{"title":"通过电泳沉积在添加剂制造的支撑结构上涂覆 RuCs/MgO 催化剂用于合成氨的性能","authors":"","doi":"10.1016/j.cep.2024.110019","DOIUrl":null,"url":null,"abstract":"<div><div>This work investigates the electrophoretic deposition of a catalytic coating on so-called fluid guiding elements (FGE) with a ruthenium-based catalyst for use in ammonia synthesis reactors. FGE are additive manufactured metallic pipe inserts that have shown to enhance the heat transfer compared to empty pipes by dividing the fluid flow and alternately guiding the partial flows to the wall. Consequently, they could improve the performance of temperature sensitive structured catalytic systems. To be able to demonstrate the degree of process intensification, the required steps to enable the deposition of a reference catalyst for ammonia synthesis are developed. Further, the distribution of catalytically active compounds is characterized. The catalytic activity is assessed in a plug flow reactor under pressures up to 5<!--> <!-->MPa and compared against a fixed bed from the same batch. The expected activity from the reference catalyst is calculated by a kinetic rate expression. The coating process does not affect catalytic activity, but a steady deactivation and high sensitivity to feed gas impurities are observed. Possible mechanisms for the deactivation are examined and discussed.</div></div>","PeriodicalId":9929,"journal":{"name":"Chemical Engineering and Processing - Process Intensification","volume":null,"pages":null},"PeriodicalIF":3.8000,"publicationDate":"2024-10-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Performance of a RuCs/MgO catalyst coated on additive manufactured support structures via electrophoretic deposition for ammonia synthesis\",\"authors\":\"\",\"doi\":\"10.1016/j.cep.2024.110019\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>This work investigates the electrophoretic deposition of a catalytic coating on so-called fluid guiding elements (FGE) with a ruthenium-based catalyst for use in ammonia synthesis reactors. FGE are additive manufactured metallic pipe inserts that have shown to enhance the heat transfer compared to empty pipes by dividing the fluid flow and alternately guiding the partial flows to the wall. Consequently, they could improve the performance of temperature sensitive structured catalytic systems. To be able to demonstrate the degree of process intensification, the required steps to enable the deposition of a reference catalyst for ammonia synthesis are developed. Further, the distribution of catalytically active compounds is characterized. The catalytic activity is assessed in a plug flow reactor under pressures up to 5<!--> <!-->MPa and compared against a fixed bed from the same batch. The expected activity from the reference catalyst is calculated by a kinetic rate expression. The coating process does not affect catalytic activity, but a steady deactivation and high sensitivity to feed gas impurities are observed. Possible mechanisms for the deactivation are examined and discussed.</div></div>\",\"PeriodicalId\":9929,\"journal\":{\"name\":\"Chemical Engineering and Processing - Process Intensification\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":3.8000,\"publicationDate\":\"2024-10-11\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Engineering and Processing - Process Intensification\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S025527012400357X\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"ENERGY & FUELS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Engineering and Processing - Process Intensification","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S025527012400357X","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
Performance of a RuCs/MgO catalyst coated on additive manufactured support structures via electrophoretic deposition for ammonia synthesis
This work investigates the electrophoretic deposition of a catalytic coating on so-called fluid guiding elements (FGE) with a ruthenium-based catalyst for use in ammonia synthesis reactors. FGE are additive manufactured metallic pipe inserts that have shown to enhance the heat transfer compared to empty pipes by dividing the fluid flow and alternately guiding the partial flows to the wall. Consequently, they could improve the performance of temperature sensitive structured catalytic systems. To be able to demonstrate the degree of process intensification, the required steps to enable the deposition of a reference catalyst for ammonia synthesis are developed. Further, the distribution of catalytically active compounds is characterized. The catalytic activity is assessed in a plug flow reactor under pressures up to 5 MPa and compared against a fixed bed from the same batch. The expected activity from the reference catalyst is calculated by a kinetic rate expression. The coating process does not affect catalytic activity, but a steady deactivation and high sensitivity to feed gas impurities are observed. Possible mechanisms for the deactivation are examined and discussed.
期刊介绍:
Chemical Engineering and Processing: Process Intensification is intended for practicing researchers in industry and academia, working in the field of Process Engineering and related to the subject of Process Intensification.Articles published in the Journal demonstrate how novel discoveries, developments and theories in the field of Process Engineering and in particular Process Intensification may be used for analysis and design of innovative equipment and processing methods with substantially improved sustainability, efficiency and environmental performance.