Marina A. Uvarova, Maxim A. Shmelev, Olga B. Bekker, Irina A. Lutsenko, Sergey E. Nefedov and Igor L. Eremenko
{"title":"基于功能化茂金属的具有抗菌活性的杂三金属一维配位聚合物的靶向设计†.","authors":"Marina A. Uvarova, Maxim A. Shmelev, Olga B. Bekker, Irina A. Lutsenko, Sergey E. Nefedov and Igor L. Eremenko","doi":"10.1039/D4NJ03598D","DOIUrl":null,"url":null,"abstract":"<p >Using (bis)diethoxyphosphoryl ferrocene [Fc(O<img>P(OEt)<small><sub>2</sub></small>)<small><sub>2</sub></small>] and transition metal carboxylates – [M<small><sub>2</sub></small>(μ-OOCR)<small><sub>4</sub></small>(CH<small><sub>3</sub></small>CN)<small><sub>2</sub></small>], M = Cu<small><sup>II</sup></small>, R = <small><sup><em>t</em></sup></small>Bu, (C<small><sub>5</sub></small>H<small><sub>4</sub></small>)Mn(CO)<small><sub>3</sub></small> (Cym) or [M<small><sub>3</sub></small>(μ-OOCR)<small><sub>6</sub></small>(CH<small><sub>3</sub></small>CN)<small><sub>2</sub></small>], M = Ni<small><sup>II</sup></small>, Co<small><sup>II</sup></small>, R = Cym, a series of heterometallic polymers with metal cores {Cu<small><sub>2</sub></small>Fe}<small><sub><em>n</em></sub></small> (<strong>1</strong>), {Cu<small><sub>2</sub></small>Mn<small><sub>4</sub></small>Fe}<small><sub><em>n</em></sub></small> (<strong>2</strong>) {Ni<small><sub>2</sub></small>Mn<small><sub>4</sub></small>Fe}<small><sub><em>n</em></sub></small> (<strong>3</strong>), and {Co<small><sub>2</sub></small>Mn<small><sub>4</sub></small>Fe}<small><sub><em>n</em></sub></small> (<strong>4</strong>) were obtained under mild conditions. Compounds <strong>1</strong> and <strong>2</strong> showed antibacterial activity against a <em>Mycobacterium smegmatis</em> strain <em>in vitro.</em></p>","PeriodicalId":95,"journal":{"name":"New Journal of Chemistry","volume":null,"pages":null},"PeriodicalIF":2.7000,"publicationDate":"2024-10-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Targeted design of heterotrimetallic 1-D coordination polymers based on functionalized metallocenes featuring antibacterial activity†\",\"authors\":\"Marina A. Uvarova, Maxim A. Shmelev, Olga B. Bekker, Irina A. Lutsenko, Sergey E. Nefedov and Igor L. Eremenko\",\"doi\":\"10.1039/D4NJ03598D\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Using (bis)diethoxyphosphoryl ferrocene [Fc(O<img>P(OEt)<small><sub>2</sub></small>)<small><sub>2</sub></small>] and transition metal carboxylates – [M<small><sub>2</sub></small>(μ-OOCR)<small><sub>4</sub></small>(CH<small><sub>3</sub></small>CN)<small><sub>2</sub></small>], M = Cu<small><sup>II</sup></small>, R = <small><sup><em>t</em></sup></small>Bu, (C<small><sub>5</sub></small>H<small><sub>4</sub></small>)Mn(CO)<small><sub>3</sub></small> (Cym) or [M<small><sub>3</sub></small>(μ-OOCR)<small><sub>6</sub></small>(CH<small><sub>3</sub></small>CN)<small><sub>2</sub></small>], M = Ni<small><sup>II</sup></small>, Co<small><sup>II</sup></small>, R = Cym, a series of heterometallic polymers with metal cores {Cu<small><sub>2</sub></small>Fe}<small><sub><em>n</em></sub></small> (<strong>1</strong>), {Cu<small><sub>2</sub></small>Mn<small><sub>4</sub></small>Fe}<small><sub><em>n</em></sub></small> (<strong>2</strong>) {Ni<small><sub>2</sub></small>Mn<small><sub>4</sub></small>Fe}<small><sub><em>n</em></sub></small> (<strong>3</strong>), and {Co<small><sub>2</sub></small>Mn<small><sub>4</sub></small>Fe}<small><sub><em>n</em></sub></small> (<strong>4</strong>) were obtained under mild conditions. Compounds <strong>1</strong> and <strong>2</strong> showed antibacterial activity against a <em>Mycobacterium smegmatis</em> strain <em>in vitro.</em></p>\",\"PeriodicalId\":95,\"journal\":{\"name\":\"New Journal of Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.7000,\"publicationDate\":\"2024-10-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"New Journal of Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2024/nj/d4nj03598d\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"New Journal of Chemistry","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2024/nj/d4nj03598d","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Targeted design of heterotrimetallic 1-D coordination polymers based on functionalized metallocenes featuring antibacterial activity†
Using (bis)diethoxyphosphoryl ferrocene [Fc(OP(OEt)2)2] and transition metal carboxylates – [M2(μ-OOCR)4(CH3CN)2], M = CuII, R = tBu, (C5H4)Mn(CO)3 (Cym) or [M3(μ-OOCR)6(CH3CN)2], M = NiII, CoII, R = Cym, a series of heterometallic polymers with metal cores {Cu2Fe}n (1), {Cu2Mn4Fe}n (2) {Ni2Mn4Fe}n (3), and {Co2Mn4Fe}n (4) were obtained under mild conditions. Compounds 1 and 2 showed antibacterial activity against a Mycobacterium smegmatis strain in vitro.
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