疏水性 Cu2（tebpz）MOF 中侵入压力随温度变化的反直觉趋势（小号 42/2024）

IF 13 2区材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Small Pub Date : 2024-10-18 DOI:10.1002/smll.202470310

Sebastiano Merchiori, Andrea Le Donne, Ribhu Bhatia, Marta Alvelli, Jiang-Jing Yu, Xu-Dong Wu, Mian Li, Dan Li, Lukasz Scheller, Alexander R. Lowe, Monika Geppert-Rybczynska, Benjamin A. Trump, Andrey A. Yakovenko, Mirosław Chorążewski, Paweł Zajdel, Yaroslav Grosu, Simone Meloni

{"title":"疏水性 Cu2（tebpz）MOF 中侵入压力随温度变化的反直觉趋势（小号 42/2024）","authors":"Sebastiano Merchiori, Andrea Le Donne, Ribhu Bhatia, Marta Alvelli, Jiang-Jing Yu, Xu-Dong Wu, Mian Li, Dan Li, Lukasz Scheller, Alexander R. Lowe, Monika Geppert-Rybczynska, Benjamin A. Trump, Andrey A. Yakovenko, Mirosław Chorążewski, Paweł Zajdel, Yaroslav Grosu, Simone Meloni","doi":"10.1002/smll.202470310","DOIUrl":null,"url":null,"abstract":"Intrusion PressureThe high vapor confined within the hydrophobic Cu2(tebpz) metal–organic framework led to a counterintuitive trend of the intrusion pressure with temperature, compared to naïve interpretations of the classical Young-Laplace law. This is due to a peculiar combination of the geometrical and chemical characteristics of the porous medium, favoring the formation of a dense vapor inside the material. More in article number 2402173, Andrea Le Donne, Pawel Zajdel, Yaroslav Grosu, and co-workers.\n\n <figure>\n <div><picture>\n <source></source></picture>\n </div>\n </figure>","PeriodicalId":228,"journal":{"name":"Small","volume":null,"pages":null},"PeriodicalIF":13.0000,"publicationDate":"2024-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/smll.202470310","citationCount":"0","resultStr":"{\"title\":\"Counterintuitive Trend of Intrusion Pressure with Temperature in the Hydrophobic Cu2(tebpz) MOF (Small 42/2024)\",\"authors\":\"Sebastiano Merchiori, Andrea Le Donne, Ribhu Bhatia, Marta Alvelli, Jiang-Jing Yu, Xu-Dong Wu, Mian Li, Dan Li, Lukasz Scheller, Alexander R. Lowe, Monika Geppert-Rybczynska, Benjamin A. Trump, Andrey A. Yakovenko, Mirosław Chorążewski, Paweł Zajdel, Yaroslav Grosu, Simone Meloni\",\"doi\":\"10.1002/smll.202470310\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Intrusion PressureThe high vapor confined within the hydrophobic Cu2(tebpz) metal–organic framework led to a counterintuitive trend of the intrusion pressure with temperature, compared to naïve interpretations of the classical Young-Laplace law. This is due to a peculiar combination of the geometrical and chemical characteristics of the porous medium, favoring the formation of a dense vapor inside the material. More in article number 2402173, Andrea Le Donne, Pawel Zajdel, Yaroslav Grosu, and co-workers.\\n\\n <figure>\\n <div><picture>\\n <source></source></picture>\\n </div>\\n </figure>\",\"PeriodicalId\":228,\"journal\":{\"name\":\"Small\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":13.0000,\"publicationDate\":\"2024-10-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://onlinelibrary.wiley.com/doi/epdf/10.1002/smll.202470310\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Small\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/smll.202470310\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Small","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/smll.202470310","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

摘要

入侵压力

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Counterintuitive Trend of Intrusion Pressure with Temperature in the Hydrophobic Cu2(tebpz) MOF (Small 42/2024)

查看原文本刊更多论文

Counterintuitive Trend of Intrusion Pressure with Temperature in the Hydrophobic Cu2(tebpz) MOF (Small 42/2024)

Intrusion Pressure

The high vapor confined within the hydrophobic Cu₂(tebpz) metal–organic framework led to a counterintuitive trend of the intrusion pressure with temperature, compared to naïve interpretations of the classical Young-Laplace law. This is due to a peculiar combination of the geometrical and chemical characteristics of the porous medium, favoring the formation of a dense vapor inside the material. More in article number 2402173, Andrea Le Donne, Pawel Zajdel, Yaroslav Grosu, and co-workers.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Small 工程技术-材料科学：综合

CiteScore

17.70

自引率

3.80%

发文量

1830

审稿时长

2.1 months

期刊介绍： Small serves as an exceptional platform for both experimental and theoretical studies in fundamental and applied interdisciplinary research at the nano- and microscale. The journal offers a compelling mix of peer-reviewed Research Articles, Reviews, Perspectives, and Comments. With a remarkable 2022 Journal Impact Factor of 13.3 (Journal Citation Reports from Clarivate Analytics, 2023), Small remains among the top multidisciplinary journals, covering a wide range of topics at the interface of materials science, chemistry, physics, engineering, medicine, and biology. Small's readership includes biochemists, biologists, biomedical scientists, chemists, engineers, information technologists, materials scientists, physicists, and theoreticians alike.