{"title":"从尿液中回收营养物质:生物炭上的尿素吸附与作为尿素酶抑制剂的钠钙镁钾的结合","authors":"","doi":"10.1016/j.resconrec.2024.107955","DOIUrl":null,"url":null,"abstract":"<div><div>This study presents an innovative technical integration for concomitant nutrient recovery from source-separated urine. While cation exchange is known for efficient K<sup>+</sup> recovery, it faces competition due to the high molarity of NH<sub>4</sub><sup>+</sup> in hydrolyzed urine. This study proposes inhibiting urease activity to facilitate the recovery of K⁺ and urea from fresh urine. Na-chabazite was first proposed as a urease inhibitor in this study, reducing urease activity by 50 %. Wood biochar, with its high porosity (308.0 m²/g) and polar functional groups, shows a urea adsorption capacity of 25.4 mg/g, which can be further improved by steam activation. The isotherm analysis suggests that urea adsorption onto biochar follows a multi-layer adsorption process. Finally, an integrated process is suggested: \"Na-chabazite and Biochar adsorption → urea hydrolysis → struvite precipitation + ammonia stripping-acid scrubbing\", ensuring efficient recovery of urea, NH<sub>4</sub><sup>+</sup>, PO<sub>4</sub><sup>3-</sup>, and K<sup>+</sup> from source-separated urine.</div></div>","PeriodicalId":21153,"journal":{"name":"Resources Conservation and Recycling","volume":null,"pages":null},"PeriodicalIF":11.2000,"publicationDate":"2024-10-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Nutrient recovery from urine: Urea adsorption onto biochar integrated with Na-chabazite as urease inhibitor\",\"authors\":\"\",\"doi\":\"10.1016/j.resconrec.2024.107955\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>This study presents an innovative technical integration for concomitant nutrient recovery from source-separated urine. While cation exchange is known for efficient K<sup>+</sup> recovery, it faces competition due to the high molarity of NH<sub>4</sub><sup>+</sup> in hydrolyzed urine. This study proposes inhibiting urease activity to facilitate the recovery of K⁺ and urea from fresh urine. Na-chabazite was first proposed as a urease inhibitor in this study, reducing urease activity by 50 %. Wood biochar, with its high porosity (308.0 m²/g) and polar functional groups, shows a urea adsorption capacity of 25.4 mg/g, which can be further improved by steam activation. The isotherm analysis suggests that urea adsorption onto biochar follows a multi-layer adsorption process. Finally, an integrated process is suggested: \\\"Na-chabazite and Biochar adsorption → urea hydrolysis → struvite precipitation + ammonia stripping-acid scrubbing\\\", ensuring efficient recovery of urea, NH<sub>4</sub><sup>+</sup>, PO<sub>4</sub><sup>3-</sup>, and K<sup>+</sup> from source-separated urine.</div></div>\",\"PeriodicalId\":21153,\"journal\":{\"name\":\"Resources Conservation and Recycling\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":11.2000,\"publicationDate\":\"2024-10-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Resources Conservation and Recycling\",\"FirstCategoryId\":\"93\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0921344924005469\",\"RegionNum\":1,\"RegionCategory\":\"环境科学与生态学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ENGINEERING, ENVIRONMENTAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Resources Conservation and Recycling","FirstCategoryId":"93","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0921344924005469","RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, ENVIRONMENTAL","Score":null,"Total":0}
Nutrient recovery from urine: Urea adsorption onto biochar integrated with Na-chabazite as urease inhibitor
This study presents an innovative technical integration for concomitant nutrient recovery from source-separated urine. While cation exchange is known for efficient K+ recovery, it faces competition due to the high molarity of NH4+ in hydrolyzed urine. This study proposes inhibiting urease activity to facilitate the recovery of K⁺ and urea from fresh urine. Na-chabazite was first proposed as a urease inhibitor in this study, reducing urease activity by 50 %. Wood biochar, with its high porosity (308.0 m²/g) and polar functional groups, shows a urea adsorption capacity of 25.4 mg/g, which can be further improved by steam activation. The isotherm analysis suggests that urea adsorption onto biochar follows a multi-layer adsorption process. Finally, an integrated process is suggested: "Na-chabazite and Biochar adsorption → urea hydrolysis → struvite precipitation + ammonia stripping-acid scrubbing", ensuring efficient recovery of urea, NH4+, PO43-, and K+ from source-separated urine.
期刊介绍:
The journal Resources, Conservation & Recycling welcomes contributions from research, which consider sustainable management and conservation of resources. The journal prioritizes understanding the transformation processes crucial for transitioning toward more sustainable production and consumption systems. It highlights technological, economic, institutional, and policy aspects related to specific resource management practices such as conservation, recycling, and resource substitution, as well as broader strategies like improving resource productivity and restructuring production and consumption patterns.
Contributions may address regional, national, or international scales and can range from individual resources or technologies to entire sectors or systems. Authors are encouraged to explore scientific and methodological issues alongside practical, environmental, and economic implications. However, manuscripts focusing solely on laboratory experiments without discussing their broader implications will not be considered for publication in the journal.