Ya-Ning Wang, Jin-Ting Wu, Bao-Han Li, Yan Yang, Jun Li, Bo Zhang
{"title":"层状硫代锡酸盐对放射性钡离子的超快和高选择性封存","authors":"Ya-Ning Wang, Jin-Ting Wu, Bao-Han Li, Yan Yang, Jun Li, Bo Zhang","doi":"10.1021/acs.inorgchem.4c03299","DOIUrl":null,"url":null,"abstract":"As a simulant of hazardous <sup>226</sup>Ra<sup>2+</sup>, the simultaneously selective and rapid elimination of radioactive <sup>133</sup>Ba<sup>2+</sup> ions from geothermal water is necessary but still challenging. In this paper, we demonstrated the usability of a layered thiostannate with facile synthesis and inexpensive cost, namely, K<sub>2<i>x</i></sub>Sn<sub>4–<i>x</i></sub>S<sub>8–<i>x</i></sub> (KTS-3, <i>x</i> = 0.65–1), for the remediation of radioactive <sup>133</sup>Ba<sup>2+</sup> in multiple conditions, including sorption isotherm, kinetics, and the influences of competitive inorganic/organic ions, pH values, and dosages. KTS-3 has a strong barium uptake ability (171.3 mg/g) and an ultrafast adsorption kinetics (about 2 min). Impressively, it can achieve a high preference for barium regardless of the excessive interference ions (Na<sup>+</sup>, K<sup>+</sup>, Mg<sup>2+</sup>, Ca<sup>2+</sup>, and humic acid) and acidic/alkaline environments, with the largest distribution coefficient <i>K</i><sub>d</sub> value reaching 6.89 × 10<sup>5</sup> mL/g. Also, the Ba<sup>2+</sup>-laden products can be easily eluted by a concentrated KCl solution, and its adsorption performances for barium resist well even after five consecutive cycles. In addition, owing to the regular appearance and excellent mechanical strength, the prepared KTS-3/PAN (PAN = polyacrylonitrile) granule displays a good removal efficiency in the flowing ion-exchange column. These advantages mentioned above render it very promising for the effective and efficient cleanup of radioactive <sup>133</sup>Ba<sup>2+</sup>-contaminated wastewater.","PeriodicalId":40,"journal":{"name":"Inorganic Chemistry","volume":null,"pages":null},"PeriodicalIF":4.3000,"publicationDate":"2024-10-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Ultrafast and Highly Selective Sequestration of Radioactive Barium Ions by a Layered Thiostannate\",\"authors\":\"Ya-Ning Wang, Jin-Ting Wu, Bao-Han Li, Yan Yang, Jun Li, Bo Zhang\",\"doi\":\"10.1021/acs.inorgchem.4c03299\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"As a simulant of hazardous <sup>226</sup>Ra<sup>2+</sup>, the simultaneously selective and rapid elimination of radioactive <sup>133</sup>Ba<sup>2+</sup> ions from geothermal water is necessary but still challenging. In this paper, we demonstrated the usability of a layered thiostannate with facile synthesis and inexpensive cost, namely, K<sub>2<i>x</i></sub>Sn<sub>4–<i>x</i></sub>S<sub>8–<i>x</i></sub> (KTS-3, <i>x</i> = 0.65–1), for the remediation of radioactive <sup>133</sup>Ba<sup>2+</sup> in multiple conditions, including sorption isotherm, kinetics, and the influences of competitive inorganic/organic ions, pH values, and dosages. KTS-3 has a strong barium uptake ability (171.3 mg/g) and an ultrafast adsorption kinetics (about 2 min). Impressively, it can achieve a high preference for barium regardless of the excessive interference ions (Na<sup>+</sup>, K<sup>+</sup>, Mg<sup>2+</sup>, Ca<sup>2+</sup>, and humic acid) and acidic/alkaline environments, with the largest distribution coefficient <i>K</i><sub>d</sub> value reaching 6.89 × 10<sup>5</sup> mL/g. Also, the Ba<sup>2+</sup>-laden products can be easily eluted by a concentrated KCl solution, and its adsorption performances for barium resist well even after five consecutive cycles. In addition, owing to the regular appearance and excellent mechanical strength, the prepared KTS-3/PAN (PAN = polyacrylonitrile) granule displays a good removal efficiency in the flowing ion-exchange column. These advantages mentioned above render it very promising for the effective and efficient cleanup of radioactive <sup>133</sup>Ba<sup>2+</sup>-contaminated wastewater.\",\"PeriodicalId\":40,\"journal\":{\"name\":\"Inorganic Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":4.3000,\"publicationDate\":\"2024-10-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Inorganic Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1021/acs.inorgchem.4c03299\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1021/acs.inorgchem.4c03299","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Ultrafast and Highly Selective Sequestration of Radioactive Barium Ions by a Layered Thiostannate
As a simulant of hazardous 226Ra2+, the simultaneously selective and rapid elimination of radioactive 133Ba2+ ions from geothermal water is necessary but still challenging. In this paper, we demonstrated the usability of a layered thiostannate with facile synthesis and inexpensive cost, namely, K2xSn4–xS8–x (KTS-3, x = 0.65–1), for the remediation of radioactive 133Ba2+ in multiple conditions, including sorption isotherm, kinetics, and the influences of competitive inorganic/organic ions, pH values, and dosages. KTS-3 has a strong barium uptake ability (171.3 mg/g) and an ultrafast adsorption kinetics (about 2 min). Impressively, it can achieve a high preference for barium regardless of the excessive interference ions (Na+, K+, Mg2+, Ca2+, and humic acid) and acidic/alkaline environments, with the largest distribution coefficient Kd value reaching 6.89 × 105 mL/g. Also, the Ba2+-laden products can be easily eluted by a concentrated KCl solution, and its adsorption performances for barium resist well even after five consecutive cycles. In addition, owing to the regular appearance and excellent mechanical strength, the prepared KTS-3/PAN (PAN = polyacrylonitrile) granule displays a good removal efficiency in the flowing ion-exchange column. These advantages mentioned above render it very promising for the effective and efficient cleanup of radioactive 133Ba2+-contaminated wastewater.
期刊介绍:
Inorganic Chemistry publishes fundamental studies in all phases of inorganic chemistry. Coverage includes experimental and theoretical reports on quantitative studies of structure and thermodynamics, kinetics, mechanisms of inorganic reactions, bioinorganic chemistry, and relevant aspects of organometallic chemistry, solid-state phenomena, and chemical bonding theory. Emphasis is placed on the synthesis, structure, thermodynamics, reactivity, spectroscopy, and bonding properties of significant new and known compounds.