{"title":"利用离子液体/石墨烯复合材料进行吸附蓄热的材料级实验研究","authors":"","doi":"10.1016/j.tsep.2024.102955","DOIUrl":null,"url":null,"abstract":"<div><div>Sorption heat storage technology has recently sparked an increasing interest because of its advanced heat storage capabilities. However, material-level heat and mass transfer challenges persist. This work contributes to the field by the development of new sorption composite materials that are comprised ionic liquids (1-ethyl-3-methylimidazolium methanesulfonate and 1-ethyl-3-methylimidazolium chloride) impregnated in 1–5 2D-layered graphene host matrix. Their sorption, heat transfer, heat storage, and charging/discharging rate properties were experimentally investigated using both water and ethanol as adsorbates. The adsorption isotherms and kinetics for both the adsorbates onto the developed composites and the parent ionic liquids were experimentally measured at different temperatures. The isosteric heat of adsorption for all the studied pairs was determined using the Clausius-Clapeyron method, showing an increasing trend with an increasing uptake. They showed that the specific heat storage capacity reached 187.5 kJ/kg when water was used as the working sorption agent. The corresponding heat charging/discharging rates are significantly higher, 69 %-78 %, than pure ionic liquids. Compared to silica gel as a baseline sorbent, ionic liquid-graphene composites’ heat storage and transfer capacities are higher by three orders of magnitude. The thermal diffusivities of the developed composites were significantly higher than the baseline silica gel. These innovative sorption composites show great potential for improving thermal energy storage efficiency, making them suitable for applications in renewable energy systems, industrial processes, waste heat recovery, and climate control solutions. However, the developed composites achieved inferior performance compared to the silica gel baseline sorbent when using ethanol as a working fluid to utilise sub-zero ambient air as a heat source because of the relatively larger molecular size of ethanol.</div></div>","PeriodicalId":23062,"journal":{"name":"Thermal Science and Engineering Progress","volume":null,"pages":null},"PeriodicalIF":5.1000,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Material-level experimental study on utilising ionic liquid/graphene composites for sorption heat storage\",\"authors\":\"\",\"doi\":\"10.1016/j.tsep.2024.102955\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Sorption heat storage technology has recently sparked an increasing interest because of its advanced heat storage capabilities. However, material-level heat and mass transfer challenges persist. This work contributes to the field by the development of new sorption composite materials that are comprised ionic liquids (1-ethyl-3-methylimidazolium methanesulfonate and 1-ethyl-3-methylimidazolium chloride) impregnated in 1–5 2D-layered graphene host matrix. Their sorption, heat transfer, heat storage, and charging/discharging rate properties were experimentally investigated using both water and ethanol as adsorbates. The adsorption isotherms and kinetics for both the adsorbates onto the developed composites and the parent ionic liquids were experimentally measured at different temperatures. The isosteric heat of adsorption for all the studied pairs was determined using the Clausius-Clapeyron method, showing an increasing trend with an increasing uptake. They showed that the specific heat storage capacity reached 187.5 kJ/kg when water was used as the working sorption agent. The corresponding heat charging/discharging rates are significantly higher, 69 %-78 %, than pure ionic liquids. Compared to silica gel as a baseline sorbent, ionic liquid-graphene composites’ heat storage and transfer capacities are higher by three orders of magnitude. The thermal diffusivities of the developed composites were significantly higher than the baseline silica gel. These innovative sorption composites show great potential for improving thermal energy storage efficiency, making them suitable for applications in renewable energy systems, industrial processes, waste heat recovery, and climate control solutions. However, the developed composites achieved inferior performance compared to the silica gel baseline sorbent when using ethanol as a working fluid to utilise sub-zero ambient air as a heat source because of the relatively larger molecular size of ethanol.</div></div>\",\"PeriodicalId\":23062,\"journal\":{\"name\":\"Thermal Science and Engineering Progress\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":5.1000,\"publicationDate\":\"2024-10-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Thermal Science and Engineering Progress\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2451904924005730\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENERGY & FUELS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Thermal Science and Engineering Progress","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2451904924005730","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
Material-level experimental study on utilising ionic liquid/graphene composites for sorption heat storage
Sorption heat storage technology has recently sparked an increasing interest because of its advanced heat storage capabilities. However, material-level heat and mass transfer challenges persist. This work contributes to the field by the development of new sorption composite materials that are comprised ionic liquids (1-ethyl-3-methylimidazolium methanesulfonate and 1-ethyl-3-methylimidazolium chloride) impregnated in 1–5 2D-layered graphene host matrix. Their sorption, heat transfer, heat storage, and charging/discharging rate properties were experimentally investigated using both water and ethanol as adsorbates. The adsorption isotherms and kinetics for both the adsorbates onto the developed composites and the parent ionic liquids were experimentally measured at different temperatures. The isosteric heat of adsorption for all the studied pairs was determined using the Clausius-Clapeyron method, showing an increasing trend with an increasing uptake. They showed that the specific heat storage capacity reached 187.5 kJ/kg when water was used as the working sorption agent. The corresponding heat charging/discharging rates are significantly higher, 69 %-78 %, than pure ionic liquids. Compared to silica gel as a baseline sorbent, ionic liquid-graphene composites’ heat storage and transfer capacities are higher by three orders of magnitude. The thermal diffusivities of the developed composites were significantly higher than the baseline silica gel. These innovative sorption composites show great potential for improving thermal energy storage efficiency, making them suitable for applications in renewable energy systems, industrial processes, waste heat recovery, and climate control solutions. However, the developed composites achieved inferior performance compared to the silica gel baseline sorbent when using ethanol as a working fluid to utilise sub-zero ambient air as a heat source because of the relatively larger molecular size of ethanol.
期刊介绍:
Thermal Science and Engineering Progress (TSEP) publishes original, high-quality research articles that span activities ranging from fundamental scientific research and discussion of the more controversial thermodynamic theories, to developments in thermal engineering that are in many instances examples of the way scientists and engineers are addressing the challenges facing a growing population – smart cities and global warming – maximising thermodynamic efficiencies and minimising all heat losses. It is intended that these will be of current relevance and interest to industry, academia and other practitioners. It is evident that many specialised journals in thermal and, to some extent, in fluid disciplines tend to focus on topics that can be classified as fundamental in nature, or are ‘applied’ and near-market. Thermal Science and Engineering Progress will bridge the gap between these two areas, allowing authors to make an easy choice, should they or a journal editor feel that their papers are ‘out of scope’ when considering other journals. The range of topics covered by Thermal Science and Engineering Progress addresses the rapid rate of development being made in thermal transfer processes as they affect traditional fields, and important growth in the topical research areas of aerospace, thermal biological and medical systems, electronics and nano-technologies, renewable energy systems, food production (including agriculture), and the need to minimise man-made thermal impacts on climate change. Review articles on appropriate topics for TSEP are encouraged, although until TSEP is fully established, these will be limited in number. Before submitting such articles, please contact one of the Editors, or a member of the Editorial Advisory Board with an outline of your proposal and your expertise in the area of your review.