominik Daisenberger, Silva Kronawitter, Sebastian Hallweger, Gregor Kieslich, Stephen Argent, Jeremiah P. Tidey, Matthew Cliffe","doi":"10.1039/d4cc04214j","DOIUrl":null,"url":null,"abstract":"Van der Waals (vdW) magnets offer unique opportunities for exploring magnetism in the 2D limit. Metal-organic magnets (MOM) are of particular interest as the functionalisation of organic ligands can control their physical properties. Here, we demonstrate tuning of mechanical and magnetic function of a noncollinear vdW ferromagnet, NiCl<em>2</em>(btd) (btd = 2,1,3-benzothiadiazole), through creating solid-solutions with the oxygen-substituted analogue ligand 2,1,3-benzoxadiazole (bod). We synthesise solid-solutions, NiCl<small><sub>2</sub></small>(btd)<small><sub>1–<em>x</em></sub></small>(bod)<small><sub><em>x</em></sub></small> , up to <em>x</em> = 0.33 above which we find mixtures form, primarily composed of a new 1D coordination polymer NiCl<small><sub>2</sub></small>(bod)<small><sub>2</sub></small>. Magnetometry on this series shows that bod incorporation reduces the coercivity significantly (up to 60%), without significantly altering the ordering temperatures. Our high pressure synchrotron diffraction measurements up to 0.4 GPa demonstrate that the stiffest axis is the b axis, through the Ni-N-(O/S)-N-Ni bonds, and the softest is the interlayer direction. Doping with bod fine-tunes this compressibility, softening the layers, but stiffening the interlayer axis. This demonstrates that substitution of organic ligands in vdW MOMs can be used to realise targetted magnetic and mechanical properties.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":null,"pages":null},"PeriodicalIF":4.3000,"publicationDate":"2024-10-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Ligand solid-solution tuning of magnetic and mechanical properties of the van der Waals metal–organic magnet NiCl2(btd)1–x(bod)x\",\"authors\":\"Emily Myatt, Simrun Lata, Jem Pitcairn, Dominik Daisenberger, Silva Kronawitter, Sebastian Hallweger, Gregor Kieslich, Stephen Argent, Jeremiah P. Tidey, Matthew Cliffe\",\"doi\":\"10.1039/d4cc04214j\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Van der Waals (vdW) magnets offer unique opportunities for exploring magnetism in the 2D limit. Metal-organic magnets (MOM) are of particular interest as the functionalisation of organic ligands can control their physical properties. Here, we demonstrate tuning of mechanical and magnetic function of a noncollinear vdW ferromagnet, NiCl<em>2</em>(btd) (btd = 2,1,3-benzothiadiazole), through creating solid-solutions with the oxygen-substituted analogue ligand 2,1,3-benzoxadiazole (bod). We synthesise solid-solutions, NiCl<small><sub>2</sub></small>(btd)<small><sub>1–<em>x</em></sub></small>(bod)<small><sub><em>x</em></sub></small> , up to <em>x</em> = 0.33 above which we find mixtures form, primarily composed of a new 1D coordination polymer NiCl<small><sub>2</sub></small>(bod)<small><sub>2</sub></small>. Magnetometry on this series shows that bod incorporation reduces the coercivity significantly (up to 60%), without significantly altering the ordering temperatures. Our high pressure synchrotron diffraction measurements up to 0.4 GPa demonstrate that the stiffest axis is the b axis, through the Ni-N-(O/S)-N-Ni bonds, and the softest is the interlayer direction. Doping with bod fine-tunes this compressibility, softening the layers, but stiffening the interlayer axis. This demonstrates that substitution of organic ligands in vdW MOMs can be used to realise targetted magnetic and mechanical properties.\",\"PeriodicalId\":67,\"journal\":{\"name\":\"Chemical Communications\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":4.3000,\"publicationDate\":\"2024-10-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Communications\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1039/d4cc04214j\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d4cc04214j","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Ligand solid-solution tuning of magnetic and mechanical properties of the van der Waals metal–organic magnet NiCl2(btd)1–x(bod)x
Van der Waals (vdW) magnets offer unique opportunities for exploring magnetism in the 2D limit. Metal-organic magnets (MOM) are of particular interest as the functionalisation of organic ligands can control their physical properties. Here, we demonstrate tuning of mechanical and magnetic function of a noncollinear vdW ferromagnet, NiCl2(btd) (btd = 2,1,3-benzothiadiazole), through creating solid-solutions with the oxygen-substituted analogue ligand 2,1,3-benzoxadiazole (bod). We synthesise solid-solutions, NiCl2(btd)1–x(bod)x , up to x = 0.33 above which we find mixtures form, primarily composed of a new 1D coordination polymer NiCl2(bod)2. Magnetometry on this series shows that bod incorporation reduces the coercivity significantly (up to 60%), without significantly altering the ordering temperatures. Our high pressure synchrotron diffraction measurements up to 0.4 GPa demonstrate that the stiffest axis is the b axis, through the Ni-N-(O/S)-N-Ni bonds, and the softest is the interlayer direction. Doping with bod fine-tunes this compressibility, softening the layers, but stiffening the interlayer axis. This demonstrates that substitution of organic ligands in vdW MOMs can be used to realise targetted magnetic and mechanical properties.
期刊介绍:
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