{"title":"通过超分散策略实现高能量密度的氮化硼纳米片与分散 BaTiO3@PEG 纳米粒子对齐的 PVDF 纳米复合材料","authors":"Dajun Hou , Jingjing Zhou , Wen Chen , Jing Zhou , Pengchao Zhang","doi":"10.1039/d4cc04430d","DOIUrl":null,"url":null,"abstract":"<div><div>The limited improvement in discharge energy density (<em>U</em><sub>e</sub>) of polyvinylidene fluoride (PVDF) nanocomposites filled with low-dielectric-constant (<em>ε</em><sub>r</sub>) nanosheets has been addressed by using a superspreading layering strategy. The integration of highly aligned boron nitride nanosheets (BNNS) and well-dispersed BaTiO<sub>3</sub>@PEG (BT@PEG) nanoparticles into the PVDF matrix results in a significant enhancement, increasing <em>E</em><sub>b</sub> and <em>ε</em><sub>r</sub> by 52% and 64%, respectively, and achieving an <em>U</em><sub>e</sub> of up to 20.12 J cm<sup>−3</sup>.</div></div>","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"60 91","pages":"Pages 13344-13347"},"PeriodicalIF":4.3000,"publicationDate":"2024-10-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"PVDF nanocomposites with aligned boron nitride nanosheets and dispersed BaTiO3@PEG nanoparticles by a superspreading strategy towards high energy density†\",\"authors\":\"Dajun Hou , Jingjing Zhou , Wen Chen , Jing Zhou , Pengchao Zhang\",\"doi\":\"10.1039/d4cc04430d\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The limited improvement in discharge energy density (<em>U</em><sub>e</sub>) of polyvinylidene fluoride (PVDF) nanocomposites filled with low-dielectric-constant (<em>ε</em><sub>r</sub>) nanosheets has been addressed by using a superspreading layering strategy. The integration of highly aligned boron nitride nanosheets (BNNS) and well-dispersed BaTiO<sub>3</sub>@PEG (BT@PEG) nanoparticles into the PVDF matrix results in a significant enhancement, increasing <em>E</em><sub>b</sub> and <em>ε</em><sub>r</sub> by 52% and 64%, respectively, and achieving an <em>U</em><sub>e</sub> of up to 20.12 J cm<sup>−3</sup>.</div></div>\",\"PeriodicalId\":67,\"journal\":{\"name\":\"Chemical Communications\",\"volume\":\"60 91\",\"pages\":\"Pages 13344-13347\"},\"PeriodicalIF\":4.3000,\"publicationDate\":\"2024-10-21\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Communications\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S1359734524022110\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1359734524022110","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
PVDF nanocomposites with aligned boron nitride nanosheets and dispersed BaTiO3@PEG nanoparticles by a superspreading strategy towards high energy density†
The limited improvement in discharge energy density (Ue) of polyvinylidene fluoride (PVDF) nanocomposites filled with low-dielectric-constant (εr) nanosheets has been addressed by using a superspreading layering strategy. The integration of highly aligned boron nitride nanosheets (BNNS) and well-dispersed BaTiO3@PEG (BT@PEG) nanoparticles into the PVDF matrix results in a significant enhancement, increasing Eb and εr by 52% and 64%, respectively, and achieving an Ue of up to 20.12 J cm−3.
期刊介绍:
ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.