Wenbin Wang, Qunlei Wen, Danji Huang, Yu Lin, Niandan Zhao, Lan Tang, Ming Li, Youwen Liu, Rongxing He
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Oxyanions Enhancing Crystallinity of Reconstructed Phase for Oxygen Evolution Reaction
The catalysts were always undergoing continuous amorphization and dissolution of active structure in operating condition, hindering the compatibility between stability and activity for oxygen evolution reaction (OER). Herein, we propose the selective adsorption of leached NO3- to strengthen the crystallinity and activity of surface reconstructed layer with amorphous and crystalline (a-c) heterojunction. Taking a-c Ni doped Fe2O(OH)3NO3·H2O (Ni-FeNH) as a model precatalyst, we uncover that the leached NO3- are readily adsorbs on the crystalline phase in the formed a-c Fe(Ni)OOH during OER, lowering the disorder degree and further activating Ni and Fe ion of the crystalline Fe(Ni)OOH on a-c heterojunctions. Accordingly, Ni-FeNH deliver a low overpotential of 303 mV and high durability of 500 hours at 500 mA cm-2 for OER. Particularly, constructing industrial water electrolysis equipment exhibits high stability of 100 hours under a high operating current of 8000 mA.
期刊介绍:
Angewandte Chemie, a journal of the German Chemical Society (GDCh), maintains a leading position among scholarly journals in general chemistry with an impressive Impact Factor of 16.6 (2022 Journal Citation Reports, Clarivate, 2023). Published weekly in a reader-friendly format, it features new articles almost every day. Established in 1887, Angewandte Chemie is a prominent chemistry journal, offering a dynamic blend of Review-type articles, Highlights, Communications, and Research Articles on a weekly basis, making it unique in the field.