{"title":"在 Er3+/Yb3+ 共掺杂的 SrBi2Nb2O9 铁电陶瓷中调控新型可调谐绿光到红光的上转换发光","authors":"Abdul Basith , Shobhangna Singh , Ankita Banwal , Megha Narwan , Manoj Verma , Renuka Bokolia","doi":"10.1016/j.ceramint.2024.10.086","DOIUrl":null,"url":null,"abstract":"<div><div>A series of SrBi<sub>2-x-y</sub>Nb<sub>2</sub>Er<sub>x</sub>Yb<sub>y</sub>O<sub>9</sub> (SBN) ferroelectric ceramics co-doped with Erbium and Ytterbium have been fabricated through solid-state approach, the formation of pure phase SrBi<sub>2</sub>Nb<sub>2</sub>O<sub>9</sub> has been confirmed by XRD spectra corresponding to orthorhombic geometry having phase group A21am. The lattice parameters and volume of the unit cell increase with the content of Yb<sup>3+</sup>. SEM study revealed the randomly oriented plate-like structure of SBN having average particle sizes ranging from 0.9 μm to 2.23 μm. The FTIR characteristic bands are found at wavenumber 602 cm<sup>−1</sup> and 812 cm<sup>−1</sup>. In Photoluminescence (PL) spectra, two green emission bands (524 nm and 549 nm) and one weak red band (660 nm) are acquired using a 488 nm excitation wavelength. The diffuse reflectance spectra (DRS) of ceramic compounds reveal that the values of band gap ranges from values 2.7–3.1eV. Two UCL bands are seen at wavelength 533 nm, and at wavelength 554 nm in the green part of the upconversion photoluminescence (UCL) spectra, and a single band observed at a wavelength of 672 nm in the red region upon excited by 980 nm laser. The green band dominates for initial concentration up to x = 0.03, y = 0.03 after which red emission dominates with increasing concentration of Yb<sup>3+</sup>. The dependence study of pump power on UCL emission intensity reveals that there are two photons are involved in UC emissions of green and red. The time decay analysis of SBN composition showed that the average decay time of Er<sup>3+</sup> is 70μs and that of the co-doped system (Er<sup>3+</sup>/Yb<sup>3+</sup>) is 37 μs</div></div>","PeriodicalId":267,"journal":{"name":"Ceramics International","volume":"50 24","pages":"Pages 52344-52355"},"PeriodicalIF":5.1000,"publicationDate":"2024-12-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Regulating novel tunable green to red upconversion luminescence in Er3+/Yb3+ co-doped SrBi2Nb2O9 ferroelectric ceramic\",\"authors\":\"Abdul Basith , Shobhangna Singh , Ankita Banwal , Megha Narwan , Manoj Verma , Renuka Bokolia\",\"doi\":\"10.1016/j.ceramint.2024.10.086\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>A series of SrBi<sub>2-x-y</sub>Nb<sub>2</sub>Er<sub>x</sub>Yb<sub>y</sub>O<sub>9</sub> (SBN) ferroelectric ceramics co-doped with Erbium and Ytterbium have been fabricated through solid-state approach, the formation of pure phase SrBi<sub>2</sub>Nb<sub>2</sub>O<sub>9</sub> has been confirmed by XRD spectra corresponding to orthorhombic geometry having phase group A21am. The lattice parameters and volume of the unit cell increase with the content of Yb<sup>3+</sup>. SEM study revealed the randomly oriented plate-like structure of SBN having average particle sizes ranging from 0.9 μm to 2.23 μm. The FTIR characteristic bands are found at wavenumber 602 cm<sup>−1</sup> and 812 cm<sup>−1</sup>. In Photoluminescence (PL) spectra, two green emission bands (524 nm and 549 nm) and one weak red band (660 nm) are acquired using a 488 nm excitation wavelength. The diffuse reflectance spectra (DRS) of ceramic compounds reveal that the values of band gap ranges from values 2.7–3.1eV. Two UCL bands are seen at wavelength 533 nm, and at wavelength 554 nm in the green part of the upconversion photoluminescence (UCL) spectra, and a single band observed at a wavelength of 672 nm in the red region upon excited by 980 nm laser. The green band dominates for initial concentration up to x = 0.03, y = 0.03 after which red emission dominates with increasing concentration of Yb<sup>3+</sup>. The dependence study of pump power on UCL emission intensity reveals that there are two photons are involved in UC emissions of green and red. The time decay analysis of SBN composition showed that the average decay time of Er<sup>3+</sup> is 70μs and that of the co-doped system (Er<sup>3+</sup>/Yb<sup>3+</sup>) is 37 μs</div></div>\",\"PeriodicalId\":267,\"journal\":{\"name\":\"Ceramics International\",\"volume\":\"50 24\",\"pages\":\"Pages 52344-52355\"},\"PeriodicalIF\":5.1000,\"publicationDate\":\"2024-12-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Ceramics International\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S027288422404598X\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, CERAMICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Ceramics International","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S027288422404598X","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
Regulating novel tunable green to red upconversion luminescence in Er3+/Yb3+ co-doped SrBi2Nb2O9 ferroelectric ceramic
A series of SrBi2-x-yNb2ErxYbyO9 (SBN) ferroelectric ceramics co-doped with Erbium and Ytterbium have been fabricated through solid-state approach, the formation of pure phase SrBi2Nb2O9 has been confirmed by XRD spectra corresponding to orthorhombic geometry having phase group A21am. The lattice parameters and volume of the unit cell increase with the content of Yb3+. SEM study revealed the randomly oriented plate-like structure of SBN having average particle sizes ranging from 0.9 μm to 2.23 μm. The FTIR characteristic bands are found at wavenumber 602 cm−1 and 812 cm−1. In Photoluminescence (PL) spectra, two green emission bands (524 nm and 549 nm) and one weak red band (660 nm) are acquired using a 488 nm excitation wavelength. The diffuse reflectance spectra (DRS) of ceramic compounds reveal that the values of band gap ranges from values 2.7–3.1eV. Two UCL bands are seen at wavelength 533 nm, and at wavelength 554 nm in the green part of the upconversion photoluminescence (UCL) spectra, and a single band observed at a wavelength of 672 nm in the red region upon excited by 980 nm laser. The green band dominates for initial concentration up to x = 0.03, y = 0.03 after which red emission dominates with increasing concentration of Yb3+. The dependence study of pump power on UCL emission intensity reveals that there are two photons are involved in UC emissions of green and red. The time decay analysis of SBN composition showed that the average decay time of Er3+ is 70μs and that of the co-doped system (Er3+/Yb3+) is 37 μs
期刊介绍:
Ceramics International covers the science of advanced ceramic materials. The journal encourages contributions that demonstrate how an understanding of the basic chemical and physical phenomena may direct materials design and stimulate ideas for new or improved processing techniques, in order to obtain materials with desired structural features and properties.
Ceramics International covers oxide and non-oxide ceramics, functional glasses, glass ceramics, amorphous inorganic non-metallic materials (and their combinations with metal and organic materials), in the form of particulates, dense or porous bodies, thin/thick films and laminated, graded and composite structures. Process related topics such as ceramic-ceramic joints or joining ceramics with dissimilar materials, as well as surface finishing and conditioning are also covered. Besides traditional processing techniques, manufacturing routes of interest include innovative procedures benefiting from externally applied stresses, electromagnetic fields and energetic beams, as well as top-down and self-assembly nanotechnology approaches. In addition, the journal welcomes submissions on bio-inspired and bio-enabled materials designs, experimentally validated multi scale modelling and simulation for materials design, and the use of the most advanced chemical and physical characterization techniques of structure, properties and behaviour.
Technologically relevant low-dimensional systems are a particular focus of Ceramics International. These include 0, 1 and 2-D nanomaterials (also covering CNTs, graphene and related materials, and diamond-like carbons), their nanocomposites, as well as nano-hybrids and hierarchical multifunctional nanostructures that might integrate molecular, biological and electronic components.