Composition and age constraints on a Hadean enriched mantle source revealed by the Paleoarchean São Tomé layered intrusion, NE Brazil

Evidence for Hadean depleted mantle reservoir(s) is well-established by mantle-derived rocks from multiple Archean complexes showing excesses in ¹⁴²Nd compared to the modern mantle. Yet, the existence of an early enriched mantle source, which should have concomitantly formed during these Hadean silicate differentiation event(s), has only been recently confirmed by well-resolved ¹⁴²Nd deficits measured in Paleoarchean mafic amphibolites from the São José do Campestre massif of the Borborema Province, NE Brazil. To investigate the nature and extent of this early-formed enriched reservoir, a series of samples from the Seridó belt, NE Brazil, have been investigated for their geochemical and coupled ^147,146Sm-^143,142Nd isotopic compositions, focusing on the Paleoarchean São Tomé layered intrusion. The São Tomé intrusion is composed of layers of metamorphosed mafic and ultramafic rocks with whole-rock trace element compositions and high olivine crystal Ni contents consistent with an incompatible trace element enriched pyroxenitic mantle source. Most analyzed samples from the Seridó belt yielded negative µ¹⁴²Nd, as low as ∼ -20 (representing the lowest ¹⁴²Nd/¹⁴⁴Nd ratio ever measured in terrestrial rocks), with an average µ¹⁴²Nd for the São Tomé intrusion of -9.6 ± 1.4. The São Tomé samples interpreted as the least isotopically disturbed yielded an ¹⁴⁷Sm-¹⁴³Nd isochron age of 3551 ± 368 Ma, consistent with previous zircon U-Pb ages, with an initial ε¹⁴³Nd = -1.7 ± 1.2. Coupling the long-lived ¹⁴⁷Sm-¹⁴³Nd and the short-lived ¹⁴⁶Sm-¹⁴²Nd systems for the São Tomé rocks suggests a Hadean enriched mantle source formed at ∼4.44 Ga with a ¹⁴⁷Sm/¹⁴⁴Nd of ∼0.18, which may be complementary to the early depleted mantle recorded by Eoarchean rocks from the North Atlantic Craton, possibly formed during magma ocean crystallization. These results also imply that the record of this Hadean enriched mantle source is not restricted to the São José do Campestre massif but extends to a larger portion of the Borborema Province.