在 Er3+/Yb3+ 共掺杂的 SrBi2Nb2O9 铁电陶瓷中调控新型可调谐绿光到红光的上转换发光

IF 5.1 2区 材料科学 Q1 MATERIALS SCIENCE, CERAMICS
Abdul Basith , Shobhangna Singh , Ankita Banwal , Megha Narwan , Manoj Verma , Renuka Bokolia
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引用次数: 0

摘要

通过固态方法制备了一系列掺杂铒和镱的 SrBi2-x-yNb2ErxYbyO9(SBN)铁电陶瓷,纯相 SrBi2Nb2O9 的形成已通过 XRD 光谱证实,其几何形状为正交菱形,相群为 A21am。晶格参数和单胞体积随 Yb3+ 含量的增加而增大。SEM 研究表明,SBN 具有随机定向的板状结构,平均粒径范围为 0.9μm 至 2.23μm。傅立叶变换红外光谱(FTIR)的特征谱带位于波长 602cm-1 和 812cm-1。在光致发光(PL)光谱中,使用 488nm 激发波长可获得两条绿色发射带(524nm 和 549nm)和一条微弱的红色发射带(660nm)。陶瓷化合物的漫反射光谱(DRS)显示,带隙值在 2.7 至 3.1eV 之间。在上转换光致发光(UCL)光谱的绿色部分,波长 533 纳米和 554 纳米处有两条 UCL 带;在 980 纳米激光的激发下,红色区域波长 672 纳米处有一条 UCL 带。在初始浓度为 x = 0.03、y = 0.03 时,绿色光带占主导地位,之后随着 Yb3+ 浓度的增加,红色发射占主导地位。泵浦功率对 UCL 发射强度的依赖性研究表明,有两个光子参与了绿色和红色的 UC 发射。对 SBN 成分的时间衰减分析表明,Er3+ 的平均衰减时间为 70μs,共掺系统(Er3+/Yb3+)的平均衰减时间为 37μs。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Regulating novel tunable green to red upconversion luminescence in Er3+/Yb3+ co-doped SrBi2Nb2O9 ferroelectric ceramic
A series of SrBi2-x-yNb2ErxYbyO9 (SBN) ferroelectric ceramics co-doped with Erbium and Ytterbium have been fabricated through solid-state approach, the formation of pure phase SrBi2Nb2O9 has been confirmed by XRD spectra corresponding to orthorhombic geometry having phase group A21am. The lattice parameters and volume of the unit cell increase with the content of Yb3+. SEM study revealed the randomly oriented plate-like structure of SBN having average particle sizes ranging from 0.9 μm to 2.23 μm. The FTIR characteristic bands are found at wavenumber 602 cm−1 and 812 cm−1. In Photoluminescence (PL) spectra, two green emission bands (524 nm and 549 nm) and one weak red band (660 nm) are acquired using a 488 nm excitation wavelength. The diffuse reflectance spectra (DRS) of ceramic compounds reveal that the values of band gap ranges from values 2.7–3.1eV. Two UCL bands are seen at wavelength 533 nm, and at wavelength 554 nm in the green part of the upconversion photoluminescence (UCL) spectra, and a single band observed at a wavelength of 672 nm in the red region upon excited by 980 nm laser. The green band dominates for initial concentration up to x = 0.03, y = 0.03 after which red emission dominates with increasing concentration of Yb3+. The dependence study of pump power on UCL emission intensity reveals that there are two photons are involved in UC emissions of green and red. The time decay analysis of SBN composition showed that the average decay time of Er3+ is 70μs and that of the co-doped system (Er3+/Yb3+) is 37 μs
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来源期刊
Ceramics International
Ceramics International 工程技术-材料科学:硅酸盐
CiteScore
9.40
自引率
15.40%
发文量
4558
审稿时长
25 days
期刊介绍: Ceramics International covers the science of advanced ceramic materials. The journal encourages contributions that demonstrate how an understanding of the basic chemical and physical phenomena may direct materials design and stimulate ideas for new or improved processing techniques, in order to obtain materials with desired structural features and properties. Ceramics International covers oxide and non-oxide ceramics, functional glasses, glass ceramics, amorphous inorganic non-metallic materials (and their combinations with metal and organic materials), in the form of particulates, dense or porous bodies, thin/thick films and laminated, graded and composite structures. Process related topics such as ceramic-ceramic joints or joining ceramics with dissimilar materials, as well as surface finishing and conditioning are also covered. Besides traditional processing techniques, manufacturing routes of interest include innovative procedures benefiting from externally applied stresses, electromagnetic fields and energetic beams, as well as top-down and self-assembly nanotechnology approaches. In addition, the journal welcomes submissions on bio-inspired and bio-enabled materials designs, experimentally validated multi scale modelling and simulation for materials design, and the use of the most advanced chemical and physical characterization techniques of structure, properties and behaviour. Technologically relevant low-dimensional systems are a particular focus of Ceramics International. These include 0, 1 and 2-D nanomaterials (also covering CNTs, graphene and related materials, and diamond-like carbons), their nanocomposites, as well as nano-hybrids and hierarchical multifunctional nanostructures that might integrate molecular, biological and electronic components.
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