{"title":"在可见光照射下降解四环素的 CeO2/BiYO3 光催化剂","authors":"Tharit Lerdwiriyanupap , Anurak Waehayee , Thitipong Choklap , Jeeranan Prachanat , Hideki Nakajima , Tammanoon Chankhanittha , Teera Butburee , Theeranun Siritanon","doi":"10.1016/j.ceramint.2024.10.126","DOIUrl":null,"url":null,"abstract":"<div><div>Photocatalysis has received extensive attention as a promising method for reducing antibiotic contamination in water. In this study, we prepared and investigated the photodegradation efficiency of the CeO<sub>2</sub>/BiYO<sub>3</sub> system, using tetracycline (TC) as a model pollutant. The composites demonstrated significantly higher photocatalytic activity compared to pure BiYO<sub>3</sub> and CeO<sub>2</sub>, demonstrating their potential as effective photocatalysts. A detailed investigation of the band potentials indicated that the two semiconductors form a type II heterojunction, enhancing charge separation. Furthermore, the presence of the Ce<sup>3+</sup>/Ce<sup>4+</sup> redox couple serves as an electron trap site, improving the photocatalytic performance by reducing electron-hole recombination. The catalyst achieved peak efficiency only during the first cycle. However, a simple annealing process effectively regenerated the catalyst to its original efficiency, suggesting that the CeO<sub>2</sub>/BiYO<sub>3</sub> composite can be reused with minimal loss of activity. Additionally, we examined the distinct photodegradation mechanisms of pure BiYO<sub>3</sub> and the CeO<sub>2</sub>/BiYO<sub>3</sub> composite. Our results provide insights into how the formation of heterostructures influences photocatalytic processes. These findings are valuable for the future design and development of related heterostructure photocatalysts, aiming to enhance their efficiency for the degradation of various pollutants.</div></div>","PeriodicalId":267,"journal":{"name":"Ceramics International","volume":"50 24","pages":"Pages 52723-52732"},"PeriodicalIF":5.1000,"publicationDate":"2024-12-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"CeO2/BiYO3 photocatalyst for the degradation of tetracycline under visible light irradiation\",\"authors\":\"Tharit Lerdwiriyanupap , Anurak Waehayee , Thitipong Choklap , Jeeranan Prachanat , Hideki Nakajima , Tammanoon Chankhanittha , Teera Butburee , Theeranun Siritanon\",\"doi\":\"10.1016/j.ceramint.2024.10.126\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Photocatalysis has received extensive attention as a promising method for reducing antibiotic contamination in water. In this study, we prepared and investigated the photodegradation efficiency of the CeO<sub>2</sub>/BiYO<sub>3</sub> system, using tetracycline (TC) as a model pollutant. The composites demonstrated significantly higher photocatalytic activity compared to pure BiYO<sub>3</sub> and CeO<sub>2</sub>, demonstrating their potential as effective photocatalysts. A detailed investigation of the band potentials indicated that the two semiconductors form a type II heterojunction, enhancing charge separation. Furthermore, the presence of the Ce<sup>3+</sup>/Ce<sup>4+</sup> redox couple serves as an electron trap site, improving the photocatalytic performance by reducing electron-hole recombination. The catalyst achieved peak efficiency only during the first cycle. However, a simple annealing process effectively regenerated the catalyst to its original efficiency, suggesting that the CeO<sub>2</sub>/BiYO<sub>3</sub> composite can be reused with minimal loss of activity. Additionally, we examined the distinct photodegradation mechanisms of pure BiYO<sub>3</sub> and the CeO<sub>2</sub>/BiYO<sub>3</sub> composite. Our results provide insights into how the formation of heterostructures influences photocatalytic processes. These findings are valuable for the future design and development of related heterostructure photocatalysts, aiming to enhance their efficiency for the degradation of various pollutants.</div></div>\",\"PeriodicalId\":267,\"journal\":{\"name\":\"Ceramics International\",\"volume\":\"50 24\",\"pages\":\"Pages 52723-52732\"},\"PeriodicalIF\":5.1000,\"publicationDate\":\"2024-12-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Ceramics International\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0272884224046376\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, CERAMICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Ceramics International","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0272884224046376","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
CeO2/BiYO3 photocatalyst for the degradation of tetracycline under visible light irradiation
Photocatalysis has received extensive attention as a promising method for reducing antibiotic contamination in water. In this study, we prepared and investigated the photodegradation efficiency of the CeO2/BiYO3 system, using tetracycline (TC) as a model pollutant. The composites demonstrated significantly higher photocatalytic activity compared to pure BiYO3 and CeO2, demonstrating their potential as effective photocatalysts. A detailed investigation of the band potentials indicated that the two semiconductors form a type II heterojunction, enhancing charge separation. Furthermore, the presence of the Ce3+/Ce4+ redox couple serves as an electron trap site, improving the photocatalytic performance by reducing electron-hole recombination. The catalyst achieved peak efficiency only during the first cycle. However, a simple annealing process effectively regenerated the catalyst to its original efficiency, suggesting that the CeO2/BiYO3 composite can be reused with minimal loss of activity. Additionally, we examined the distinct photodegradation mechanisms of pure BiYO3 and the CeO2/BiYO3 composite. Our results provide insights into how the formation of heterostructures influences photocatalytic processes. These findings are valuable for the future design and development of related heterostructure photocatalysts, aiming to enhance their efficiency for the degradation of various pollutants.
期刊介绍:
Ceramics International covers the science of advanced ceramic materials. The journal encourages contributions that demonstrate how an understanding of the basic chemical and physical phenomena may direct materials design and stimulate ideas for new or improved processing techniques, in order to obtain materials with desired structural features and properties.
Ceramics International covers oxide and non-oxide ceramics, functional glasses, glass ceramics, amorphous inorganic non-metallic materials (and their combinations with metal and organic materials), in the form of particulates, dense or porous bodies, thin/thick films and laminated, graded and composite structures. Process related topics such as ceramic-ceramic joints or joining ceramics with dissimilar materials, as well as surface finishing and conditioning are also covered. Besides traditional processing techniques, manufacturing routes of interest include innovative procedures benefiting from externally applied stresses, electromagnetic fields and energetic beams, as well as top-down and self-assembly nanotechnology approaches. In addition, the journal welcomes submissions on bio-inspired and bio-enabled materials designs, experimentally validated multi scale modelling and simulation for materials design, and the use of the most advanced chemical and physical characterization techniques of structure, properties and behaviour.
Technologically relevant low-dimensional systems are a particular focus of Ceramics International. These include 0, 1 and 2-D nanomaterials (also covering CNTs, graphene and related materials, and diamond-like carbons), their nanocomposites, as well as nano-hybrids and hierarchical multifunctional nanostructures that might integrate molecular, biological and electronic components.