利用离子束技术和光学方法追踪钯封镁薄膜的等温氢吸收过程

IF 15.8 1区 材料科学 Q1 METALLURGY & METALLURGICAL ENGINEERING
D. Abejón , P. Prieto , J.K. Kim , A. Redondo-Cubero , M.L. Crespillo , F. Leardini , I.J. Ferrer , G. García , J.R. Ares
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引用次数: 0

摘要

利用电子束蒸发法制备了钯封层纳米晶镁薄膜,并在等温条件下进行氢化,通过离子束技术和原位光学方法研究了氢吸收过程。通过 X 射线衍射(XRD)和扫描电子显微镜(SEM)等不同技术对薄膜进行了表征。卢瑟福背散射光谱法(RBS)和弹性反冲检测分析法(ERDA)提供了氢化过程中薄膜的详细成分深度剖面图。应用于 ERDA 数据的气固反应动力学理论揭示了由 H 扩散控制的 H 吸收机制。XRD 测量也证实了这一限速步骤。扩散系数 (D) 也是通过 RBS 和 ERDA 测定的,在 140 ∘∘C 时的值为 (1.1±0.1)-10-13(1.1±0.1)-10-13 cm22/s。结果证实了 IBA 监测氢化过程和提取过程控制机制的有效性。光学方法提供的氢动力学信息受到镁层光学吸收的强烈影响,这表明需要更薄的薄膜才能从该技术中提取更多可靠的信息。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Isothermal hydrogen absorption process of Pd-capped Mg films traced by ion beam techniques and optical methods

Isothermal hydrogen absorption process of Pd-capped Mg films traced by ion beam techniques and optical methods

Isothermal hydrogen absorption process of Pd-capped Mg films traced by ion beam techniques and optical methods
Pd-capped nanocrystalline Mg films were prepared by electron beam evaporation and hydrogenated under isothermal conditions to investigate the hydrogen absorption process via ion beam techniques and in situ optical methods. Films were characterized by different techniques such as X-ray diffraction (XRD) and scanning electron microscopy (SEM). Rutherford backscattering spectrometry (RBS) and elastic recoil detection analysis (ERDA) provided a detailed compositional depth profile of the films during hydrogenation. Gas-solid reaction kinetics theory applied to ERDA data revealed a H absorption mechanism controlled by H diffusion. This rate-limiting step was also confirmed by XRD measurements. The diffusion coefficient (D) was also determined via RBS and ERDA, with a value of (1.1±0.1)·1013 cm2/s at 140 C. Results confirm the validity of IBA to monitor the hydrogenation process and to extract the control mechanism of the process. The H kinetic information given by optical methods is strongly influenced by the optical absorption of the magnesium layer, revealing that thinner films are needed to extract further and reliable information from that technique.
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来源期刊
Journal of Magnesium and Alloys
Journal of Magnesium and Alloys Engineering-Mechanics of Materials
CiteScore
20.20
自引率
14.80%
发文量
52
审稿时长
59 days
期刊介绍: The Journal of Magnesium and Alloys serves as a global platform for both theoretical and experimental studies in magnesium science and engineering. It welcomes submissions investigating various scientific and engineering factors impacting the metallurgy, processing, microstructure, properties, and applications of magnesium and alloys. The journal covers all aspects of magnesium and alloy research, including raw materials, alloy casting, extrusion and deformation, corrosion and surface treatment, joining and machining, simulation and modeling, microstructure evolution and mechanical properties, new alloy development, magnesium-based composites, bio-materials and energy materials, applications, and recycling.
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