将入侵植物高价值转化为掺氮多孔碳,用于高性能超级电容器

IF 5.8 2区 化学 Q1 CHEMISTRY, ANALYTICAL
Shan Zhong , Hao Xu , Xiaojun Zheng , Guanlin Li , Shuang Wang
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引用次数: 0

摘要

鉴于入侵植物对环境造成的危害和高昂的处理成本,我们提出了对入侵植物进行高价值转化和利用的建议。通过一种可行的绿色碳化方法,成功合成了从入侵植物(加拿大金线莲)中提取的高多孔碳,并首次将其用作超级电容器电极。研究发现,添加富氮(N)小球藻可积极增加 N 含量,并显著提高碳-GC1-800 的比表面积,使其达到 2231.41 m2 g-1,这是加速离子传输和改善电容行为的关键因素。值得注意的是,Carbon-GC1-800 的微孔体积与总孔隙体积之比最高(70.9%)。CarbonGC1-800 电极的电化学特性显示,在电流密度为 0.5 A g-1 时,其比电容高达 388.2 F g-1,在 0.5 A g-1 至 10 A g-1 的范围内,其速率能力高达 75.7%。以离子液体为电解质组装的对称超级电容器的最大功率密度为 8753.7 W kg-1,峰值能量密度为 59.3 Wh kg-1。本研究提出了利用入侵植物资源生产多孔碳储能器的新思路和有效技术。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
High-value conversion of invasive plant into nitrogen-doped porous carbons for high-performance supercapacitors
Given the harm caused by invasive plants to the environment and the high cost of treatment, we propose high-value transformation and utilization for invasive plants. Highly porous carbon derived from invasive plant (Canada goldenrod) was successfully synthesized through a feasible and green carbonization approach, which was firstly utilized as supercapacitor electrode. It is found that the addition of nitrogen (N)-rich chlorella could positively increase the N content and considerably boost the specific surface area up to 2231.41 m2 g−1 for the resultant Carbon-GC1-800, which are crucial factors for accelerating the ion transport and improving the capacitive behaviors. Notably, Carbon-GC1-800 exhibits the highest ratio (70.9 %) of microporous volume to total pore volume. The electrochemical properties of Carbon-GC1-800 electrode exhibits an outstanding specific capacitance of 388.2 F g−1 at a current density of 0.5 A g−1 and a superb rate capability of 75.7 % from 0.5 A g−1 to 10 A g−1. The assembled symmetric supercapacitor with ionic liquid as electrolyte demonstrates the exceptional maximum power density of 8753.7 W kg−1 and peak energy density of 59.3 Wh kg−1. This study presents the novel ideas and effective techniques to produce porous carbons for energy storage from invasive plant resources.
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来源期刊
CiteScore
9.10
自引率
11.70%
发文量
340
审稿时长
44 days
期刊介绍: The Journal of Analytical and Applied Pyrolysis (JAAP) is devoted to the publication of papers dealing with innovative applications of pyrolysis processes, the characterization of products related to pyrolysis reactions, and investigations of reaction mechanism. To be considered by JAAP, a manuscript should present significant progress in these topics. The novelty must be satisfactorily argued in the cover letter. A manuscript with a cover letter to the editor not addressing the novelty is likely to be rejected without review.
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