Efficient recovery of organic phase from crud in solvent extraction unit of Sarcheshmeh copper complex in Iran by powerful water-absorbent reagents

The formation of stable multi-phase emulsions (crud) is a serious problem in almost all commercial solvent extraction (SX) plants. Crud is a mixture of organic and aqueous phases, air, and organic or inorganic solid particles, often found to distribute itself randomly throughout the separating phases of SX plants. Crud formation is encountered in almost all SX units in metal extraction plants. It causes the loss of solvent and thus increases the process costs. Therefore, the removal of crud and recovery of the expensive organic phase including diluent and extracting reagents from it is of great importance. In this research, the applicability of a range of powerful water absorbent reagents was studied for the recovery of organic phase from the crud formed in copper extraction/electrowining unit of Sarchashmeh copper complex (IRAN). The reagents included gypsum, carbomer, sodium polyacrylate, sodium sulfate, magnesium sulfate and calcium chloride. The results showed that gypsum, carbomer and sodium polyacrylate are effective additives which let the organic phase to be recovered with up to 95 % yield. To ensure that gypsum does not cause a negative effect on the copper loading and stripping of the recovered solvent, the extraction/stripping properties of the organic phase separated with gypsum was compared with the organic phase separated by centrifugation without additives. Surface tension analysis of the gypsum-recovered organic phase also confirmed its suitability for recovery of organic phase from crud. Finally, the calcium content of gypsum-recovered organic phase was measured and compared with that of the organic phase separated by centrifugation without any additive.