细胞抑制剂 Dioxadet 的水合焓和热容量

IF 1.8 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Mendeleev Communications Pub Date : 2024-09-01 DOI:10.1016/j.mencom.2024.09.017

Nataliya L. Smirnova , Andrey V. Kustov , Airat A. Notfullin , Michail I. Yagofarov , Dmitriy V. Batov , Konstantin N. Semenov

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引用次数: 0

摘要

研究人员获得了著名抗癌剂 Dioxadet 水化的热化学数据。通过热量计测定了它在不同温度下的溶解焓和升华焓，并在此基础上计算了溶质在 298.15 K 时从理想气体状态转移到无限稀释水溶液的标准焓（ΔhydrH0 = -154.6 ± 3.6 kJ mol-1）和标准热容（ΔhydrCp0 = 384 ± 80 J mol-1 K-1）。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Enthalpy and heat capacity of hydration of the cytostatic Dioxadet

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Enthalpy and heat capacity of hydration of the cytostatic Dioxadet

Thermochemical data on hydration of the well-established anticancer agent Dioxadet were obtained. Its enthalpies of solution and sublimation at various temperatures were determined calorimetrically, and on their basis the standard enthalpy (Δ_hydrH⁰ = −154.6 ± 3.6 kJ mol⁻¹) and the standard heat capacity (Δ_hydrC_p⁰ = 384 ± 80 J mol⁻¹ K⁻¹) of the transfer of the solute from the state of an ideal gas to an aqueous solution at infinite dilution at 298.15 K were calculated.

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来源期刊

Mendeleev Communications 化学-化学综合

CiteScore

3.00

自引率

21.10%

发文量

226

审稿时长

4-8 weeks

期刊介绍： Mendeleev Communications is the journal of the Russian Academy of Sciences, launched jointly by the Academy of Sciences of the USSR and the Royal Society of Chemistry (United Kingdom) in 1991. Starting from 1st January 2007, Elsevier is the new publishing partner of Mendeleev Communications. Mendeleev Communications publishes short communications in chemistry. The journal primarily features papers from the Russian Federation and the other states of the former USSR. However, it also includes papers by authors from other parts of the world. Mendeleev Communications is not a translated journal, but instead is published directly in English. The International Editorial Board is composed of eminent scientists who provide advice on refereeing policy.