丙酮与η3-烯丙基配体在[Pd(η3-C6H9O)(μ-Cl)]2 复合物中的非同寻常的缩合作用

IF 1.8 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Mendeleev Communications Pub Date : 2024-09-01 DOI:10.1016/j.mencom.2024.09.040

Inessa A. Efimenko , Alexey S. Kubasov , Nina A. Ivanova , Olga S. Erofeeva , Ludmila I. Demina

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引用次数: 0

摘要

发现了一种一步反应生成 h3-烯丙基配合物 [Pd(h3-C6H9O)(μ-Cl)]2。在室温下，丙酮在含有[Pd(PhCN)2Cl2]和有机酸的溶液中缩合，形成了该配合物中的取代 h3-烯丙基配体。通过单晶 X 射线衍射分析确定了 Pdii 复合物的结构。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Unusual condensation of acetone giving η3-allyl ligand in the [Pd(η3-C6H9O)(μ-Cl)]2 complex

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Unusual condensation of acetone giving η3-allyl ligand in the [Pd(η3-C6H9O)(μ-Cl)]2 complex

A one-step reaction was discovered giving the h³-allyl complex [Pd(h³-C₆H₉O)(μ-Cl)]₂. The formation of the substituted h³-allyl ligand in the complex occurs as a result of the condensation of acetone at room temperature in a solution containing [Pd(PhCN)₂Cl₂] and organic acids. The structure of the resulting Pdⁱⁱ complex was determined by single crystal X-ray diffraction analysis.

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来源期刊

Mendeleev Communications 化学-化学综合

CiteScore

3.00

自引率

21.10%

发文量

226

审稿时长

4-8 weeks

期刊介绍： Mendeleev Communications is the journal of the Russian Academy of Sciences, launched jointly by the Academy of Sciences of the USSR and the Royal Society of Chemistry (United Kingdom) in 1991. Starting from 1st January 2007, Elsevier is the new publishing partner of Mendeleev Communications. Mendeleev Communications publishes short communications in chemistry. The journal primarily features papers from the Russian Federation and the other states of the former USSR. However, it also includes papers by authors from other parts of the world. Mendeleev Communications is not a translated journal, but instead is published directly in English. The International Editorial Board is composed of eminent scientists who provide advice on refereeing policy.