在混合水溶液和有机电解质中提高镁空气电池电化学性能的新见解

IF 7.4 1区材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY

Corrosion Science Pub Date : 2024-10-11 DOI:10.1016/j.corsci.2024.112512

Yuxin Zhou , Xiaopeng Lu , Antoine Seyeux , Jolanta Światowska , Fuhui Wang

{"title":"在混合水溶液和有机电解质中提高镁空气电池电化学性能的新见解","authors":"Yuxin Zhou , Xiaopeng Lu , Antoine Seyeux , Jolanta Światowska , Fuhui Wang","doi":"10.1016/j.corsci.2024.112512","DOIUrl":null,"url":null,"abstract":"<div><div>A new strategy of utilizing mixtures of ethanol and complexing agents on Mg-air battery is investigated systematically. The presence of ethanol promotes formation of a dense inner layer with a high portion of oxide in the discharge film, leading to significantly enhanced utilization efficiency. The highest utilization efficiency of Mg anode has been increased from 53.6 % to 85.7 % and the discharge potential is decreased 300 mV, when discharges in mixed electrolyte. The adsorption/deposition of S-like species on metal surface is evidenced in ethanol and 5-sulfosalicylate acid containing solution, resulting in inhibition of the hydroxide-rich outer layer growth.</div></div>","PeriodicalId":290,"journal":{"name":"Corrosion Science","volume":"240 ","pages":"Article 112512"},"PeriodicalIF":7.4000,"publicationDate":"2024-10-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A novel insight into the enhanced electrochemical performance of Mg-air battery in mixed aqueous and organic electrolytes\",\"authors\":\"Yuxin Zhou , Xiaopeng Lu , Antoine Seyeux , Jolanta Światowska , Fuhui Wang\",\"doi\":\"10.1016/j.corsci.2024.112512\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>A new strategy of utilizing mixtures of ethanol and complexing agents on Mg-air battery is investigated systematically. The presence of ethanol promotes formation of a dense inner layer with a high portion of oxide in the discharge film, leading to significantly enhanced utilization efficiency. The highest utilization efficiency of Mg anode has been increased from 53.6 % to 85.7 % and the discharge potential is decreased 300 mV, when discharges in mixed electrolyte. The adsorption/deposition of S-like species on metal surface is evidenced in ethanol and 5-sulfosalicylate acid containing solution, resulting in inhibition of the hydroxide-rich outer layer growth.</div></div>\",\"PeriodicalId\":290,\"journal\":{\"name\":\"Corrosion Science\",\"volume\":\"240 \",\"pages\":\"Article 112512\"},\"PeriodicalIF\":7.4000,\"publicationDate\":\"2024-10-11\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Corrosion Science\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0010938X24007078\",\"RegionNum\":1,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Corrosion Science","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0010938X24007078","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

摘要

本文系统地研究了在镁空气电池中使用乙醇和络合剂混合物的新策略。乙醇的存在促进了放电膜中氧化物含量较高的致密内层的形成，从而显著提高了利用效率。在混合电解质中放电时，镁阳极的最高利用效率从 53.6% 提高到 85.7%，放电电位降低了 300 mV。在含乙醇和 5-磺基水杨酸的溶液中，S 类物质在金属表面的吸附/沉积得到了证实，从而抑制了富氢氧化物外层的生长。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

A novel insight into the enhanced electrochemical performance of Mg-air battery in mixed aqueous and organic electrolytes

A new strategy of utilizing mixtures of ethanol and complexing agents on Mg-air battery is investigated systematically. The presence of ethanol promotes formation of a dense inner layer with a high portion of oxide in the discharge film, leading to significantly enhanced utilization efficiency. The highest utilization efficiency of Mg anode has been increased from 53.6 % to 85.7 % and the discharge potential is decreased 300 mV, when discharges in mixed electrolyte. The adsorption/deposition of S-like species on metal surface is evidenced in ethanol and 5-sulfosalicylate acid containing solution, resulting in inhibition of the hydroxide-rich outer layer growth.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Corrosion Science 工程技术-材料科学：综合

CiteScore

13.60

自引率

18.10%

发文量

763

审稿时长

46 days

期刊介绍： Corrosion occurrence and its practical control encompass a vast array of scientific knowledge. Corrosion Science endeavors to serve as the conduit for the exchange of ideas, developments, and research across all facets of this field, encompassing both metallic and non-metallic corrosion. The scope of this international journal is broad and inclusive. Published papers span from highly theoretical inquiries to essentially practical applications, covering diverse areas such as high-temperature oxidation, passivity, anodic oxidation, biochemical corrosion, stress corrosion cracking, and corrosion control mechanisms and methodologies. This journal publishes original papers and critical reviews across the spectrum of pure and applied corrosion, material degradation, and surface science and engineering. It serves as a crucial link connecting metallurgists, materials scientists, and researchers investigating corrosion and degradation phenomena. Join us in advancing knowledge and understanding in the vital field of corrosion science.