{"title":"用于二氧化碳加氢的 CoCe 复合催化剂:孔结构的影响","authors":"","doi":"10.1016/j.joei.2024.101856","DOIUrl":null,"url":null,"abstract":"<div><div>In order to realize the dual carbon goals of “carbon peaking” and “carbon neutrality”, the design and development CO<sub>2</sub> hydrogenation catalyst with high performances is of great significance. In this study, the CoCe composite catalysts were prepared by different methods and used to CO<sub>2</sub> catalytic hydrogenation. The physicochemical properties of the prepared catalysts were characterized by XRD, BET, TEM/HRTEM, and H<sub>2</sub>-TPD. The characterization results indicated that the studied CoCe composite catalytsts with different pore structure can be prepared by different preparation methods. The suitable preparation method can promote Co species to be dissolved into the CeO<sub>2</sub> lattice to form Ce-O-Co solid solution, which can promote the corresponding Co species to be reduced by H<sub>2</sub> to form active Co<sup>0</sup> species. The large specific surface area and developed ordered mesoporous structure of the CoCe-HT catalyst precursor, which was prepared by hard-template method, are conducive to the formation of active Co<sup>0</sup> species and activation of H<sub>2</sub> to produce reactive H species. The CO<sub>2</sub> hydrogenation activity of the studied CoCe composite catalysts follows the following order: CoCe-HT > CoCe-CP > CoCe-CA > CoCe-HY. The CoCe-HT catalyst showed high CO<sub>2</sub> hydrogenation conversion of 53.9 % and good using stability at 360 °C for 600 min. However, the CoCe-CA prepared by complex method has a poor use stability.</div></div>","PeriodicalId":17287,"journal":{"name":"Journal of The Energy Institute","volume":null,"pages":null},"PeriodicalIF":5.6000,"publicationDate":"2024-10-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"CoCe composite catalyst for CO2 hydrogenation: Effect of pore structure\",\"authors\":\"\",\"doi\":\"10.1016/j.joei.2024.101856\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>In order to realize the dual carbon goals of “carbon peaking” and “carbon neutrality”, the design and development CO<sub>2</sub> hydrogenation catalyst with high performances is of great significance. In this study, the CoCe composite catalysts were prepared by different methods and used to CO<sub>2</sub> catalytic hydrogenation. The physicochemical properties of the prepared catalysts were characterized by XRD, BET, TEM/HRTEM, and H<sub>2</sub>-TPD. The characterization results indicated that the studied CoCe composite catalytsts with different pore structure can be prepared by different preparation methods. The suitable preparation method can promote Co species to be dissolved into the CeO<sub>2</sub> lattice to form Ce-O-Co solid solution, which can promote the corresponding Co species to be reduced by H<sub>2</sub> to form active Co<sup>0</sup> species. The large specific surface area and developed ordered mesoporous structure of the CoCe-HT catalyst precursor, which was prepared by hard-template method, are conducive to the formation of active Co<sup>0</sup> species and activation of H<sub>2</sub> to produce reactive H species. The CO<sub>2</sub> hydrogenation activity of the studied CoCe composite catalysts follows the following order: CoCe-HT > CoCe-CP > CoCe-CA > CoCe-HY. The CoCe-HT catalyst showed high CO<sub>2</sub> hydrogenation conversion of 53.9 % and good using stability at 360 °C for 600 min. However, the CoCe-CA prepared by complex method has a poor use stability.</div></div>\",\"PeriodicalId\":17287,\"journal\":{\"name\":\"Journal of The Energy Institute\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":5.6000,\"publicationDate\":\"2024-10-05\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Energy Institute\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1743967124003349\",\"RegionNum\":2,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENERGY & FUELS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Energy Institute","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1743967124003349","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
引用次数: 0
摘要
为了实现 "碳调峰 "和 "碳中和 "的双碳目标,设计和开发高性能的二氧化碳加氢催化剂具有重要意义。本研究采用不同方法制备了 CoCe 复合催化剂,并将其用于 CO2 催化加氢。通过 XRD、BET、TEM/HRTEM 和 H2-TPD 对所制备催化剂的理化性质进行了表征。表征结果表明,所研究的不同孔结构的 CoCe 复合催化剂可通过不同的制备方法制备。合适的制备方法可以促进 Co 物种溶解到 CeO2 晶格中形成 Ce-O-Co 固溶体,从而促进相应的 Co 物种被 H2 还原形成活性 Co0 物种。硬模板法制备的 CoCe-HT 催化剂前驱体具有较大的比表面积和发达的有序介孔结构,有利于形成活性 Co0 物种并活化 H2 生成活性 H 物种。所研究的 CoCe 复合催化剂的 CO2 加氢活性按以下顺序排列:CoCe-HT;CoCe-CP;CoCe-CA;CoCe-HY。CoCe-HT 催化剂的二氧化碳加氢转化率高达 53.9%,在 360 °C 下 600 分钟的使用稳定性良好。然而,用复合方法制备的 CoCe-CA 的使用稳定性较差。
CoCe composite catalyst for CO2 hydrogenation: Effect of pore structure
In order to realize the dual carbon goals of “carbon peaking” and “carbon neutrality”, the design and development CO2 hydrogenation catalyst with high performances is of great significance. In this study, the CoCe composite catalysts were prepared by different methods and used to CO2 catalytic hydrogenation. The physicochemical properties of the prepared catalysts were characterized by XRD, BET, TEM/HRTEM, and H2-TPD. The characterization results indicated that the studied CoCe composite catalytsts with different pore structure can be prepared by different preparation methods. The suitable preparation method can promote Co species to be dissolved into the CeO2 lattice to form Ce-O-Co solid solution, which can promote the corresponding Co species to be reduced by H2 to form active Co0 species. The large specific surface area and developed ordered mesoporous structure of the CoCe-HT catalyst precursor, which was prepared by hard-template method, are conducive to the formation of active Co0 species and activation of H2 to produce reactive H species. The CO2 hydrogenation activity of the studied CoCe composite catalysts follows the following order: CoCe-HT > CoCe-CP > CoCe-CA > CoCe-HY. The CoCe-HT catalyst showed high CO2 hydrogenation conversion of 53.9 % and good using stability at 360 °C for 600 min. However, the CoCe-CA prepared by complex method has a poor use stability.
期刊介绍:
The Journal of the Energy Institute provides peer reviewed coverage of original high quality research on energy, engineering and technology.The coverage is broad and the main areas of interest include:
Combustion engineering and associated technologies; process heating; power generation; engines and propulsion; emissions and environmental pollution control; clean coal technologies; carbon abatement technologies
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The journal''s coverage reflects changes in energy technology that result from the transition to more efficient energy production and end use together with reduced carbon emission.