Matilde Fondo, Paula Oreiro-Martínez, Julio Corredoira-Vázquez, Ana M. García-Deibe, Jesús Sanmartín-Matalobos, Daniel Aravena
{"title":"用 N5O2 配体调节 DyIII 单离子磁体的磁性能","authors":"Matilde Fondo, Paula Oreiro-Martínez, Julio Corredoira-Vázquez, Ana M. García-Deibe, Jesús Sanmartín-Matalobos, Daniel Aravena","doi":"10.1002/aoc.7684","DOIUrl":null,"url":null,"abstract":"<p>[Dy (L<sup>Me</sup>)(H<sub>2</sub>O)]CF<sub>3</sub>SO<sub>3</sub>·0.25H<sub>2</sub>O (<b>1</b>·0.25H<sub>2</sub>O), where H<sub>2</sub>L<sup>Me</sup> is the reported ligand 2,2′-(((pyridine-2,6-diylbis (methylene))bis((pyridin-2-ylmethyl)azanediyl))bis (methylene))bis(4-methylphenol), shows the Dy<sup>III</sup> ion in an <i>N</i><sub><i>5</i></sub><i>O</i><sub><i>3</i></sub> environment, with triangular dodecahedral geometry (D<sub>2d</sub> symmetry). <b>1</b>·0.25H<sub>2</sub>O is a single ion magnet (SIM) with an energy barrier for spin reversal of 510 K, and open hysteresis loops up to 8 K. The magnetostructural comparison of <b>1</b>·0.25H<sub>2</sub>O with some closely related complexes and with other eight-coordinated SIMs with high energy barriers (> 300 K) allows to draw some conclusions to enhance the magnetic performance in these nanomagnets with non-purely axial geometries. <i>Ab initio</i> calculations complement and support the experimental results.</p>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"38 11","pages":""},"PeriodicalIF":3.7000,"publicationDate":"2024-08-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aoc.7684","citationCount":"0","resultStr":"{\"title\":\"Modulating Magnetic Performance in DyIII Single Ion Magnets With N5O2 Ligands\",\"authors\":\"Matilde Fondo, Paula Oreiro-Martínez, Julio Corredoira-Vázquez, Ana M. García-Deibe, Jesús Sanmartín-Matalobos, Daniel Aravena\",\"doi\":\"10.1002/aoc.7684\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>[Dy (L<sup>Me</sup>)(H<sub>2</sub>O)]CF<sub>3</sub>SO<sub>3</sub>·0.25H<sub>2</sub>O (<b>1</b>·0.25H<sub>2</sub>O), where H<sub>2</sub>L<sup>Me</sup> is the reported ligand 2,2′-(((pyridine-2,6-diylbis (methylene))bis((pyridin-2-ylmethyl)azanediyl))bis (methylene))bis(4-methylphenol), shows the Dy<sup>III</sup> ion in an <i>N</i><sub><i>5</i></sub><i>O</i><sub><i>3</i></sub> environment, with triangular dodecahedral geometry (D<sub>2d</sub> symmetry). <b>1</b>·0.25H<sub>2</sub>O is a single ion magnet (SIM) with an energy barrier for spin reversal of 510 K, and open hysteresis loops up to 8 K. The magnetostructural comparison of <b>1</b>·0.25H<sub>2</sub>O with some closely related complexes and with other eight-coordinated SIMs with high energy barriers (> 300 K) allows to draw some conclusions to enhance the magnetic performance in these nanomagnets with non-purely axial geometries. <i>Ab initio</i> calculations complement and support the experimental results.</p>\",\"PeriodicalId\":8344,\"journal\":{\"name\":\"Applied Organometallic Chemistry\",\"volume\":\"38 11\",\"pages\":\"\"},\"PeriodicalIF\":3.7000,\"publicationDate\":\"2024-08-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aoc.7684\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Applied Organometallic Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/aoc.7684\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, APPLIED\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Organometallic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/aoc.7684","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
Modulating Magnetic Performance in DyIII Single Ion Magnets With N5O2 Ligands
[Dy (LMe)(H2O)]CF3SO3·0.25H2O (1·0.25H2O), where H2LMe is the reported ligand 2,2′-(((pyridine-2,6-diylbis (methylene))bis((pyridin-2-ylmethyl)azanediyl))bis (methylene))bis(4-methylphenol), shows the DyIII ion in an N5O3 environment, with triangular dodecahedral geometry (D2d symmetry). 1·0.25H2O is a single ion magnet (SIM) with an energy barrier for spin reversal of 510 K, and open hysteresis loops up to 8 K. The magnetostructural comparison of 1·0.25H2O with some closely related complexes and with other eight-coordinated SIMs with high energy barriers (> 300 K) allows to draw some conclusions to enhance the magnetic performance in these nanomagnets with non-purely axial geometries. Ab initio calculations complement and support the experimental results.
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All new compounds should be satisfactorily identified and proof of their structure given according to generally accepted standards. Structural reports, such as papers exclusively dealing with synthesis and characterization, analytical techniques, or X-ray diffraction studies of metal-organic or organometallic compounds will not be considered. The editors reserve the right to refuse without peer review any manuscript that does not comply with the aims and scope of the journal. Applied Organometallic Chemistry publishes Full Papers, Reviews, Mini Reviews and Communications of scientific research in all areas of organometallic and metal-organic chemistry involving main group metals, transition metals, lanthanides and actinides. All contributions should contain an explicit application of novel compounds, for instance in materials science, nano science, catalysis, chemical vapour deposition, metal-mediated organic synthesis, polymers, bio-organometallics, metallo-therapy, metallo-diagnostics and medicine. Reviews of books covering aspects of the fields of focus are also published.
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