Mo2C 催化剂实现醇和胺的高效氢转移以合成 N-烷基胺

IF 4.2 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2024-10-21 DOI:10.1039/d4cc04327h

Yimei Chen , Zhe Wang , Zhouyang Long , Yunfei Wang , Pingbo Zhang , Yan Leng

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引用次数: 0

摘要

我们发现碳化钼（Mo2C）可作为一种新型高效的异相催化剂，用于苯胺和醇的氢转移，从而合成 N-烷基胺。实验和 DFT 计算的结果表明，Mo2C 表面可以降低醇脱氢关键步骤的能障，并产生氢溢出效应，从而表现出优异的催化性能。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Mo2C catalyst leads to highly efficient hydrogen transfer of alcohols and amines to synthesize N-alkylamines†

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Mo2C catalyst leads to highly efficient hydrogen transfer of alcohols and amines to synthesize N-alkylamines†

We found that molybdenum carbide (Mo₂C) can be applied as a novel and efficient heterogeneous catalyst for hydrogen transfer of anilines and alcohols to synthesize N-alkylamines. The results of experiments and DFT calculations demonstrate that Mo₂C surface can reduce the energy barrier of the key step of alcohol dehydrogenation and generate a hydrogen spillover effect, thereby exhibiting outstanding catalytic performance.

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.