用于二氧化碳光还原的中性单核铟（III）光敏剂

IF 3.3 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Dalton Transactions Pub Date : 2024-10-19 DOI:10.1039/D4DT02595D

Zaichao Zhang, Li-Zhi Fu, Piao He and Xiao-Yi Yi

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引用次数: 0

摘要

在此，我们报告了含有 2,6-二（1H-吡咯-2-基）吡啶和取代二吡啶吡咯钳配体的中性单核铟（III）配合物（In-1~In-3）在光催化二氧化碳还原中用作光敏剂（PS）。In-2 具有良好的光活性和选择性，甚至优于经典的 Ru(铋)32+。在 CH3CN 介质中使用 In-2 作为 PS 和 CoPc 作为催化剂时，CO 生成量为 28.4 μmol，CO 选择性为 93%。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Neutral mononuclear indium(iii) photosensitizers for CO2 photoreduction†

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Neutral mononuclear indium(iii) photosensitizers for CO2 photoreduction†

Herein, neutral mononuclear indium(III) complexes (In-1–In-3) containing 2,6-di(1H-pyrrol-2-yl)pyridine and substituted dipyridylpyrrole pincer ligand were employed as photosensitizers (PS) in photocatalytic CO₂ reduction. In-2 exhibits good photo-activity and selectivity, which is superior to the classic PS Ru(bpy)₃²⁺. The amount of CO generation is 28.4 μmol with a CO selectivity of 93% when using In-2 as a PS and CoPc as a catalyst in CH₃CN media.

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来源期刊

Dalton Transactions 化学-无机化学与核化学

CiteScore

6.60

自引率

7.50%

发文量

1832

审稿时长

1.5 months

期刊介绍： Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.