阐释用于光子应用的发光和光学活性 RE3+ 三掺杂硅磷酸盐玻璃薄膜

IF 3.3 3区 物理与天体物理 Q2 OPTICS
P.J. Gracie, D. Geetha
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引用次数: 0

摘要

通过旋涂技术制备了三掺杂 Er3+/Yb3+/Nd3+ 的多组分硅酸盐玻璃薄膜。X 射线衍射显示,在掺杂了 0.6 mol% 以上 Nd3+ 的玻璃中存在嵴钙钛矿相。薄膜的透明度随着共掺杂剂的加入而增加,这是由于伯斯坦-莫斯偏移导致光带隙增大。蓝色发射的相关色温值较高,表明视觉感知能力增强,这也是冷蓝色薄膜激光器的特征。上转换产生的红色发射显示出平面显示面板的潜力。含有 0.6 mol% Nd3+ 的玻璃的增益截面为 13.54 ×10-20 cm2,这使其成为 S 波段近红外薄膜激光器的理想选择。根据 Inokuti-Hirayama 模型的预测,掺杂超过 0.6 mol% Nd3+ 的玻璃中的偶极-偶极相互作用会导致发光淬灭。在薄膜中观察到的 4F9/2→4I13/2 转变表明,它们适用于电信领域的 O + E + S 波段近红外薄膜激光器。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Explication of the luminescent and optically active RE3+ triply-doped silica phosphate glass films for photonic applications

Explication of the luminescent and optically active RE3+ triply-doped silica phosphate glass films for photonic applications
The multi-component silicate glass films triply-doped with Er3+/Yb3+/Nd3+ were fabricated by spin coating technique. X-ray diffraction revealed a cristobalite phase in the glasses doped above 0.6 mol% of Nd3+. The transparency of the films increases with the addition of the co-dopant, due to the increase in optical band gap by the Burstein-Moss shift. The high value of the correlated color temperature of the blue emission indicates enhanced visual perception, suggestive of cool blue film lasers. The red emission from upconversion exhibits potentiality for flat display panels. The gain cross-section of the glass with 0.6 mol% of Nd3+ was 13.54 ×1020 cm2 which makes it ideal for NIR film lasers in the S-band region. The Inokuti-Hirayama model predicts luminescence quenching due to dipole-dipole interactions in the glasses co-doped beyond 0.6 mol% of Nd3+. The 4F9/24I13/2 transition observed in the films, suggests their suitability for O + E + S band NIR film lasers in telecommunication sectors.
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来源期刊
Journal of Luminescence
Journal of Luminescence 物理-光学
CiteScore
6.70
自引率
13.90%
发文量
850
审稿时长
3.8 months
期刊介绍: The purpose of the Journal of Luminescence is to provide a means of communication between scientists in different disciplines who share a common interest in the electronic excited states of molecular, ionic and covalent systems, whether crystalline, amorphous, or liquid. We invite original papers and reviews on such subjects as: exciton and polariton dynamics, dynamics of localized excited states, energy and charge transport in ordered and disordered systems, radiative and non-radiative recombination, relaxation processes, vibronic interactions in electronic excited states, photochemistry in condensed systems, excited state resonance, double resonance, spin dynamics, selective excitation spectroscopy, hole burning, coherent processes in excited states, (e.g. coherent optical transients, photon echoes, transient gratings), multiphoton processes, optical bistability, photochromism, and new techniques for the study of excited states. This list is not intended to be exhaustive. Papers in the traditional areas of optical spectroscopy (absorption, MCD, luminescence, Raman scattering) are welcome. Papers on applications (phosphors, scintillators, electro- and cathodo-luminescence, radiography, bioimaging, solar energy, energy conversion, etc.) are also welcome if they present results of scientific, rather than only technological interest. However, papers containing purely theoretical results, not related to phenomena in the excited states, as well as papers using luminescence spectroscopy to perform routine analytical chemistry or biochemistry procedures, are outside the scope of the journal. Some exceptions will be possible at the discretion of the editors.
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