{"title":"基于铝簇分子环的异金属配合物的合成、晶体结构和光热转换特性","authors":"Wei Lv, Song-Yan Sui, Zhe Xue, Lei-Lei Guo, Xiao-Yu Li* and Guo-Ming Wang, ","doi":"10.1021/acs.cgd.4c0105610.1021/acs.cgd.4c01056","DOIUrl":null,"url":null,"abstract":"<p >Effective combination of Al clusters with functional motif is a good way to expand the application of Al cluster materials. In this work, by introducing noble-metal ions with photothermal property into the assembly of aluminum clusters, four Al<sub>8</sub>-based mixed metal complexes, {[Al<sub>8</sub>Ag<sub>2</sub>(OH)<sub>8</sub>(NA)<sub>16</sub>(CH<sub>3</sub>CN)<sub>2</sub>]·2SO<sub>3</sub>CF<sub>3</sub>}<i><sub>n</sub></i> (<b>Ag–Al</b><sub><b>8</b></sub>, <b>NA<sup>–</sup></b> <b>=</b> nicotinic acid), {[(H<sub>3</sub>O)<sub>2</sub>Al<sub>8</sub>Ag<sub>3</sub>Cl<sub>9</sub>(OH)<sub>8</sub>(NA)<sub>2</sub>(HNA)<sub>14</sub>]·AgCl<sub>4</sub>·Ag<sub>2</sub>Cl<sub>7</sub>·2SO<sub>3</sub>CF<sub>3</sub>}<i><sub>n</sub></i> (<b>AgCl-Al</b><sub><b>8</b></sub>), {[Al<sub>8</sub>Cu<sub>4</sub>Br<sub>3</sub>(OH)<sub>8</sub>(NA)<sub>16</sub>]·NA·HNA}<i><sub>n</sub></i> (<b>CuBr-Al</b><sub><b>8</b></sub><b>-1</b>) and {[Al<sub>8</sub>Cu<sub>4</sub>Br<sub>2</sub>(OH)<sub>8</sub>(NA)<sub>16</sub>]·2NA}<i><sub>n</sub></i> (<b>CuBr-Al</b><sub><b>8</b></sub><b>-2</b>), were obtained. They are all constructed by the <b>Al</b><sub><b>8</b></sub> ring cluster as the building unit and Ag/AgCl/CuBr-pyridine N as the linkers. Moreover, the <b>Ag–Al</b><sub><b>8</b></sub> and <b>AgCl-Al</b><sub><b>8</b></sub> show a photothermal conversion property under the irradiation of a 980 nm infrared laser. The temperatures of <b>Ag–Al</b><sub><b>8</b></sub> and <b>AgCl-Al</b><sub><b>8</b></sub> can respectively increase to 50 and 32 °C, and the photothermal conversion efficiency can reach 26.62 and 28.64%. Furthermore, the photothermal performance is reversible at least five irradiation cycles. This work first reports Al–Ag mixed metal frameworks with photothermal conversion performance based on aluminum metal clusters, enriching the family of Al cluster-based frameworks and expanding their application.</p>","PeriodicalId":34,"journal":{"name":"Crystal Growth & Design","volume":null,"pages":null},"PeriodicalIF":3.2000,"publicationDate":"2024-10-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Syntheses, Crystal Structures, and Photothermal Conversion Property of Aluminum Cluster Molecular Rings-Based Heterometallic Complexes\",\"authors\":\"Wei Lv, Song-Yan Sui, Zhe Xue, Lei-Lei Guo, Xiao-Yu Li* and Guo-Ming Wang, \",\"doi\":\"10.1021/acs.cgd.4c0105610.1021/acs.cgd.4c01056\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Effective combination of Al clusters with functional motif is a good way to expand the application of Al cluster materials. In this work, by introducing noble-metal ions with photothermal property into the assembly of aluminum clusters, four Al<sub>8</sub>-based mixed metal complexes, {[Al<sub>8</sub>Ag<sub>2</sub>(OH)<sub>8</sub>(NA)<sub>16</sub>(CH<sub>3</sub>CN)<sub>2</sub>]·2SO<sub>3</sub>CF<sub>3</sub>}<i><sub>n</sub></i> (<b>Ag–Al</b><sub><b>8</b></sub>, <b>NA<sup>–</sup></b> <b>=</b> nicotinic acid), {[(H<sub>3</sub>O)<sub>2</sub>Al<sub>8</sub>Ag<sub>3</sub>Cl<sub>9</sub>(OH)<sub>8</sub>(NA)<sub>2</sub>(HNA)<sub>14</sub>]·AgCl<sub>4</sub>·Ag<sub>2</sub>Cl<sub>7</sub>·2SO<sub>3</sub>CF<sub>3</sub>}<i><sub>n</sub></i> (<b>AgCl-Al</b><sub><b>8</b></sub>), {[Al<sub>8</sub>Cu<sub>4</sub>Br<sub>3</sub>(OH)<sub>8</sub>(NA)<sub>16</sub>]·NA·HNA}<i><sub>n</sub></i> (<b>CuBr-Al</b><sub><b>8</b></sub><b>-1</b>) and {[Al<sub>8</sub>Cu<sub>4</sub>Br<sub>2</sub>(OH)<sub>8</sub>(NA)<sub>16</sub>]·2NA}<i><sub>n</sub></i> (<b>CuBr-Al</b><sub><b>8</b></sub><b>-2</b>), were obtained. They are all constructed by the <b>Al</b><sub><b>8</b></sub> ring cluster as the building unit and Ag/AgCl/CuBr-pyridine N as the linkers. Moreover, the <b>Ag–Al</b><sub><b>8</b></sub> and <b>AgCl-Al</b><sub><b>8</b></sub> show a photothermal conversion property under the irradiation of a 980 nm infrared laser. The temperatures of <b>Ag–Al</b><sub><b>8</b></sub> and <b>AgCl-Al</b><sub><b>8</b></sub> can respectively increase to 50 and 32 °C, and the photothermal conversion efficiency can reach 26.62 and 28.64%. Furthermore, the photothermal performance is reversible at least five irradiation cycles. This work first reports Al–Ag mixed metal frameworks with photothermal conversion performance based on aluminum metal clusters, enriching the family of Al cluster-based frameworks and expanding their application.</p>\",\"PeriodicalId\":34,\"journal\":{\"name\":\"Crystal Growth & Design\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":3.2000,\"publicationDate\":\"2024-10-06\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Crystal Growth & Design\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.acs.org/doi/10.1021/acs.cgd.4c01056\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Crystal Growth & Design","FirstCategoryId":"92","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acs.cgd.4c01056","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Syntheses, Crystal Structures, and Photothermal Conversion Property of Aluminum Cluster Molecular Rings-Based Heterometallic Complexes
Effective combination of Al clusters with functional motif is a good way to expand the application of Al cluster materials. In this work, by introducing noble-metal ions with photothermal property into the assembly of aluminum clusters, four Al8-based mixed metal complexes, {[Al8Ag2(OH)8(NA)16(CH3CN)2]·2SO3CF3}n (Ag–Al8, NA–= nicotinic acid), {[(H3O)2Al8Ag3Cl9(OH)8(NA)2(HNA)14]·AgCl4·Ag2Cl7·2SO3CF3}n (AgCl-Al8), {[Al8Cu4Br3(OH)8(NA)16]·NA·HNA}n (CuBr-Al8-1) and {[Al8Cu4Br2(OH)8(NA)16]·2NA}n (CuBr-Al8-2), were obtained. They are all constructed by the Al8 ring cluster as the building unit and Ag/AgCl/CuBr-pyridine N as the linkers. Moreover, the Ag–Al8 and AgCl-Al8 show a photothermal conversion property under the irradiation of a 980 nm infrared laser. The temperatures of Ag–Al8 and AgCl-Al8 can respectively increase to 50 and 32 °C, and the photothermal conversion efficiency can reach 26.62 and 28.64%. Furthermore, the photothermal performance is reversible at least five irradiation cycles. This work first reports Al–Ag mixed metal frameworks with photothermal conversion performance based on aluminum metal clusters, enriching the family of Al cluster-based frameworks and expanding their application.
期刊介绍:
The aim of Crystal Growth & Design is to stimulate crossfertilization of knowledge among scientists and engineers working in the fields of crystal growth, crystal engineering, and the industrial application of crystalline materials.
Crystal Growth & Design publishes theoretical and experimental studies of the physical, chemical, and biological phenomena and processes related to the design, growth, and application of crystalline materials. Synergistic approaches originating from different disciplines and technologies and integrating the fields of crystal growth, crystal engineering, intermolecular interactions, and industrial application are encouraged.