Chantal J. Abou-Fayssal , Leonhard Schill , Rinaldo Poli , Anders Riisager , Eric Manoury , Karine Philippot
{"title":"封闭在具有聚阴离子外壳的三苯基膦氧化物功能化核心交联胶束中的 Rh 纳米粒子:合成、表征及在水性双相氢化中的应用","authors":"Chantal J. Abou-Fayssal , Leonhard Schill , Rinaldo Poli , Anders Riisager , Eric Manoury , Karine Philippot","doi":"10.1016/j.reactfunctpolym.2024.106061","DOIUrl":null,"url":null,"abstract":"<div><div>Core-crosslinked micelles (CCMs) with a hydrophilic polyanionic shell made of poly(sodium styrene sulfonate) chains, P(SS<sup>−</sup>Na<sup>+</sup>), a triphenylphosphine oxide-functionalized polystyrene core (TPPO@PSt) and crosslinked at the inner end of the polystyrene chains by diethylene glycol dimethacrylate (DEGDMA) were synthesized by reversible addition-fragmentation chain-transfer (RAFT) polymerization as a stable TPPO@CCM-A latex. One-pot synthesis of rhodium nanoparticles (RhNPs) by the reduction of [Rh(COD)(<em>μ</em>-Cl)]<sub>2</sub> in the aqueous TPPO@CCM-A latex yielded a stable RhNP-TPPO@CCM-A latex without the need of additional stabilizer or base. This Rh-loaded latex was applied to the catalytic biphasic hydrogenation of styrene under mild conditions with complete selectivity towards ethylbenzene and corrected turnover frequencies (<em>c</em>TOFs) ranging from 3250 to 10,010 h<sup>−1</sup> based on the surface atoms of the RhNPs. Importantly, the catalytic phase proved recyclable after product extraction, owing to the efficient retention of the RhNPs by the core TPPO ligands.</div></div>","PeriodicalId":20916,"journal":{"name":"Reactive & Functional Polymers","volume":"205 ","pages":"Article 106061"},"PeriodicalIF":4.5000,"publicationDate":"2024-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Rh nanoparticles confined in triphenylphosphine oxide-functionalized core-crosslinked micelles with a polyanionic shell: Synthesis, characterization, and application in aqueous biphasic hydrogenation\",\"authors\":\"Chantal J. Abou-Fayssal , Leonhard Schill , Rinaldo Poli , Anders Riisager , Eric Manoury , Karine Philippot\",\"doi\":\"10.1016/j.reactfunctpolym.2024.106061\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Core-crosslinked micelles (CCMs) with a hydrophilic polyanionic shell made of poly(sodium styrene sulfonate) chains, P(SS<sup>−</sup>Na<sup>+</sup>), a triphenylphosphine oxide-functionalized polystyrene core (TPPO@PSt) and crosslinked at the inner end of the polystyrene chains by diethylene glycol dimethacrylate (DEGDMA) were synthesized by reversible addition-fragmentation chain-transfer (RAFT) polymerization as a stable TPPO@CCM-A latex. One-pot synthesis of rhodium nanoparticles (RhNPs) by the reduction of [Rh(COD)(<em>μ</em>-Cl)]<sub>2</sub> in the aqueous TPPO@CCM-A latex yielded a stable RhNP-TPPO@CCM-A latex without the need of additional stabilizer or base. This Rh-loaded latex was applied to the catalytic biphasic hydrogenation of styrene under mild conditions with complete selectivity towards ethylbenzene and corrected turnover frequencies (<em>c</em>TOFs) ranging from 3250 to 10,010 h<sup>−1</sup> based on the surface atoms of the RhNPs. Importantly, the catalytic phase proved recyclable after product extraction, owing to the efficient retention of the RhNPs by the core TPPO ligands.</div></div>\",\"PeriodicalId\":20916,\"journal\":{\"name\":\"Reactive & Functional Polymers\",\"volume\":\"205 \",\"pages\":\"Article 106061\"},\"PeriodicalIF\":4.5000,\"publicationDate\":\"2024-09-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Reactive & Functional Polymers\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1381514824002360\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, APPLIED\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Reactive & Functional Polymers","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1381514824002360","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
Rh nanoparticles confined in triphenylphosphine oxide-functionalized core-crosslinked micelles with a polyanionic shell: Synthesis, characterization, and application in aqueous biphasic hydrogenation
Core-crosslinked micelles (CCMs) with a hydrophilic polyanionic shell made of poly(sodium styrene sulfonate) chains, P(SS−Na+), a triphenylphosphine oxide-functionalized polystyrene core (TPPO@PSt) and crosslinked at the inner end of the polystyrene chains by diethylene glycol dimethacrylate (DEGDMA) were synthesized by reversible addition-fragmentation chain-transfer (RAFT) polymerization as a stable TPPO@CCM-A latex. One-pot synthesis of rhodium nanoparticles (RhNPs) by the reduction of [Rh(COD)(μ-Cl)]2 in the aqueous TPPO@CCM-A latex yielded a stable RhNP-TPPO@CCM-A latex without the need of additional stabilizer or base. This Rh-loaded latex was applied to the catalytic biphasic hydrogenation of styrene under mild conditions with complete selectivity towards ethylbenzene and corrected turnover frequencies (cTOFs) ranging from 3250 to 10,010 h−1 based on the surface atoms of the RhNPs. Importantly, the catalytic phase proved recyclable after product extraction, owing to the efficient retention of the RhNPs by the core TPPO ligands.
期刊介绍:
Reactive & Functional Polymers provides a forum to disseminate original ideas, concepts and developments in the science and technology of polymers with functional groups, which impart specific chemical reactivity or physical, chemical, structural, biological, and pharmacological functionality. The scope covers organic polymers, acting for instance as reagents, catalysts, templates, ion-exchangers, selective sorbents, chelating or antimicrobial agents, drug carriers, sensors, membranes, and hydrogels. This also includes reactive cross-linkable prepolymers and high-performance thermosetting polymers, natural or degradable polymers, conducting polymers, and porous polymers.
Original research articles must contain thorough molecular and material characterization data on synthesis of the above polymers in combination with their applications. Applications include but are not limited to catalysis, water or effluent treatment, separations and recovery, electronics and information storage, energy conversion, encapsulation, or adhesion.